化工进展 ›› 2024, Vol. 43 ›› Issue (3): 1412-1417.DOI: 10.16085/j.issn.1000-6613.2023-0437

• 材料科学与技术 • 上一篇    

多孔有机聚合物中试制备及其在聚烯烃催化剂中的应用

王雄(), 康文倩, 任悦, 乔彤森, 张鹏, 黄安平, 李广全   

  1. 中国石油石油化工研究院兰州化工研究中心,甘肃 兰州 730060
  • 收稿日期:2023-03-22 修回日期:2023-04-20 出版日期:2024-03-10 发布日期:2024-04-11
  • 通讯作者: 王雄
  • 作者简介:王雄(1980—),男,博士,高级专家,研究方向为聚烯烃催化剂及聚烯烃新产品开发。E-mail:wangxiong1@petrochina.com.cn
  • 基金资助:
    中石油科技管理部项目(2026B-2621)

Pilot scale production of porous organic polymers and their application in polyolefin catalysts

WANG Xiong(), KANG Wenqian, REN Yue, QIAO Tongsen, ZHANG Peng, HUANG Anping, LI Guangquan   

  1. Lanzhou Petrochemical Research Center, Petrochemical Research Institute, PetroChina, Lanzhou 730060, Gansu, China
  • Received:2023-03-22 Revised:2023-04-20 Online:2024-03-10 Published:2024-04-11
  • Contact: WANG Xiong

摘要:

多孔有机聚合物广泛应用在吸附、分离、催化等领域。本文采用分散聚合工艺,中试制备得到形貌及流动性良好的POP3120T和POP3100载体,POP3120T载体堆密度为0.29g/cm3,比表面积为282m2/g,与无机硅胶载体相当,颗粒粒径23.4μm,粒径分布1.00;POP3100载体堆密度为0.34g/cm3,比表面积约503m2/g,均高于无机硅胶载体,颗粒粒径36.0μm,粒径分布0.93。负载的POP型Z-N聚丙烯催化剂具有良好的丙烯聚合活性,其活性可达到1.0×107g/(mol·h)以上。得到的聚合物堆密度可以达到0.36g/cm3,聚合物细粉含量小于1%,达到商业催化剂的水平,此外负载的POP型Z-N聚丙烯催化剂具有高的立构规整选择性及宽的分子量分布,采用DIBP作为内给电子体制备的催化剂,丙烯聚合制备的聚合物等规度可达97.5%以上,分子量分布可达11以上。

关键词: 多孔有机聚合物, 聚烯烃催化剂, 丙烯聚合, 聚丙烯

Abstract:

Porous organic polymers (POPs) are widely used in many fields such as adsorption, separation and catalysis. In this research, pilot scale POPs (POP3120T and POP3100) were produced by via of dispersion polymerization, which exhibited excellent flowability and surface morphology. High specific surface area (SSA of 282m2/g), bulk density (0.29g/cm3) of POP3120T with average particle size of 23.4µm (PSD: 1.0) were obtained, which was comparable to inorganic silica gel support. POP3100 obtained higher SSA of 503m2/g with average particle size of 36.0µm (PSD: 0.93). The supported Z-N@POP PP catalysts exhibited good polymerization activity above 1.0×107gPP/(mol Ti·h), high bulk density of 0.36g/cm3 and low fine powder content (≥100 mesh, <1%), which was equal to the level of commercial PP catalysts. Furthermore, the supported Z-N@POP PP catalysts showed high stereoregularity with isotacticity index above 97.5% and broad molecular weight distribution above 11.

Key words: porous organic polymers, polyolefin catalysts, propylene polymerization, polypropylene

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