黄原酸改性交联面包酵母的制备及对Pb(Ⅱ)的吸附特性

doi:10.16085/j.issn.1000-6613.2021-1900

化工进展 ›› 2022, Vol. 41 ›› Issue (7): 3925-3937.doi: 10.16085/j.issn.1000-6613.2021-1900

黄原酸改性交联面包酵母的制备及对Pb(Ⅱ)的吸附特性

段正洋¹(), 胡柠檬¹, 李天国²()

^1.楚雄师范学院资源环境与化学学院，云南楚雄 675000
^2.云南农业大学资源与环境学院，云南昆明 650201

收稿日期:2021-09-06 修回日期:2021-10-24 出版日期:2022-07-25 发布日期:2022-07-23
通讯作者: 李天国 E-mail:zyduan@cxtc.edu.cn;rgqinkmust@sina.com
作者简介:段正洋（1990—），男，博士，讲师，主要从事含重金属及染料污染水体控制与治理方面的研究。E-mail：zyduan@cxtc.edu.cn。
基金资助:
国家自然科学基金(41701362);云南省地方高校联合专项——青年项目(202101BA070001-012);云南省教育厅基金(2019J0397);楚雄师范学院博士科研启动基金(JBS2002)

Preparation of xanthate-functionalized cross-linked baker's yeast and its adsorption characteristics for Pb(Ⅱ)

DUAN Zhengyang¹(), HU Ningmeng¹, LI Tianguo²()

^1.College of Resources, Environment and Chemistry, Chuxiong Normal University, Chuxiong 675000, Yunnan, China
^2.College of Resources and Environment, Yunnan Agricultural University, Kunming 650201, Yunnan, China

Received:2021-09-06 Revised:2021-10-24 Online:2022-07-25 Published:2022-07-23
Contact: LI Tianguo E-mail:zyduan@cxtc.edu.cn;rgqinkmust@sina.com

摘要/Abstract

摘要：

以面包酵母为基材，通过两步法制备得到黄原酸改性交联面包酵母（XCBY），并应用于水溶液中Pb(Ⅱ)的去除研究，原始面包酵母、XCBY和XCBY-Pb(Ⅱ)的理化特性分别采用SRA、SEM、EDS、FTIR、XRD和XPS等手段进行表征，研究了溶液pH、吸附剂用量、Pb(Ⅱ)初始浓度等因素对XCBY 吸附性能的影响，并探讨了吸附动力学、等温线、热力学和XCBY的再生性能。结果表明，原始面包酵母经交联和黄原酸改性后，其细胞形态没有明显变化，且对Pb(Ⅱ)的吸附性能得到明显提高。XCBY对Pb(Ⅱ)的吸附过程更符合伪二阶动力学和Langmuir吸附等温线模型，热力学分析表明吸附过程为自发的吸热反应。在30℃、吸附时间为40min的条件下，Langmuir吸附等温线拟合结果显示XCBY对Pb(Ⅱ)的最大吸附量达到319.91mg/g。此外，Pb(Ⅱ)在XCBY上的吸附机制主要依赖于XCBY表面—NH₂的配位作用、—OH的离子交换以及—C( $? ???????$ S)—S^-的螯合作用。指出作为一种简便经济的面包酵母化学改性方法，XCBY在含重金属离子废水的吸附处理方面具有潜在的发展应用前景。

关键词: 面包酵母, 黄原酸改性, 交联, 废水, 吸附机制

Abstract:

Xanthate-functionalized cross-linked baker's yeast (XCBY) was prepared by a two-step method and applied to remove Pb(Ⅱ) from aqueous solutions. The physicochemical characteristics of non-modified baker's yeast, XCBY and Pb(Ⅱ)-loaded XCBY were characterized by SRA, SEM, EDS, FTIR, XRD, and XPS. The impacts of operating parameters of pH, adsorbent dosage, initial concentration of Pb(Ⅱ) on the adsorption performance of XCBY were systematically investigated, and the adsorption kinetics, isotherm, thermodynamics and regeneration performance of XCBY were discussed. The results showed that the original baker's yeast had no significant change in cell morphology after crosslinking and xanthic acid modification, and its adsorption performance for Pb(Ⅱ) was significantly improved. Pseudo-second-order and Langmuir isotherm models effectively described the adsorption behavior of XCBY, and the thermodynamic analysis revealed that the adsorption process of Pb(Ⅱ) onto XCBY was spontaneous and endothermic. The adsorption process for Pb(Ⅱ) reached equilibrium at 30℃ in 40min with a maximum adsorption capacity of 319.91mg/g from the Langmuir isotherm model. Additionally, the adsorption mechanism of Pb(Ⅱ) on XCBY mainly depended on the coordination of —NH₂, ion exchange of —OH and complexation of —C( $? ???????$ S)—S^-. As a facile and economical chemical modification method of baker's yeast, the modified material was a potential and prospective adsorbent for use in the treatment of heavy metal-bearing wastewater.

Key words: baker's yeast, xanthate-functionalized, cross-linked, wastewater, adsorption mechanism

中图分类号:

X705

段正洋, 胡柠檬, 李天国. 黄原酸改性交联面包酵母的制备及对Pb(Ⅱ)的吸附特性[J]. 化工进展, 2022, 41(7): 3925-3937.

DUAN Zhengyang, HU Ningmeng, LI Tianguo. Preparation of xanthate-functionalized cross-linked baker's yeast and its adsorption characteristics for Pb(Ⅱ)[J]. Chemical Industry and Engineering Progress, 2022, 41(7): 3925-3937.

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C₀/mg·L ^-¹	q_{e， exp}/mg·g ^-¹	伪一阶动力学模型			伪二阶动力学模型
C₀/mg·L ^-¹	q_{e， exp}/mg·g ^-¹	q_e/mg·g ^-¹	k₁/min ^-¹	R²	q_e/mg·g ^-¹	k₂/g·mg ^-¹·min ^-¹	R²
25	117.78	112.25	0.285	0.9788	119.21	0.00367	0.9995
50	231.77	222.28	0.320	0.9749	235.04	0.00214	0.9991
100	307.58	296.96	0.509	0.9757	309.93	0.00280	0.9988
200	317.10	308.74	0.537	0.9785	321.62	0.00289	0.9989

t /℃	q_{e， exp}/mg·g ^-¹	Langmuir模型			Freundlich模型			Langmuir-Freundlich模型
t /℃	q_{e， exp}/mg·g ^-¹	q_max/mg·g ^-¹	K_L /L·mg ^-¹	R²	K_F /mg·g ^-¹	n	R²	q_max /mg·g ^-¹	K_LF/L·mg ^-¹	n_LF	R²
25	306.51	308.95	0.433	0.9972	122.38	4.746	0.9217	317.79	0.392	0.868	0.9988
30	317.87	319.91	0.496	0.9927	131.23	4.906	0.9069	323.59	0.478	0.932	0.9922
35	321.90	322.39	0.871	0.9954	149.63	5.531	0.9103	331.11	0.795	0.829	0.9982

吸附剂	吸附量/mg·g ^-¹	参考文献
黄原酸改性交联面包酵母	319.91	本研究
黄原酸改性壳聚糖海绵	216.45	［1］
黄原酸改性纤维素	531.29	［18］
黄原酸改性玉米秸秆	20.58	［25］
黄原酸改性多孔木质素	64.90	［32］
黄原酸功能化蛋壳膜	33.11	［37］
黄原酸改性交联淀粉	47.11	［38］
黄原酸改性交联磁性壳聚糖/聚乙烯醇颗粒	59.86	［39］
黄原酸改性多壁纳米碳管	83.01	［40］
超声协助黄原酸改性纤维素	134.41	［41］
黄原酸改性板栗壳	124.84	［42］

温度/℃	K_d/cm³·g ^-¹	ΔG^?/kJ·mol ^-¹	ΔH^?/kJ·mol ^-¹	ΔS^?/J·mol ^-¹·K ^-¹
25	4.639	-3.803	17.29	70.04
30	5.565	-4.325
35	5.709	-4.463

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黄原酸改性交联面包酵母的制备及对Pb(Ⅱ)的吸附特性

Preparation of xanthate-functionalized cross-linked baker's yeast and its adsorption characteristics for Pb(Ⅱ)

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