化工进展 ›› 2022, Vol. 41 ›› Issue (4): 1873-1885.DOI: 10.16085/j.issn.1000-6613.2021-0732

• 工业催化 • 上一篇    下一篇

钼铋复合金属氧化物催化低碳烯烃选择氧化制备醛类研究进展

李庆慧1,2(), 宋焕玲1, 赵华华1(), 杨建1, 赵军1, 闫亮1, 丑凌军1,3()   

  1. 1.中国科学院兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,甘肃 兰州 730000
    2.中国科学院 大学,北京 100049
    3.中国科学院兰州化学物理研究所苏州研究院,江苏 苏州 215123
  • 收稿日期:2021-04-08 修回日期:2021-07-21 出版日期:2022-04-23 发布日期:2022-04-25
  • 通讯作者: 赵华华,丑凌军
  • 作者简介:李庆慧(1997—),女,硕士研究生,研究方向为多相催化。E-mail:liqinghui97@163.com
  • 基金资助:
    中国石油科技创新基金(2019D-5007-0404);中国科学院青年创新促进会(2017460)

Selective oxidation of light olefins to aldehydes catalyzed by molybdenum-bismuth composite metal oxides

LI Qinghui1,2(), SONG Huanling1, ZHAO Huahua1(), YANG Jian1, ZHAO Jun1, YAN Liang1, CHOU Lingjun1,3()   

  1. 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China
    2.University of Chinese Academy of Sciences, Beijing 100049, China
    3.Suzhou Research Institute of LICP, Chinese Academy of Sciences, Suzhou 215123, Jiangsu, China
  • Received:2021-04-08 Revised:2021-07-21 Online:2022-04-23 Published:2022-04-25
  • Contact: ZHAO Huahua,CHOU Lingjun

摘要:

低碳烯烃选择氧化制备醛类等含氧化合物是生产有机化工中间体及产品的关键步骤,钼铋复合金属氧化物因其优异的催化性能在相关工业界和学术界受到广泛关注,然而目前关于该催化剂上选择氧化反应机制和催化反应本质等科学问题的认识尚未形成统一理论。本文系统综述了钼铋复合金属氧化物在催化低碳烯烃选择氧化制备醛类反应中的研究进展,包括催化剂微观结构的三种调控手段,即主组分钼酸铋物相结构、助剂及载体等对反应性能的影响,并对反应机理进行了深入讨论与总结。最后展望了钼铋复合金属氧化物在该选择氧化反应中的发展前景,为钼铋复合金属氧化物修饰改性及开发高效低碳烯烃选择氧化制含氧化合物催化剂提供思路。

关键词: 催化剂, 多相反应, 活化, 丙烯, 异丁烯, 复合金属氧化物

Abstract:

Selective oxidation of light olefins to produce the corresponding aldehydes and other oxygen-containing compounds is a key step in the production of important organic chemical intermediates and products. Molybdenum bismuth composite metal oxides have attracted wide attentions in industry and academia because of their excellent catalytic performance. However, there is still debate on the selective oxidation mechanism on the catalyst and the nature of the catalytic reaction. This work systematically reviews the research progress of using molybdenum bismuth composite metal oxides as catalyst in selective oxidation of light olefins to aldehydes. It is pointed out that the micro-structure and catalytic performance of molybdenum bismuth composite metal oxides are mainly controlled by three strategies including the phase structure of bismuth molybdate, additives and carriers. And the selective oxidation reaction mechanism over the molybdenum bismuth composite metal oxides is discussed and summarized. Finally, the development of molybdenum-bismuth composite metal oxides in selective oxidation reaction is prospected to provide ideas for their modification and the exploration of efficient catalysts for light olefins to oxygen-containing compounds.

Key words: catalyst, multiphase reaction, activation, propylene, isobutylene, composite metal oxides

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