化工进展 ›› 2021, Vol. 40 ›› Issue (6): 3034-3045.DOI: 10.16085/j.issn.1000-6613.2020-1958
收稿日期:
2020-09-25
修回日期:
2021-01-01
出版日期:
2021-06-06
发布日期:
2021-06-22
通讯作者:
陈焕浩
作者简介:
范晓雷,博士,教授,博士生导师,研究方向为低温等离子体催化。基金资助:
CHEN Huanhao1(), FAN Xiaolei2(
)
Received:
2020-09-25
Revised:
2021-01-01
Online:
2021-06-06
Published:
2021-06-22
Contact:
CHEN Huanhao
摘要:
非热等离子体催化具有反应条件温和、启动快和反应器结构紧凑等特点,在C1分子催化转化领域(如CO2加氢、甲烷活化、水煤气变换反应和甲醇重整制氢)有着广阔的应用前景。具体来说,等离子体特有的高能电子可在气相中快速活化稳定性极强的C1分子并生成活性物质,接着与催化剂结合发生表面化学反应,从而实现常温常压下C1分子的高效转化。然而,等离子体与催化剂之间的协同作用机制以及催化机理极为复杂,仍有待进一步研究。本综述简单介绍了非热等离子体催化转化C1分子的近期研究进展,重点探讨了适用于非热等离子 体的催化剂研究以及催化机理的高级原位表征。最后,提出了非热等离子体催化转化C1分子的未来发展方向:①设计并构筑适用于非热等离子体催化的高效催化剂,并研究其构效关系;②发展高级原位表征技术,揭示活性物质的作用机理以及催化机理;③设计并构建高效的等离子体催化反应器,并建立反应器的理论模型和数值模拟方法,科学指导等离子体反应器的设计、优化和放大。
中图分类号:
陈焕浩, 范晓雷. 非热等离子体催化转化C1分子及其催化剂研究进展[J]. 化工进展, 2021, 40(6): 3034-3045.
CHEN Huanhao, FAN Xiaolei. Review on non-thermal plasma (NTP) catalytic conversion of C1 molecules and its catalysts[J]. Chemical Industry and Engineering Progress, 2021, 40(6): 3034-3045.
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