“背包式”反应精馏集成过程研究进展

doi:10.16085/j.issn.1000-6613.2020-0947

摘要/Abstract

摘要：

“背包式”反应精馏是一种反应器与精馏塔既相互独立又相互耦合的离散集成技术。由于反应与分离处于不同空间位置，能够突破传统反应精馏对工况的限制，拓宽应用范围，且便于工程放大。本文综述了国内外“背包式”反应精馏从基础到应用的研究概况。从转化率、选择性、塔内温度、组成分布等方面，分析了“背包式”反应精馏与传统反应精馏的等效性，指出“背包式”反应精馏的优势在于工况的灵活选择利于实现反应与分离能力的最佳匹配。介绍了“背包式”反应精馏在稳态模拟与优化、动态模拟及控制等方面的研究进展，并从不同工况反应与精馏集成技术的应用、便捷的催化剂装填与反应器设计应用两个角度归纳了该技术的应用进展。最后，从优化设计理论、先进控制方法、能量综合利用以及强化酶催化反应等方面对“背包式”反应精馏进一步的研究与应用进行展望。

关键词: 过程强化, “背包式”反应精馏, 过程集成, 优化设计, 过程控制

Abstract:

Side-reactor column (SRC) configuration is a discrete integration technology in which the reactors and distillation column are not only independent but also coupled with each other. The limitation of operation conditions in traditional reactive distillation (RD) could be overcame due to the different location of reaction and separation, expanding the RD application areas and facilitates industrial amplification. This study reviewed the SRC technology from basic to application. The equivalence of SRC and RD were analyzed from the aspects of conversion, selectivity, temperature, and composition profile. The advantage of SRC was the flexible adjustment of operating conditions, which could realize the perfect match between reaction and separation capacity. The developments in steady state simulation and optimization, dynamic simulation and control strategies of SRC were introduced. It also summarized the current applications of this technology from two aspects: integrated technology of reaction and distillation under different working conditions, convenient catalyst loading and reactor design. The future research and application of SRC were prospected from the aspects of optimization design theory, advanced control methods, comprehensive utilization of energy, enhanced enzyme-catalyzed reaction.

Key words: process intensification, side-reactor column configuration, process integration, optimal design, process control

中图分类号:

TQ03-39

陆佳伟, 孔倩, 汤吉海, 张竹修, 崔咪芬, 陈献, 乔旭. “背包式”反应精馏集成过程研究进展[J]. 化工进展, 2020, 39(12): 4940-4953.

Jiawei LU, Qian KONG, Jihai TANG, Zhuxiu ZHANG, Mifen CUI, Xian CHEN, Xu QIAO. Review on investigation of side-reactor column configuration technology[J]. Chemical Industry and Engineering Progress, 2020, 39(12): 4940-4953.

参考文献

1	KISS A A, JOBSON M, GAO Xin. Reactive distillation: stepping up to the next level of process intensification[J]. Industrial & Engineering Chemistry Research, 2018, 58(15): 5909-5918.
2	高鑫, 赵悦, 李洪, 等. 反应精馏过程耦合强化技术基础与应用研究述评[J]. 化工学报, 2018, 69(1): 218-238.
2	GAO Xin, ZHAO Yue, LI Hong, et al. Review of basic and application investigation of reactive distillation technology for process intensification[J]. CIESC Journal, 2018, 69(1): 218-238.
3	LI Xingang, WANG Rui, YAN Yutao, et al. Ethylene glycol recovery from 2-ethyl-1,3-dioxolane hydrolysis via reactive distillation: pilot-scale experiments and process analysis[J]. Industrial & Engineering Chemistry Research, 2019, 58(45): 20746-20757.
4	HUANG Zhixian, LI Junlan, WANG Lieyun, et al. Novel procedure for the synthesis of dimethyl carbonate by reactive distillation[J]. Industrial & Engineering Chemistry Research, 2014, 53(8): 3321-3328.
5	GAO Xin, WANG Fangzhou, LI Hong, et al. Heat-integrated reactive distillation process for TAME synthesis[J]. Separation and Purification Technology, 2014, 132: 468-478.
6	BO Cuimei, TANG Jihai, CUI Mifen, et al. Control and profile setting of reactive distillation column for benzene chloride consecutive reaction system[J]. Industrial & Engineering Chemistry Research, 2013, 52(49): 17465-17474.
7	WANG Xiaoda, WANG Hongxing, CHEN Jinyi, et al. High conversion of methyl acetate hydrolysis in a reactive dividing wall column by weakening the self-catalyzed esterification reaction[J]. Industrial & Engineering Chemistry Research, 2017, 56(32): 9177-9187.
8	GAO Xin, LIU Xinshuang, LI Xingang, et al. Continuous microwave-assisted reactive distillation column: pilot-scale experiments and model validation[J]. Chemical Engineering Science, 2018, 186: 251-264.
9	GUDENA K, RANGAIAH G P, LAKSHMINARAYANAN S. Modeling and analysis of solid catalyzed reactive HiGee stripping[J]. Chemical Engineering Science, 2012, 80: 242-252.
10	OUNI T, JAKOBSSON K, PYH?LATHI A, et al. Enhancing productivity of side reactor configuration through optimizing the reaction conditions[J]. Chemical Engineering Research & Design, 2004, 82(2): 167-174.
11	JAKOBSSON K, PYH?LAHTI A, PAKKANEN S, et al. Modelling of a side reactor configuration combining reaction and distillation[J]. Chemical Engineering Science, 2002, 57(9): 1521-1524.
12	HUSSAIN A, CHANIAGO Y D, RIAZ A, et al. Design method for the feasibility and technical evaluation of side-reactor column configurations[J]. Chemical Engineering and Processing: Process Intensification, 2019, 144: 107648.
13	BAUR R, KRISHNA R. Distillation column with reactive pump arounds: an alternative to reactive distillation[J]. Chemical Engineering and Processing: Process Intensification, 2004, 43(3): 435-445.
14	HUGHES M J, MOLLER K P. Economic assessment of the toluene disproportionation process using an external reactor-separator configuration[J]. Nephron Clinical Practice, 2007, 5(1): 35-43.
15	BISOWARNO B H, TIAN Yuchu, TADé M O. Application of side reactors on ETBE reactive distillation[J]. Chemical Engineering Journal, 2004, 99(1): 35-43.
16	NAVA J A O, BAUR R, KRISHNA R. Combining distillation and heterogeneous catalytic reactors[J]. Chemical Engineering Research & Design, 2004, 82(2): 160-166.
17	徐骏, 乔旭, 崔咪芬, 等. 制备氯代环己烷的反应精馏耦合工艺研究[J]. 石油化工, 2005, 34(1): 37-40.
17	XU Jun, QIAO Xu, CUI Mifen, et al. Study on preparation of chlorocyclohexane by coupling of reactor and distillation tower[J]. Petrochemical Technology, 2005, 34(1): 37-40.
18	黄丽丽, 白鹏, 赵欢欢, 等. 背包进料的背包式反应精馏生产甲缩醛的模拟[J]. 化学工业与工程, 2011, 28(6): 54-58.
18	HUANG Lili, BAI Peng, ZHAO Huanhuan, et al. Simulation of methylal production by reactive distillation with side reactors fed with methanol[J]. Chemical Industry and Engineering, 2011, 28(6): 54-58.
19	LU Jiawei, KONG Qian, ZHANG Zhuxiu, et al. MINLP optimization of side-reactor column configuration based upon improved bat algorithm[J]. Industrial & Engineering Chemistry Research, 2020, 59(13): 5945-5955.
20	王振松, 许戈, 汤吉海, 等. 常压反应-减压精馏集成生产甲酸环己酯的过程模拟[J]. 高校化学工程学报, 2016, 30(5): 1021-1026.
20	WANG Zhensong, XU Ge, TANG Jihai, et al. Process simulation of cyclohexyl formate production with an atmospheric reaction-vacuum distillation integrated system[J]. Journal of Chemical Engineering of Chinese Universities, 2016, 30(5): 1021-1026.
21	丁良辉, 汤吉海, 崔咪芬, 等. 甲苯氯化连串反应的RD和SRC过程分析与比较[J]. 化工学报, 2013, 64(9): 3277-3284.
21	DING Lianghui, TANG Jihai, CUI Mifen, et al. Analysis and comparison of RD and SRC involving consecutive reaction of chlorination of toluene[J]. CIESC Journal, 2013, 64(9): 3277-3284.
22	KAYMAK D B, LUYBEN W L. Design of distillation columns with external side reactors[J]. Industrial & Engineering Chemistry Research, 2004, 43(25): 8049-8056.
23	KAYMAK D B, LUYBEN W L. Optimum design of a column/side reactor process[J]. Industrial & Engineering Chemistry Research, 2007, 46(15): 5175-5185.
24	徐骏, 乔旭, 崔咪芬, 等. 背包式反应与精馏耦合生产氯化苄技术研究[J]. 化学反应工程与工艺, 2005, 21(2): 122-126.
24	XU Jun, QIAO Xu, CUI Mifen, et al. Study on preparation of benzyl chloride by the technique of coupling knapsack reactors with a distillation tower[J]. Chemical Reaction Engineering and Technology, 2005, 21(2): 122-126.
25	丁良辉, 汤吉海, 崔咪芬, 等. 常压反应-减压精馏耦合生产氯化苄的工艺优化设计[J]. 化工学报, 2011, 62(8): 2323-2327.
25	DING Lianghui, TANG Jihai, CUI Mifen, et al. Optimum design of coupled atmospheric reaction-vacuum distillation technology for benzyl chloride production[J]. CIESC Journal, 2011, 62(8): 2323-2327.
26	薄翠梅, 汤吉海, 乔旭, 等. 苯氯化侧反应精馏过程的模拟优化与系统实现方法[J]. 上海交通大学学报, 2011, 45(8): 1157-1166.
26	BO Cuimei, TANG Jihai, QIAO Xu, et al. The optimization method and simulating system of distillation column with side reactors for benzene chloride production[J]. Journal of Shanghai Jiaotong University, 2011, 45(8): 1157-1166.
27	丁良辉, 汤吉海, 崔咪芬, 等. 不同工况反应精馏耦合生产苄叉二氯的过程模拟[J]. 南京工业大学学报(自然科学版), 2013, 35(2): 16-20.
27	DING Lianghui, TANG Jihai, CUI Mifen, et al. Simulation of coupled reaction and separation technology under different operation conditions for benzal chloride Production[J]. Journal of Nanjing University of technology (Natural Science Edition), 2013, 35(2): 16-20.
28	HOFFMANN A, NOERES C, GóRAK A. Scale-up of reactive distillation columns with catalytic packings[J]. Chemical Engineering and Processing: Process Intensification, 2004, 43(3): 383-395.
29	TAYLOR R, KRISHNA R. Modelling reactive distillation[J]. Chemical Engineering Science, 2000, 55(22): 5183-5229.
30	周娇, 汤吉海, 乔旭, 等. 背包式反应器与精馏塔耦合合成醋酸甲酯的模拟[J]. 南京工业大学学报(自然科学版), 2006, 28(5): 51-56.
30	ZHOU Jiao, TANG Jihai, QIAO Xu, et al. Smiulation of reactive distillation process coupled with side reactors for preparation of methy lacetate[J]. Journal of Nanjing University of technology (Natural Science Edition), 2006, 28(5): 51-56.
31	刘彬彬, 汤吉海, 乔旭, 等. 新型反应精馏集成过程与传统反应精馏过程的比较[J]. 南京工业大学学报(自然科学版), 2008, 30(5): 63-67.
31	LIU Binbin, TANG Jihai, QIAO Xu, et al. Comparison between novel reactive distillation process integrated with side reactors and traditional reactive distillation process[J]. Journal of Nanjing University of technology (Natural Science Edition), 2008, 30(5): 63-67.
32	DING Lianghui, TANG Jihai, CUI Mifen, et al. Optimum design and analysis based on independent reaction amount for distillation column with side reactors: production of benzyl chloride[J]. Industrial & Engineering Chemistry Research, 2011, 50(19): 11143-11152.
33	柏杨进, 薄翠梅, 丁良辉, 等. 带侧反应器反应精馏塔的苯氯化与氯苯精馏过程模拟研究[J]. 过程工程学报, 2011, 11(2): 244-248.
33	BAI Yangjin, BO Cuimei, DING Lianghui, et al. Simulation of chlorination of benzene and distillation of chlorobenzene in a combined reaction and distillation tower with side reactors[J]. The Chinese Journal of Process Engineering, 2011, 11(2): 244-248.
34	宋建国, 黄玉鑫, 孙玉玉, 等. 多效反应精馏过程生产氯化苄的能量集成[J]. 化工学报, 2015, 66(8): 3161-3168.
34	SONG Jianguo, HUANG Yuxin, SUN Yuyu, et al. Energy integration of multi-effect reactive distillation for benzyl chloride Production[J]. CIESC Journal, 2015, 66(8): 3161-3168.
35	丁良辉. 用于甲苯氯化的侧反应器-精馏塔集成系统的优化设计及工业验证[D]. 南京: 南京工业大学, 2013.
35	DING Lianghui. Optimum design and industrial verification of the distillation column coupled with side reactors for the chlorination of toluene[D]. Nanjing: Nanjing Tech University, 2013.
36	DING Lianghui, TANG Jihai, QIAO Xu, et al. Design and analysis of an intensified column with side reactor configuration for ethylene glycol production from ethylene oxide[J]. Chemical Engineering and Processing: Process Intensification, 2020, 147: 107744.
37	HUSSAIN A, CHANIAGO Y D, RIAZ A, et al. Significance of operating pressure on process intensification in a distillation with side-reactor configuration[J]. Separation and Purification Technology, 2019, 213: 533-544.
38	HUSSAIN A, RIAZ A, QYYUM M A, et al. Design trade-offs in a column with side-reactor configuration for improving selectivity in multiple reaction systems[J]. Chemical Engineering and Processing: Process Intensification, 2018, 134: 86-96.
39	许戈, 汤吉海, 陈献, 等. “背包式”反应精馏生产乙酸环己酯工艺的模拟研究[J]. 石油化工, 2017, 46(1): 54-59.
39	XU Ge, TANG Jihai, CHEN Xian, et al. Simulation of “Backpack” reactive distillation process for the production of cyclohexyl acetate[J]. Petrochemical Technology, 2017, 46(1): 54-59.
40	BORCHERS B, MITCHELL J E. An improved branch and bound algorithm for mixed integer nonlinear programs[J]. Computers and Operations Research, 1994, 21(4): 359-367.
41	GEOFFRION A M. Generalized benders decomposition[J]. Journal of Optimization Theory and Application, 1972, 10(4): 237-260.
42	LI Yunpeng, TANG Jihai, CHEN Xian, et al. Effect of relative volatility on the design of reactive distillation with side reactors using MINLP optimization[J]. Chemical Engineering Transactions, 2017, 61: 1267-1272.
43	GANGADWALA J, KIENLE A, STEIN E, et al. Production of butyl acetate by catalytic distillation: process design studies[J]. Industrial & Engineering Chemistry Research, 2004, 43(1): 136-143.
44	GANGADWALA J, KIENLE A. MINLP optimization of butyl acetate synthesis[J]. Chemical Engineering and Processing: Process Intensification, 2007, 46(2): 107-118.
45	SEGOVIA-HERNáNDEZ J G, HERNáNDEZ S, PETRICIOLET A B. Reactive distillation: a review of optimal design using deterministic and stochastic techniques[J]. Chemical Engineering and Processing: Process Intensification, 2015, 97: 134-143.
46	CHENG Jian-Kai, Hao-Yeh LEE, HUANG Hsiao-Ping, et al. Optimal steady-state design of reactive distillation processes using simulated annealing[J]. Journal of the Taiwan Institute of Chemical Engineers, 2009, 40(2): 188-196.
47	蒋宁, 俞杭生, 韩文巧. 基于面积再分配和遗传算法的换热网络改造[J]. 化工进展, 2017, 36(8): 2830-2837.
47	JIANG Ning, YU Hangsheng, HAN Wenqiao. Retrofit of heat exchanger network based on exchanger reassignment and genetic algorithm (GA)[J]. Chemical Industry and Engineering Progress, 2017, 36(8): 2830-2837.
48	薄翠梅, 汤吉海, 杨海荣, 等. 侧反应与精馏集成过程的故障动态特性模拟研究[J]. 化工学报, 2011, 62(8): 70-74.
48	BO Cuimei, TANG Jihai, YANG Hairong, et al. Fault dynamic simulation for distillation process with side reactor[J]. CIESC Journal, 2011, 62(8): 70-74.
49	孙玉玉, 汤吉海, 陈献, 等. 带多台侧反应器的间歇反应精馏生产氯化苄非稳态模拟与过程设计[J]. 高校化学工程学报, 2015, 29(2): 388-394.
49	SUN Yuyu, TANG Jihai, CHEN Xian, et al. Unsteady state simulation and process design of a batch reactive distillation column with multiple side reactors for benzyl chloride production[J]. Journal of Chemical Engineering of Chinese Universities, 2015, 29(2): 388-394.
50	薄翠梅, 柏杨进, 李芳芳, 等. 反应精馏模拟与控制研究进展[J]. 石油化工自动化, 2012, 48(2): 1-6.
50	BO Cuimei, BAI Yangjin, LI Fangfang, et al. Research development on reactive distillation simulation and control[J]. Automation in Petro-chemical Industry, 2012, 48(2): 1-6.
51	AL-ARFAJ M, LUYBEN W L. Comparison of alternative control structures for an ideal two-product reactive distillation column[J]. Industrial & Engineering Chemistry Research, 2000, 39(9): 3298-3307.
52	AL-ARFAJ M, LUYBEN W L. Comparative control study of ideal and methyl acetate reactive distillation[J]. Chemical Engineering Science, 2002, 57(24): 5039-5050.
53	KAYMAK D B, LUYBEN W L. Dynamic control of a column/side-reactor process[J]. Industrial & Engineering Chemistry Research, 2008, 47(22): 8704-8712.
54	柏杨进, 薄翠梅, 丁良辉, 等. 运用HYSYS对背包式反应精馏过程控制的仿真[J]. 化工自动化及仪表, 2011, 38(6): 679-681, 688.
54	BAI Yangjin, BO Cuimei, DING Lianghui, et al. Dynamic simulation and control strategy for distillation column with side reactors[J]. Control and Instruments in Chemical Industry, 2011, 38(6): 679-681, 688.
55	BO Cuimei, TANG Jihai, BAI Yangjin, et al. The design and control of distillation column with side reactors for chlorobenzene production[J]. Chinese Journal of Chemical Engineering, 2012, 20(6): 1113-1120.
56	TSAI Reui-Chiang, CHENG Jian-Kai, HUANG Hsiao-Ping, et al. Design and control of the side reactor configuration for production of ethyl acetate[J]. Industrial & Engineering Chemistry Research, 2008, 47(23): 9472-9484.
57	薄翠梅, 黄庆庆, 汤吉海, 等. 醋酸甲酯侧反应精馏过程的多变量动态控制[J]. 化工学报, 2016, 67(3): 241-246.
57	BO Cuimei, HUANG Qingqing, TANG Jihai, et al. Multi-variable dynamic control of distillation column with side reactors for methyl acetate production[J]. CIESC Journal, 2016, 67(3): 241-246.
58	LEI Zhigang, LI Chengyue, LI Jianwei, et al. Suspension catalytic distillation of simultaneous alkylation and transalkylation for producing cumene[J]. Separation and Purification Technology, 2004, 34(1/2/3): 265-271.
59	施俐, 汤吉海, 陈献, 等. 苯与丙烯烷基化的加压反应与常压精馏集成过程模拟研究[J]. 计算机与应用化学, 2015, 32(8): 912-916.
59	SHI Li, TANG Jihai, CHEN Xian, et al. Simulation of process integrated atmospheric distillation with pressure reaction for alkylation of benzene and propylene[J]. Computers and Applied Chemistry, 2015, 32(8): 912-916.
60	HUSSAIN A, MINH Le Quang, Moonyong LEE. Intensification of the ethylbenzene production process using a column configured with a side reactor[J]. Chemical Engineering and Processing: Process Intensification, 2017, 122: 204-212.
61	KARAS L J. Ester preparation: US5994578[P]. 1999-11-30.
62	黄玉鑫, 汤吉海, 陈献, 等. 不同温度反应与精馏集成生产醋酸叔丁酯的过程模拟[J]. 化工学报, 2015, 66(10): 4039-4046.
62	HUANG Yuxin, TANG Jihai, CHEN Xian, et al. Process simulation of tert-butyl acetate production by distillation column integrated with side reactors under different temperatures[J]. CIESC Journal, 2015, 66(10): 4039-4046.
63	乔旭, 汤吉海, 李聪, 等. 一种有机酸和异丁烯酯化反应精馏耦合生产叔丁酯类化合物的方法: CN102924271B[P]. 2015-04-29.
63	QIAO Xu, TANG Jihai, LI Cong, et al. A method for tert-butyl ester compound production via the esterification of organic acid and isobutylene by reactive distillation: CN102924271B[P]. 2015-04-29.
64	CHEN Xian, LI Yunpeng, XU Ge, et al. A novel process integrating vacuum distillation with atmospheric chlorination reaction for flexible production of tetrachloroethane and pentachloroethane[J]. Chinese Journal of Chemical Engineering, 2018, 26(4): 120-128.
65	汤吉海, 乔旭, 孙玉玉, 等. 一种两段反应精馏串联生产氯化苄的能量集成方法: CN103922891B[P]. 2015-07-15.
65	TANG Jihai, QIAO Xu, SUN Yuyu, et al. An energy integration method for two reactive distillation to produce benzyl chloride: CN103922891B[P]. 2015-07-15.
66	乔旭, 汤吉海, 崔咪芬, 等. 一种生产苄叉二氯或氯代苄叉二氯的方法: CN100532339C[P]. 2009-08-26.
66	QIAO Xu, TANG Jihai, CUI Mifen, et al. A method for producing benzylidene dichloride or chlorinated benzylidene dichloride: CN100532339C[P]. 2009-08-26.
67	乔旭, 吴国新, 陈明, 等. 一种1,2-二氯乙烷氯化生产四/五氯乙烷的反应精馏集成工艺: CN103922888B[P]. 2015-12-02.
67	QIAO Xu, WU Xuoxin, CHEN Ming, et al. An integrated process of distillation column and reactors for chlorination of 1,2-dichloroethane to produce tetra/pentachloroethane: CN103922888B[P]. 2015-12-02.
68	STEYER F, FREUND H, SUNDMACHER K. A novel reactive distillation process for the indirect hydration of cyclohexene to cyclohexanol using a reactive entrainer[J]. Industrial & Engineering Chemistry Research, 2008, 47(23): 9581-9587.
69	YE Jianchu, LI Jun, SHA Yong, et al. Evaluation of reactive distillation and side reactor configuration for direct hydration of cyclohexene to cyclohexanol[J]. Industrial & Engineering Chemistry Research, 2014, 53(4): 1461-1469.
70	HUSSAIN A, Moonyong LEE. Optimal design of an intensified column with side-reactor configuration for the methoxy-methylheptane process[J]. Chemical Engineering Research and Design, 2018, 136: 11-24.
71	王清莲, 王晓达, 王红星, 等. 酶反应精馏耦合技术研究进展[J]. 化工学报, 2020, 71(1): 122-137.
71	WANG Qinglian, WANG Xiaoda, WANG Hongxing, et al. Recent developments in enzymatic reactive distillation coupling technology[J]. CIESC Journal, 2020, 71(1): 122-137.
72	AU-YEUNG P H, RESNICK S M, WITT P M, et al. Horizontal reactive distillation for multicomponent chiral resolution[J]. AIChE Journal, 2013, 59(7): 2603-2620.
73	HUSSAIN A, CHANIAGO Y D, RIAZ A, et al. Process design alternatives for producing ultra-high-purity electronic-grade propylene glycol monomethyl ether acetate[J]. Industrial & Engineering Chemistry Research, 2019, 58(6): 2246-2257.
74	HONDA M, SUZUKI A, NOORJAHAN B, et al. Low pressure CO₂ to dimethyl carbonate by the reaction with methanol promoted by acetonitrile hydration[J]. Chemical Communications, 2009(30): 4596-4598.
75	HU Xutao, CHENG Hongye, KANG Xueqing, et al. Analysis of direct synthesis of dimethyl carbonate from methanol and CO₂ intensified by in-situ hydration-assisted reactive distillation with side reactor[J]. Chemical Engineering and Processing: Process Intensification, 2018, 129: 109-117.
76	WU Tsai-Wei, I-Lung CHIEN. CO₂ utilization feasibility study: dimethyl carbonate direct synthesis process with dehydration reactive distillation[J]. Industrial & Engineering Chemistry Research, 2020, 59(3): 1234-1248.

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