化工进展 ›› 2021, Vol. 40 ›› Issue (2): 1008-1017.DOI: 10.16085/j.issn.1000-6613.2020-0719
郭重阳(), 王玉高(), 申峻(), 牛艳霞, 刘刚, 盛清涛
收稿日期:
2020-04-30
修回日期:
2020-07-02
出版日期:
2021-02-05
发布日期:
2021-02-09
通讯作者:
王玉高,申峻
作者简介:
郭重阳(1995—),男,硕士研究生,研究方向为生物基平台化合物的合成。E-mail:基金资助:
Chongyang GUO(), Yugao WANG(), Jun SHEN(), Yanxia NIU, Gang LIU, Qingtao SHENG
Received:
2020-04-30
Revised:
2020-07-02
Online:
2021-02-05
Published:
2021-02-09
Contact:
Yugao WANG,Jun SHEN
摘要:
2,5-呋喃二甲酸(2,5-FDCA)作为呋喃的衍生物,是一种具有良好稳定性和高附加值的生物基平台化合 物,在聚酯、聚酰胺、聚氨酯、热固性材料和塑化剂等众多领域都得到了广泛应用,如何绿色高效地制备 2,5-FDCA是近年来的研究重点。本文综述了以5-羟甲基糠醛(HMF)、糠酸、己糖二酸等生物质衍生原料合成 2,5-FDCA的方法及特点。己糖二酸等其他路线产率较低,不利于工业化的发展。HMF路线与之相比具有产率高和副产物少的优势,但由于原料来源与食品行业相冲突且生产成本较高,所以利用不可食用的生物质衍生原料糠酸低成本合成目标产物将成为未来可持续发展的重要研究方向。在此基础上,本文通过对比糠酸各路线的优缺点后发现,CO
中图分类号:
郭重阳, 王玉高, 申峻, 牛艳霞, 刘刚, 盛清涛. 从生物质衍生原料到2,5-呋喃二甲酸产品的合成研究进展[J]. 化工进展, 2021, 40(2): 1008-1017.
Chongyang GUO, Yugao WANG, Jun SHEN, Yanxia NIU, Gang LIU, Qingtao SHENG. Research progress on synthesis of 2,5-furandicarboxylic acid from biomass-derived raw materials[J]. Chemical Industry and Engineering Progress, 2021, 40(2): 1008-1017.
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