生物质衍生物催化转化制喷气燃料组分的研究进展

doi:10.16085/j.issn.1000-6613.2016.09.015

摘要/Abstract

摘要： 随着我国航空业的不断发展，对喷气燃料的需求也日益增加。在石油危机和环境问题日益严重的背景下，如何可再生地利用生物质资源生产出喷气燃料组分来部分代替传统炼油得到的喷气燃料受到相关科研人员密切关注。从催化的层面入手，本文回顾了利用催化化学方法将生物质衍生物催化制备转化为喷气燃料组分的不同途径，介绍了合成高密度、高辛烷值等高品质喷气燃料组分的新型工艺路线，给出不同糖醇平台的优缺点，如：单官能团化合物平台工艺路线复杂，目的产物选择性低；糠醛和5-羟甲基糠醛平台、乙酰丙酸和γ-戊内酯平台、2-甲基呋喃平台目前工艺较为成熟，已实现工业化。在此基础上，总结分析了目前以糖醇平台催化制备喷气燃料组分的研究状况，指出解决单糖到平台化合物大规模生产问题和研发高效、水热稳定性好的加氢脱氧催化剂可能是未来该领域研究的重点。

关键词: 生物质衍生物, 平台化合物, 催化转化, 喷气燃料组分

Abstract: With the existence of an oil crisis and environmental problems,more attention is being paid to methods for producing jet fuel components from biomass instead of traditional fossil resources. Starting from the level of catalysis,this paper reviews several technologies for producing jet fuel range alkanes from biomass-derivatives by catalysis,especially some creative technologies for obtaining high-quality jet fuel range alkanes. Then,the advantages and disadvantages of different technologies were discussed. For example,compared to the complicated routes of mono-functional compound platforms,those of the furfural platform and γ-valerolactone platform got higher conversion rate and selectivity and had achieved industrialization. In conclusion,the platform chemicals production and stable catalysts preparation are highly expected to be the subject of future research in this field.

Key words: biomass-derivatives, platform chemicals, catalytic conversion, jet fuel range alkanes

中图分类号:

O643

闫瑞, 郭勇, 李杨, 陶志平. 生物质衍生物催化转化制喷气燃料组分的研究进展[J]. 化工进展, 2016, 35(09): 2735-2745.

YAN Rui, GUO Yong, LI Yang, TAO Zhiping. Progress in catalytic production of jet fuel range alkanes from biomass-derivatives[J]. Chemical Industry and Engineering Progree, 2016, 35(09): 2735-2745.

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