固定源废气处理的催化剂涂覆工艺研究进展

doi:10.16085/j.issn.1000-6613.2019-2122

摘要/Abstract

摘要：

由工业固定源排放的NO_x和挥发性有机物（VOCs）是大气复合污染物的重要前体物质。整体式催化剂常被用于脱除NO_x和VOCs。涂覆法是可工业化大规模生产整体式催化剂的工艺之一，具有活性组分用量少、生产成本低的优点，此工艺被广泛用于固定源废气处理的催化剂制备领域。但是由于高通量烟气的冲刷会造成表面活性组分损失和寿命降低，限制其应用，所以在设计催化剂的过程中不但需要关注催化剂涂层的高活性，还需要重点考察其耐磨损性。本文综述了国内外用于固定源废气处理整体式催化剂涂覆工艺的研究进展，主要分析了预处理方法对蜂窝陶瓷载体物理化学性质的影响；重点综述了蜂窝陶瓷负载催化剂活性组分的常规涂覆方法，分为间接涂覆法和直接涂覆法，进一步对间接涂覆法的第二载体涂层进行分类探讨，简述了直接涂覆法的浆料配方及工艺参数对涂层性能的影响，然后对两种涂覆工艺的优缺点进行论述，最后总结了整体式催化剂在固定源废气（NO_x和VOCs）处理领域的相关应用。

关键词: 整体器件, 催化剂, 制备, 涂覆工艺, 氮氧化物, 挥发性有机物

Abstract:

NO_x and VOCs emitted from industrial fixed sources are important precursors of atmospheric composite pollutants. Monolithic catalysts are often used to remove NO_x and VOCs. The coating method is one of the large-scale production processes of monolithic catalysts. It has the advantages of less active components without generation of a large amount of catalyst waste and low production costs. This process is widely used in the preparation of catalyst for stationary source exhaust gas treatment. Because the flushing of high-throughput flue gas will cause the loss of surface active components of the catalysis and reduce its life, which limits its application in fixed source exhaust gas treatment. The preparation of monolithic catalyst by the coating process not only needs to pay attention to the high catalyst activity and the abrasion resistance of the coating. The research progress of monolithic catalyst coating processes was summarized and discussed. The influence of pretreatment methods on the physical and chemical properties of honeycomb ceramic support was mainly analyzed. The conventional coating methods for active components of honeycomb ceramic supported catalysts were summarized, which were divided into indirect coating method and direct coating method. For the indirect coating method, the second carrier coating was further classified. For the direct coating method, the effects of slurry formulation and process parameters on coating performance are briefly described. The advantages and disadvantages of the two coating processes are also discussed. Finally, the applications of monolithic catalyst in the field of fixed source exhaust gas (NO_x and VOCs) treatment were introduced.

Key words: monolith, catalyst, preparation, wash-coating, nitrogen oxides (NO_x), volatile organic compounds (VOCs)

中图分类号:

X511

赵春林, 马子然, 王宝冬, 李歌, 王红妍, 周佳丽, 路光杰, 肖雨亭, 杨建辉, 陆金丰. 固定源废气处理的催化剂涂覆工艺研究进展[J]. 化工进展, 2020, 39(10): 4015-4023.

Chunlin ZHAO, Ziran MA, Baodong WANG, Ge LI, Hongyan WANG, Jiali ZHOU, Guangjie LU, Yuting XIAO, Jianhui YANG, Jinfeng LU. Research progress of catalyst coating process for exhaust gas treatment from fixed source[J]. Chemical Industry and Engineering Progress, 2020, 39(10): 4015-4023.

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