化工进展 ›› 2018, Vol. 37 ›› Issue (03): 1037-1046.DOI: 10.16085/j.issn.1000-6613.2017-1038

• 材料科学与技术 • 上一篇    下一篇

基于水通道蛋白的水处理仿生膜研究进展

顾正阳1, 龚超1, 杨望臻1, 于水利1, 姚启翰2   

  1. 1 同济大学环境科学与工程学院, 污染控制与资源化研究国家重点实验室, 上海 200092;
    2 湖南大学土木工程学院市政工程系, 湖南 长沙 410082
  • 收稿日期:2017-06-01 修回日期:2017-09-07 出版日期:2018-03-05 发布日期:2018-03-05
  • 通讯作者: 于水利,教授,主要研究膜分离技术在饮用水处理中的应用。
  • 作者简介:顾正阳(1993-),男,博士研究生,E-mail:guzhengyang@tongji.edu.cn。
  • 基金资助:
    国家自然科学基金项目(51578390)。

Recent progress on AQP based biomimetic membranes for water treatment

GU Zhengyang1, GONG Chao1, YANG Wangzhen1, YU Shuili1, YAO Qihan2   

  1. 1 State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science & Engineering, Tongji University, Shanghai 200092, China;
    2 Department of Municipal Engineering, College of Civil Engineering, Hunan Univisity, Changsha 410082, Hunan, China
  • Received:2017-06-01 Revised:2017-09-07 Online:2018-03-05 Published:2018-03-05

摘要: 膜分离技术目前已广泛应用于饮用水净化、污废水处理和海水淡化等各领域。传统的膜分离技术普遍存在水通量低和污染物截留率低等缺陷,而水通道蛋白(AQP)由于对水分子具有极高的选择渗透性,因此将水通道蛋白嵌入到传统的水处理膜中,可使制得的仿生膜发挥水通道蛋白的优势而具有更高的水通量及脱盐率。通过对近年来水通道蛋白仿生膜的相关研究进行归纳,介绍了水通道蛋白的分子结构和特异性透过功能,对各类仿生膜的制备方法及膜处理性能进行了总结和比较。最后,指出当前仿生膜技术存在机械强度差、化学性质不稳定及膜制备面积小等缺陷,并提出今后在提高仿生膜上AQP分子稳定性的同时应开发新型的膜制备技术和水通道材料,为制备高性能的仿生膜提供新的思路。

关键词: 水通道蛋白, 仿生膜, 水通量, 过滤, 制备, 脱盐

Abstract: Membrane separation technologies have been widely applied in drinking water purification,waste water treatment,seawater desalination,and many other fields. Traditional membrane technologies,such as reverse osmosis(RO) and ultrafiltration(UF),have gained rapid development but are still limited due to their low water flux or low salt rejection rate. Aquaporin(AQP),one kind of protein vastly existed in cell membranes,has special "water channels" which only allow water molecules to pass through but reject all the other molecules and ions. Thus,when incorporating AQPs into traditional membranes,the produced biomimetic membranes could exert AQP's superiorities and obtain the properties of enhanced water flux and desalination rate. This paper introduced the structure and fast water transport mechanism of aquaporins,then generalized different AQP based biomimetic membrane preparation methods and compared the performance improvements of these membranes. Limitations of current biomimetic membranes were also addressed,such as difficulty to scale up and instability under extreme conditions. Finally,ideas of developing new AQP loading techniques and fabricating new "water channel" materials were presented.

Key words: aquaporin (AQP), biomimetic membrane, water flux, filtration, preparation, desalination

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