生物柴油副产物甘油的分离提纯工艺进展

doi:10.16085/j.issn.1000-6613.2017-0526

化工进展 ›› 2017, Vol. 36 ›› Issue (S1): 155-160.DOI: 10.16085/j.issn.1000-6613.2017-0526

生物柴油副产物甘油的分离提纯工艺进展

孙启梅, 张霖, 王领民, 王崇辉

中国石油化工股份有限公司抚顺石油化工研究院, 辽宁抚顺 113001

收稿日期:2017-03-24 修回日期:2017-06-08 出版日期:2017-12-31 发布日期:2017-12-13
通讯作者: 孙启梅(1987-),女,硕士,工程师,从事生物化工研究。
作者简介:孙启梅(1987-),女,硕士,工程师,从事生物化工研究。E-mail:sunqimei.fshy@sinopec.com。

Development and progress of separation and purification technology of glycerol as a by-product of biodiesel

SUN Qimei, ZHANG Lin, WANG Lingmin, WANG Chonghui

Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun 113001, Liaoning, China

Received:2017-03-24 Revised:2017-06-08 Online:2017-12-31 Published:2017-12-13

摘要/Abstract

摘要： 生物柴油产业的快速发展，使得副产物甘油的产量激增，而当前食品、化妆品、医药等行业对甘油都有着广泛的需求，但它们对甘油的纯度要求很较高。这就需要对生物柴油副产物甘油进行精制提纯。通常经酯交换反应得到的生物柴油，通过简单的离心或沉降过程即可得到粗甘油，其中含有催化剂、色素、盐、皂、脂肪酸等杂质，再加上甘油本身黏度大、沸点高，且是热敏性的物质，使得其分离精制过程变得很困难。本文介绍了现有文献中报道的从生物柴油中提纯精制甘油的各种工艺，主要有絮凝、乙醇结晶、草酸钠络合、离子交换、膜分离、减压蒸馏或分子蒸馏、生物吸附和反应络合等精制提纯工艺。并提出将两种或多种精制提纯技术相结合，将会是一种高效的甘油精制方案。

关键词: 生物柴油, 甘油, 提纯

Abstract: As the rapid development of biodiesel industry,the output of its by-product glycerol has increased sharply.High purity of glycerol has a great demand for food industry,domestic industry and pharmaceutical industry.This need a refine process to purify glycerol as a by-product of biodiesel.Usually,biodiesel after transesterification process can be centrifuged or settled to obtain unrefined glycerol.It consists of glycerol and the other impurities,such as the catalyst,coloring matters,salts,soaps,fatty acid.Moreover,glycerol has a larger viscosity and a higher boiling point,and it is also a heat-sensitive matter.All those made it difficult to separate and purify glycerol.In this paper,we give a brief introduction of a variety of glycerol purification process that has been reported in the literature,including flocculation,ethanol recrystallization,Sodium oxalate complex,ion exchange,membrane separation,reduced pressure distillation or molecular distillation,biosorption,reaction complex,and so on.Integrating one purification process with two or more processes will be a efficient project for purifying glycerol from biodiesel.

Key words: biodiesel, glycerol, purification

中图分类号:

TQ923

孙启梅, 张霖, 王领民, 王崇辉. 生物柴油副产物甘油的分离提纯工艺进展[J]. 化工进展, 2017, 36(S1): 155-160.

SUN Qimei, ZHANG Lin, WANG Lingmin, WANG Chonghui. Development and progress of separation and purification technology of glycerol as a by-product of biodiesel[J]. Chemical Industry and Engineering Progress, 2017, 36(S1): 155-160.

参考文献

[1] WLISON E K.Biodiesel revs up:Fuel made from vegetable oil leads the pack of alternatives to petroleum products[J]. Chem.Eng.News,2002,80:46-49.
[2] KONGJAO S,DAMRONGLERD S,HUNSOM M. Purification of crude glycerol derived from waste used-oil methyl ester plant[J]. Korean J.Chem.Eng.,2010,27(3):944-949.
[3] 钱俊峰,云志.双液相萃取棉籽油制备生物柴油副产物甘油的精制[J].粮油加工,2008(10):63-67.
[4] 杨凯华,蒋剑春,聂晓安,等.生物柴油的制备及其副产物粗甘油分离与精制工艺的研究[J].生物质化学工程,2006,40(1):1-4.
[5] ADDISON K.Separating glycerine/FFAs[M/OL]. Hongkong:Journey to Forever,2006[2011-03-12]. http://journeyforever.org/biodiesel_glycerin.html
[6] 黄艳芹.生物柴油副产物——甘油精制工艺优化研究[J].新乡学院学报(自然科学版),2012,29(4):329-331.
[7] 郝一男,王喜明,丁立军.文冠果油生物柴油副产物粗甘油的精制[J].中国油脂,2011,36(11):80-82.
[8] BROCKMANN R,JEROMIN L,JOHANNISBAUER W,et al. Glycerol distillation process:US4655879[P]. 1987-04-07.
[9] 邬国英,林西平,巫淼鑫,等.制备生物柴油的副产物甘油分离与精制工艺的研究[J].江苏工业学院学报,2003,15(4):17-19.
[10] IKUYA N,SHIGEO O,KAZUO M.Production of high-purity diglycerol:JP 2169536A2[P].1990-06-29.
[11] 王治敏,陆向红,胡立松,等.从生物柴油副产物中提纯甘油的预处理实验[J].太阳能学报,2013,34(8):1458-1462.
[12] 刘妍,罗艳丹,钟南京.生物柴油副产物甘油的提纯研究[J].油脂工程,2015,12:35-37.
[13] 杨丽.黄连木籽油制备生物柴油副产物甘油的分离与精制[D].郑州:郑州大学,2009.
[14] 谭艳来,欧仕益,汪勇,等.生物柴油副产物甘油精制工艺研究[J].中国油脂,2007,32(5):44-46.
[15] 敖红伟,王淑波,廖克俭,等.棕榈油制生物柴油副产物甘油精制工艺研究[J].油脂工程,2009(4):70-72.
[16] 史荣炳,史荣荐,孙洪如,等.一种生物柴油副产品粗甘油精制工艺:102952000A[P].2013-03-06.
[17] WAN N R W I,RAMLI Z A C,ISMAIL M,et al. Recovery and purification of crude glycerol from vegetable oil transesterification[J].Separation & Purification Reviews,2015,44(3):250-267.
[18] 苏有勇,王华,包桂蓉,等.生物柴油副产物粗甘油精制工艺研究[J].中国油脂,2008,33(12):58-60.
[19] 陆向红,计建炳,杨运财,等.一种生物柴油副产物油脂的精制方法:101481297A[P].2009-07-15.
[20] 余建,宋紧东,徐忠民,等.一种粗甘油精制及副产物回收工艺:102229521A[P].2011-11-02.
[21] CARMONA M,VALVERDE J,PEREZ A.Purification of glycerol/water solutions from biodiesel synthesis by ion exchange:sodium removal Part 1[J]. J. Chem. Technol. Biotech.,2009,84(5):738-744.
[22] ARESKI R.Method for purification of glycerol:US7667081B2[P].2010-02-23.
[23] HE H Y,GUO X,ZHU S L.Comparison of membrane extraction with traditional extraction methods for biodiesel production[J].Journal of the American Oil Chemists' Society,2006,83(5):457-460.
[24] BUENEMANN T,OUDEJANS J C,GAMBA P,et al. Process for purifying crude glycerol:US4990695[P]. 1991-02-05.
[25] GOMES M C S,PEREIRA N C,DE BARROS S T D.Separation of biodiesel and glycerol using ceramic membranes[J]. J. Membrane Sci.,2010,352(1-2):271-276.
[26] SALEH J,TREMBLAY A Y,DUBE M A.Glycerol removal from biodiesel using membrane separation technology[J].Fuel,89(9):2260-2266.
[27] IGNACIO C A,ELISEO A M,JONATHAN F S C. Purification of glycerol from biodiesel production by sequential extraction monitored by ¹H NMR[J].Fuel Processing Technology,2015,132(1):99-104.
[28] MANN H,FAROUQ S M,MOHD A H,et al.A novel technique for separating glycerine from palm oil-based biodiesel using ionic liquids[J]. Fuel Processing Technology,2010,91(1):116-120.
[29] KO M K,LIAO P Y,LI S,et al.Production of partially refined waste glycerol:US 9469586 B2[P].2016-10-18.
[30] SAIFUDDIN N,REFAL H,KUMARAN P.Rapid purification of glycerol by-product from biodiesel production through combined process of microwave assisted acidification and adsorption via chitosan immobilized[J].Research Journal of Applied Sciences Engineering and Technology,2013,7(3):593-602.
[31] 臧阳阳,陈磊,陈丽娜.一种改进的甘油生产工艺:105585423A[P].2016-05-18.
[32] LOURENCO W C F,MACRET R,CIELO J E.Process for the purification of crude glycerol:EP2475633A1[P].2012-07-28.
[33] EET Corporation,Glycerol purification.Website[EB/OL].[2009-05-01].http://www.eetcorp.com/heepm/glycerine.html.
[34] AILKENJ E.Purification of glycerin:US7126032 B1[P]. 2006-10-24.

生物柴油副产物甘油的分离提纯工艺进展

Development and progress of separation and purification technology of glycerol as a by-product of biodiesel

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	金鑫, 李玉姗, 解青青, 王梦雨, 夏星帆, 杨朝合. 多孔材料催化丙酮缩甘油合成研究进展[J]. 化工进展, 2023, 42(2): 731-743.
[2]	秦振芳, 廖日红, 马伟芳. 吸收-微藻法固定燃气电厂低浓度CO₂同步产油技术研究进展[J]. 化工进展, 2023, 42(1): 94-106.
[3]	岳瑶, 蒲梦凡, 王文瑞, 赵俭波, 曹辉. 聚天冬氨酸凝胶的制备及生物降解性[J]. 化工进展, 2022, 41(8): 4491-4497.
[4]	赵建兵, 杨丹, 舒原草, 朱俊波, 普仕萍, 宋晓丹, 刘守庆, 柴希娟, 李雪梅. Na₂CO₃/CF固体碱对菜籽油酯交换反应的催化性能[J]. 化工进展, 2022, 41(7): 3608-3614.
[5]	邹鹏程, 金光远, 李臻峰, 宋春芳, 韩太柏, 祝玉莲. 一种具有模式搅拌的微波反应釜内多物理场特性分析[J]. 化工进展, 2022, 41(5): 2301-2310.
[6]	陈丹阳, 朱建宇, 吴勤, 王自庆, 张金利. KF/MgO催化甘油和碳酸二甲酯酯交换合成甘油碳酸酯[J]. 化工进展, 2022, 41(4): 2082-2089.
[7]	马鑫, 王霜, 李法社, 张逸水, 蒋上. 生物柴油雾化特性仿真模拟及实验研究[J]. 化工进展, 2022, 41(2): 655-665.
[8]	朱长辉, 朱文超, 罗嘉, 田保河, 孙佳琳, 邹志云. 微波强化酯交换反应制备生物柴油研究进展[J]. 化工进展, 2022, 41(10): 5145-5154.
[9]	纪淑兰, 李迅, 王飞. 丝瓜络固定化米根霉催化光皮树油制备生物柴油[J]. 化工进展, 2022, 41(10): 5381-5389.
[10]	岳倩倩, 高李璟, 肖国民, 魏瑞平, 雷严. 生物柴油连续化生产设备及工艺进展[J]. 化工进展, 2021, 40(S2): 81-88.
[11]	邹帅, 李玉芹, 马怡然, 齐振华, 贾权威. 二乙醇胺强化胶球藻Coccomyxa subellipsoidea C-169固定CO₂和积累油脂[J]. 化工进展, 2021, 40(9): 5222-5230.
[12]	包文君, 李子富, 王雪梅, 高瑞岭, 程世昆, 门玉. 产油酵母利用廉价原料合成油脂的研究进展[J]. 化工进展, 2021, 40(5): 2484-2495.
[13]	柯义虎, 李景云, 刘春玲, 董文生, 刘海. Zn(Al)O复合氧化物负载Au催化剂催化氧化甘油制备1,3-二羟基丙酮[J]. 化工进展, 2021, 40(5): 2581-2592.
[14]	邹俊康, 鲍宗必, 杨启炜, 张治国, 任其龙, 杨亦文. 甘油磷酰胆碱的分析、制备及纯化研究进展[J]. 化工进展, 2021, 40(11): 6295-6304.
[15]	郭润楠, 李文博, 韩跃新. 天然石墨分选提纯及应用进展[J]. 化工进展, 2021, 40(11): 6155-6172.