钠离子电池碳基负极材料的研究进展

doi:10.16085/j.issn.1000-6613.2017-0315

化工进展 ›› 2017, Vol. 36 ›› Issue (11): 4106-4115.DOI: 10.16085/j.issn.1000-6613.2017-0315

钠离子电池碳基负极材料的研究进展

张英杰¹, 朱子翼¹, 董鹏¹, 赵少博¹, 章艳佳¹, 杨成云², 杨城沣², 韦克毅³, 李雪¹

1. 昆明理工大学, 锂离子电池及材料制备技术国家地方联合工程实验室, 云南省先进电池材料重点实验室, 云南昆明 650093;
2. 云南能投汇龙科技股份有限公司, 云南昆明 650093;
3. 云南中烟工业有限责任公司技术中心, 云南昆明 650093

收稿日期:2017-02-27 修回日期:2017-07-26 出版日期:2017-11-05 发布日期:2017-11-05
通讯作者: 李雪,博士,讲师,研究方向为先进二次电池及相关能源材料,包括锂离子电池和钠离子电池。
作者简介:张英杰(1963-),女,博士,教授,研究方向为新能源材料、电化学防护与电化学环保。E-mail:zyjkmust@126.com。
基金资助:
国家自然科学基金（51604132）及云南省省院、省校科技合作项目（2015IB025）。

Research progress of carbon-based anode materials for sodium ion batteries

ZHANG Yingjie¹, ZHU Ziyi¹, DONG Peng¹, ZHAO Shaobo¹, ZHANG Yanjia¹, YANG Chengyun², YANG Chengfeng², WEI Keyi³, LI Xue¹

1. National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology, Key Laboratory of Advanced Battery Materials of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, Yunnan, China;
2. Yunnan Energy Investment Heolo Technology Company Limited, Kunming 650093, Yunnan, China;
3. Research & Development Center, China Tobacco Yunnan Industrial Company Limited, Kunming 650093, Yunnan, China

Received:2017-02-27 Revised:2017-07-26 Online:2017-11-05 Published:2017-11-05

摘要/Abstract

摘要： 电极材料的研究开发是钠离子电池技术发展和应用的关键之一，碳基负极材料具有原料丰富、成本低廉、可逆容量较大及倍率性能良好等优点，备受国内外专家、学者的关注。本文系统综述了钠离子电池碳基负极材料的最新研究进展，就石墨类和非石墨类碳基负极材料的分类和掺杂改性研究进行了详细介绍。石墨类材料有石墨和石墨烯，非石墨类材料有软碳和硬碳；元素掺杂改性主要是以N和S为主，并分别阐述了各种碳基负极材料的电化学性能及可能的充放电机理。分析了目前碳基负极材料面临着首次库仑效率较低、电压滞后现象严重、循环稳定性能不佳等问题，未来的发展方向主要是增大碳基负极材料的碳层间距、结构的纳米化以及优化制备工艺，以确保循环稳定性及倍率性能的优异性。

关键词: 钠离子电池, 碳基负极材料, 掺杂改性, 电化学性能, 充放电机理

Abstract: The development of electrode materials is one of the key factors in the application of sodium ion batteries. Carbon-based anode materials have attracted the attention of experts and scholars at home and abroad because of their advantages of rich raw materials,low cost,high reversible capacity and good rate performance. In this paper,the recent research progress of the carbon-based anode materials for sodium ion batteries have been briefly reviewed,and the classification and doping modification of graphite and non-graphite carbon-based anode materials are described in detail. Graphite-based materials are graphite and graphene,while non-graphite-based materials are soft carbon and hard carbon and element doping modification is mainly N-and S-based. The electrochemical properties and the possible mechanism of the sodium storage process are discussed in detail as well. The future advances of carbon-based anode materials should mainly focus on improving the low efficiency of coulomb,the phenomenon of severe voltage hysteresis and poor cycle stability. The future modification direction is to increase the carbon layer spacing,reduce the structure into nanoscale and optimize the preparation process to ensure the high cyclical stability and excellent rate performance.

Key words: sodium ion battery, carbon-based anode materials, doping modification, electrochemical performance, charge/discharge mechanism

中图分类号:

TM911

张英杰, 朱子翼, 董鹏, 赵少博, 章艳佳, 杨成云, 杨城沣, 韦克毅, 李雪. 钠离子电池碳基负极材料的研究进展[J]. 化工进展, 2017, 36(11): 4106-4115.

ZHANG Yingjie, ZHU Ziyi, DONG Peng, ZHAO Shaobo, ZHANG Yanjia, YANG Chengyun, YANG Chengfeng, WEI Keyi, LI Xue. Research progress of carbon-based anode materials for sodium ion batteries[J]. Chemical Industry and Engineering Progress, 2017, 36(11): 4106-4115.

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钠离子电池碳基负极材料的研究进展

Research progress of carbon-based anode materials for sodium ion batteries

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