TiO2纳米管阵列的制备改性及应用研究进展

doi:10.16085/j.issn.1000-6613.2016.s1.031

摘要/Abstract

摘要： TiO₂纳米管阵列作为一种新型的三维立体纳米材料,因其大的比表面积及特殊的几何结构而受到了广泛的关注与研究。本文回顾了近年来阳极氧化法在Ti基底上原位生成TiO₂纳米管阵列所用电解液的发展趋势,介绍了TiO₂纳米管阵列的特性,如晶型结构、光学和电学特性以及催化活性,阐述了TiO₂纳米管阵列的金属离子掺杂、非金属离子掺杂、金属沉积、导电聚合物复合、半导体复合以及其他等多种改性手段,探讨了TiO₂纳米管阵列在光电催化降解污染物、光解水制氢、染料敏化太阳能电池和传感器以及其他多个领域的应用研究进展。最后,展望了TiO₂纳米管阵列的主要研究方向是对其形貌调控与表面改性等方面作进一步研究,以期为后续研究提供参考依据。

关键词: TiO₂ 纳米管阵列, 纳米材料, 制备, 合成, 改性, 应用

Abstract: TiO₂ nanotube arrays have attract much attention due to its novel three-dimensional structure, big surface areas and special geometric structure.In this review, TiO₂ nanotube arrays in situ grown on Ti substrate were fabricated by anodic oxidation and the development of electrolyte was summarized.The property of the TiO₂ nanotube arrays were introduced, including the crystal structure, optical property, electrical characteristics and the catalytic activity.Moreover, the modification of TiO₂ nanotube arrays was described in detail.The modification method contains metal ion doping, nonmetal ion doping, metal deposition, coupling with the conducting polymer, coupling with semiconductor and other modified approaches.The application in photoelectrocatalytic degradation of pollutions, photocatalytic water splitting, dye-sensitized solar cell, sensors and other fields were also inveatigated.Finally, the future studies on the morphology control and modification of TiO₂ nanotube arrays were proposed.

Key words: TiO₂ nanotube arrays, nanomaterials, preparation, synthesis, modification, application

中图分类号:

O649

武佳, 徐浩, 延卫. TiO₂纳米管阵列的制备改性及应用研究进展[J]. 化工进展, 2016, 35(S1): 188-194.

WU Jia, XU Hao, YAN Wei. Fabrication, modification of TiO₂ nanotube arrays and their research progress in application[J]. Chemical Industry and Engineering Progree, 2016, 35(S1): 188-194.

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TiO₂纳米管阵列的制备改性及应用研究进展

Fabrication, modification of TiO₂ nanotube arrays and their research progress in application

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