化工进展 ›› 2016, Vol. 35 ›› Issue (12): 3735-3745.DOI: 10.16085/j.issn.1000-6613.2016.12.002

• 化工过程与装备 • 上一篇    下一篇

微波场强化化工分离过程研究进展

李洪1,2, 崔俊杰1, 李鑫钢1,2,3, 高鑫1,2   

  1. 1 天津大学化工学院, 天津 300072;
    2 精馏技术国家工程研究中心, 天津 300072;
    3 天津化学化工协同创新中心, 天津 300072
  • 收稿日期:2016-05-03 修回日期:2016-09-02 出版日期:2016-12-05 发布日期:2016-12-05
  • 通讯作者: 高鑫,副教授,主要从事传质与分离工程、化工分离过程强化及非常规化石能源炼制方面的研究工作。E-mail:gaoxin@tju.edu.cn。
  • 作者简介:李洪(1980-),女,特聘研究员。
  • 基金资助:

    国家自然科学基金项目(21306128)。

Recent developments in microwave-assisted chemical separation processes

LI Hong1,2, CUI Junjie1, LI Xingang1,2,3, GAO Xin1,2   

  1. 1 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
    2 National Engineering Research Center of Distillation Technology, Tianjin 300072, China;
    3 Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072, China
  • Received:2016-05-03 Revised:2016-09-02 Online:2016-12-05 Published:2016-12-05

摘要: 优化化工分离技术、实现化工分离过程的节能减排,一直是化工分离过程研究的热门课题。近年来,微波场强化分离过程的研究非常活跃。本文阐述了微波对物质的作用机理以及微波加热较普通加热的优势与特点;系统介绍了微波场在萃取、精馏、干燥、脱附/吸附、蒸馏和反应精馏等分离过程的强化效果和应用进展,并分析总结了微波场在这些分离过程中的强化机理,分析表明将微波应用于化工分离过程具有加热速度快、产品质量高、耗能低和易于控制等特点;同时指出微波在分离过程特别是蒸馏/蒸发和反应精馏领域研究的欠缺,提出对于微波是否对蒸馏/蒸发或反应精馏过程具有强化作用还需要大量的实验验证和相应的理论支撑;最后本文对微波在分离领域的发展作了分析与展望。

关键词: 微波, 分离, 过程强化, 萃取, 蒸馏

Abstract: It has been a hot topic in the study of chemical separation process to strengthen the chemical separation technology and to realize the energy conservation and emission reduction in the separation process. The study of separation processes enhanced by microwave field is very active in recent years. In this paper,the mechanism of microwave on matters were explained,and the advantages and characteristics of microwave heating compared with conventional heating were discussed. The strengthening effects and application progress of microwave field in extraction,drying,desorption/adsorption,distillation and reactive distillation separation process were introduced systematically,and the strengthening mechanisms of microwave field in these separation processes were summarized and analyzed. The analysis showed that the application of microwave in chemical separation process had the characteristics of high heating speed,high product quality,low energy consumption and easy-control production process. Moreover,the lack of research of microwave in the field of distillation/evaporation and reactive distillation was pointed out. In addition,this paper suggested that a lot of experiments and the corresponding theoretical support were needed to verify whether the microwave was beneficial to the distillation process or reactive distillation process.Meanwhile,the development of microwave in the field of separation was analyzed and forecasted.

Key words: microwave, separation, process intensification, extraction, distillation

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