化工进展 ›› 2015, Vol. 34 ›› Issue (02): 447-455,478.DOI: 10.16085/j.issn.1000-6613.2015.02.022

• 材料科学与技术 • 上一篇    下一篇

超双疏表面的构筑及研究进展

辛忠, 张雯斐   

  1. 华东理工大学化工学院化学工程联合国家重点实验室, 上海 200237
  • 收稿日期:2014-04-16 修回日期:2014-06-17 出版日期:2015-02-05 发布日期:2015-02-05
  • 通讯作者: 辛忠(1962-),男,教授,博士生导师,主要从事功能性微(纳)米尺寸有机硅材料的制备技术及应用研究、功能性高分子材料添加剂和聚烯烃添加剂的设计合成及应用研究。E-mail:xzh@ecust.edu.cn
  • 基金资助:
    上海市科委优秀学科带头人基金(10XD1401500)、国家自然科学基金联合基金(U1162110)及教育部中央高校探索研究基金(222201314051)项目

Research progress of fabrication and application of superamphiphobic surface

XIN Zhong, ZHANG Wenfei   

  1. State Key Laboratary of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
  • Received:2014-04-16 Revised:2014-06-17 Online:2015-02-05 Published:2015-02-05

摘要: 超双疏表面拒水又拒油的特性指导着油水共存环境下材料表面的设计。本文概述了其构筑方法包括溶胶-凝胶法、自组装法、相分离法等自下而上的方法,以及刻蚀法、纳米压印法等自上而下的方法,并指出后者相比前者更易于构筑有利于形成超双疏表面的倒悬结构,但往往存在制备过程繁琐的问题。此外,文中简述了超双疏特性主要用于构建油污环境下的自清洁表面,提高表面抗黏附能力,实现油水环境下的减阻作用等,并提出可进一步探索该特性在微流控管道设计领域的应用。最后展望了该领域未来的研究重点是探索简易的制备方法来构筑超双疏表面,在确保良好超双疏特性的前提下提高其耐久性,以满足在实际环境中的应用。

关键词: 超双疏, 表面, 加工制造, 纳米结构, 微尺度

Abstract: Superamphiphobic surface with water and oil repellent properties guides the design of surface under oil and/or water environment. In this review,we focus on the fabrication and application of superamphiphobic surface. Primarily,we highlight the bottom-up methods like sol-gel method,self-assembly and phase separation,and the top-down methods like etching process and nanoimprint lithography technology for the fabrication of superamphiphobic surface. The top-down methods are more efficient to fabricate an overhang structure which makes the superamphiphobic property stable,while the processes tend to be complex. Next,we propose hat these unique surfaces are promising in self-cleaning,anti-adhesion,anti-corrosion and drag reduction under oil and/or water environment and the application to microfluidic device should be further explored. Additionally,long durability of superamphiphobic surface in practical application is important. Finally,we prospect that research emphasis of superamphiphobic surface is to prepare superamphiphobic surface with enhanced durability to fulfill practical applications by an easier method.

Key words: superamphiphobicity, surface, fabrication, nanostructure, microscale

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