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Table of Content
25 December 2007, Volume 26 Issue 12
    进展与述评
    Progress in research of p-n type semiconductor composite photocatalysts
    WU Huanwen,ZHANG Ning,ZHONG Jinlian,HONG Sanguo
    2007, 26(12):  1669. 
    Abstract ( 2021 )  
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    The principle of photocatalysis of p-n type semiconductor composite photocatalysts and its current research progress are reviewed. Based on the p-type semiconductors,the catalysts are divided into four types:CoOx-n-type,CuxO-n-type,NiOx-n-type,and other p-n type semiconductor materials,such as p-n heterojunction photocatalysts and photocatalytical diodes. Finally,some problems in the study of p-n type semiconductor composite photocatalysts are indicated and a brief discussion about the future research is given.
    Progress in supported catalyst for hydroformylation of olefins
    MA Zhanhua,LIU Xuenuan,YANG Guohua,LIU Chenguang
    2007, 26(12):  1675. 
    Abstract ( 1679 )  
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    In this paper,the recent developments of supported catalysts for hydroformylation of olefins are reviewed based on the immobilization modes and varieties of the carrier. Particular attention is focused on the properties and features of the catalysts supported on polymers,zeolites,SiO2 and activated carbon. Some existing problems in the use of supported catalysts and development prospects are analyzed.
    Progress of extractive desulfurization technology with ionic liquids
    XIANG Xiaoyan,LIN Jinqing
    2007, 26(12):  1681. 
    Abstract ( 1632 )  
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    The recent research and application of ionic liquids (ILs) in extractive desulfurization (EDS) are summarized and discussed. The extraction mechanism and the effects on desulfurization rate of such factors as structures of ILs,sulfide types,temperature,extraction time,solvent-oil ratio are introduced respectively. Several probable regeneration methods of ILs are compared and the prospect of ILs in EDS is predicted. It is proposed that the prime task is to develop and synthesize ILs at a lower price,higher sulfide selectivity. In addition,it is essential to raise the recycling utilization ratio of ILs,develop combined desulfurization technologies,complete various basic data so as to accelerate industrial application of ILs.
    New progress on research of catalysts for synthesis of bisphenol A
    MA Yi,CHANG Chun,LI Hongliang
    2007, 26(12):  1686. 
    Abstract ( 2087 )  
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    The new progress of catalysts for bisphenol A synthesis is reviewed,which includes the modification of existing ion exchange resins,new-type catalysts such as molecular sieves,heteropoly acids,synthetical solid acid personally,ionic liquids,etc. Compared with ion exchange resins,mesoporous molecular sieves,heteropoly acids and ionic liquids show excellent catalytic performance. The existing problem and further research are indicated. The future development of catalysts is also discussed .
    Review of the development of application technologies of CL-20
    OU Yuxiang,MENG Zheng,LIU Jinquan
    2007, 26(12):  1690. 
    Abstract ( 1890 )  
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    The development of application technologies of CL-20 in the last two decades is reviewed,and the criterion which determines a military high energy compound’s practical applications is presented. The research achievements in composite explosives,solid rocket propellants and gun propellants are summarized and discussed. Most of these achievements were obtained during the end of the last century and the beginning of this century. Some composite explosives have overcome the shortcomings of the high sensitivity of CL-20 and greatly improved the power of the explosive formulas,such as PAX-11,PAX-12 and PAX-29. The solid rocket propellants containing CL-20 showed higher energy output and lower signature in spite of slightly higher sensitivity. The gun propellants containing CL-20 showed higher energy and the same sensitivity compared with the RDX gun propellants. It is believed that the research of CL-20 has turned into application stage from laboratory study stage. A great number of successful formulas related to CL-20 have been invented,and some of them could fulfill the use in weapon system.
    Characterization techniques for the morphology of supported catalyst and nascent polymer particles in olefin polymerization
    ZHENG Xuejing
    2007, 26(12):  1695. 
    Abstract ( 1673 )  
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    This paper reviews several techniques of characterizing the morphology of catalysts and nascent polyolefin particles,including ordinary optical microscopy,scanning electron microscope,transmission electron microscope,laser scanning confocal fluorescence microscope,video microscope and Raman spectroscope/microscope. The advantages and disadvantages of each technique are analyzed.
    From noise to information-some applications of acoustic emission techniques in process industries
    CAO Yijia,LIU Wei,JIANG Xiaojing,WANG Jingdai,YANG Yongrong
    2007, 26(12):  1702. 
    Abstract ( 1622 )  
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    The application of acoustic emission (AE) technology in the multiphase system of process industries is reviewed and its basic principles,generic data path flow-sheet and equipment setup are presented. The interaction between sampling frequency and the flexibility of equipment as well as data regression methods in AE technology are presented. The uses of AE technology in the control of catalyst automatic feed unit (gas-solid) and dew point control in fluidized beds (gas-liquid) were studied,and the results show that acoustic measurement techniques are bound to have an even broader prospect for development in liquid system. Compared with other methods,AE technology has the advantages of convenience in implementation,online measurement,and environmental friendliness with fairly good accuracy.
    Progress of carbon dioxide removal from the recycle gas of Fischer-Tropsch synthesis
    WANG Xiangyun
    2007, 26(12):  1708. 
    Abstract ( 1641 )  
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    A new technology of carbon dioxide removal from the recycle gas of Fischer-Tropsch synthesis is introduced. It has the advantages of low hydrocarbon loss,stable solution,low heat consumption for solution desorption. The heat consumption for solution desorption is reduced by 30% against the conventional technology.
    Application of potassium permanganate and composite potassium permanganate in water treatment
    LI Xiang,WU Yaoguo,NIE Guoqing,LIU Zhitao
    2007, 26(12):  1712. 
    Abstract ( 2209 )  
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    This paper introduces the application of potassium permanganate,composite potassium permanganate and permanganate oxidation combined with other medicaments. Potassium permanganate and composite potassium permanganate have outstanding performance in removing the organic pollutants,algae and deodorization,color and turbidity,heavy metals,and advantages in enhanced disinfection. This oxidizer is highly efficient and economical. It is very promising in water treatment.
    Biofermented acetic acid and purification
    WANG Yali,HONG Housheng,ZANG Qingwen,LI Bo,ZHOU Haiyan
    2007, 26(12):  1717. 
    Abstract ( 1725 )  
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    This paper presents the fermentation technology of acetic acid from renewable resources and the separation methods of acetic acid - water solution. Acetic acid fermentation is reviewed mainly in terms of traditional fermentation and immobilization technology as well as submerged technology. The submerged technology plays an important role in acetic acid fermentation for its lower production cost,especially for producing high-strength acetic acid more than 220 g/L.Different ways for the separation of acetic acid-water solution by evaporation,membrane or extractive distillation as well as the combination of those methods for efficiently separation are introduced.
    Progress of lignin in biochemical engineering
    LI Xianfa,LUO Xuegang
    2007, 26(12):  1722. 
    Abstract ( 1681 )  
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    The recent research situation of lignin application in biochemical engineering is summarized,including lignin degradation and biopulping,organic wastewater disposal,preparation of chemical raw materials and application of industrial lignin in bio-fertilizer,bio-pharmacy,bio-adsorption material and food. In addition,the problems and difficulties involved are analyzed,and the means for expanding application of lignin in biochemical engineering are discussed.
    Research progress and high yield strategy of acetone-butanol fermentation
    JIN Xiaoqing,WANG Guilan,HE Bingfang
    2007, 26(12):  1727. 
    Abstract ( 1896 )  
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    Acetone-butanol fermentation is one of the thriving industrial fermentation processes. Its decline since the 1950s was caused by the availability of much cheaper feed stocks for chemical solvent synthesis in the petrochemical industry. With the exhaustion of petrochemical resources,acetone-butanol fermentation displays great economic benefits and strategic significance. In this paper,the recent research progress in acetone-butanol fermentation is reviewed in detail,including metabolic mechanism,improvement of producing strains and development of fermentation process. High yield strategies are presented to resolve the existing problems in acetone-butanol fermentation,such as screening high butanol-tolerance strains,screening producing strains with high proportion of butanol,high efficiency utilization of solvent-producing cells and coupling fermentation with efficient separation process with low energy consumption.
    Research and application of affix carbon composite (hybrid) phase change materials for thermal energy storage
    ZHAN Lizhi,LI Suping,ZHANG Zhengguo,FANG Xiaoming
    2007, 26(12):  1733. 
    Abstract ( 1926 )  
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    Phase change thermal energy storage materials have important applications in many fields for their advantages,such as high storage density,small temperature variation during phase change and good process controllability. However,low conductivity and liquid leakage after the change from solid state to liquid state restrict their use in application. Carbon materials,including graphite,carbon fibre,carbon foam and expanded graphite possess the properties of high conductivity,low density and good chemical stability. In order to increase the conductivity and enhance the performance of phase change materials,carbon-based composite (hybrid) phase change materials are prepared by adding the carbon materials into the phase change materials or blending the carbon materials with the phase change materials. In this paper,the research progress of the carbon-based composite (hybrid) phase change materials are reviewed. The expanded graphite-based composite phase change materials prepared by absorbing the organic phase change materials into the pores of expanded graphite with excellent absorbability,have the advantages of large storage density,high conductivity,good stability,low cost and without the problem of liquid leakage,and are considered as the most important carbon-based composite (hybrid) phase change materials in their future research and application.

    Preparation and application of polymer nanocomposites
    LENG Shiliang
    2007, 26(12):  1738. 
    Abstract ( 1612 )  
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    The properties of polymer-nanocomposites are presented and the preparation methods are classified into four categories:directly blending nano-units with polymer,in-situ synthesizing,in-situ synthesizing nano-units with monomer polymerizing and in-situ synthesizing synchronously in two phases. Finally the applications of polymer nanocomposites are introduced.
    研究开发
    Prediction of the settling of n-alkane in diesel by thermodynamic model
    LÜ Ya,CHEN Shufen
    2007, 26(12):  1743. 
    Abstract ( 1685 )  
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    Based on the characteristics of complicated composition in diesel,equation of state was applied to the description of the liquid phase,and regular solution theory was applied to the description of the solid phase for the sake of calculation of the compositions of the phases of liquid and solid in equilibrium. For the first time,non-n-alkane composition was regarded as a pseudo-component to simplify calculation. The thermodynamic model can successfully predict the temperature of wax appearance,which is close to the cloud point. The trend that every n-alkane in diesel was settled was studied by means of calculated compositions of solid phase and solid phase. The proportion of heavy n-alkane in solid was still small despite the stronger settling trend of heavy n-alkanes than light n-alkanes, because the proportion of heavy n-alkane in the original diesel was small. n-Eicosene,n-octadecane and n-docosane were most easily precipitated in diesel. The average carbon number of n-alkane in settled solid became less with increasing temperature. The phenomena that the settled waxy crystals entrapped significant amounts of liquid could be explained by calculated results obtained from thermodynamic model.
    Photocatalytic oxidation desulfurization with modified TiO2
    CHEN Ying,MA Jinli,LI Jinlian,WANG Baohui,WANG Xiunan
    2007, 26(12):  1749. 
    Abstract ( 1670 )  
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    Transition metal modified nano-titanium dioxide was prepared by the sol-gel method and characterized. Desulfurization of sulfur compounds in FCC naphtha with the prepared catalyst was investigated. The effects of TiO2 dosage,addition of tetrabutyl ammonium bromide, doping by Fe, Ni, Cu, Zn and reaction time on desulfurization performance were studied. Test results showed that under the conditions of using FCC naphtha,a volume ratio of naphtha to formic acid of 1∶1,7.5%(mol)Ni-TiO2 20mg,adding 5mg tetrabutyl ammonium bromide,illumination 3h,desulfurization rate was up to 98.4%.
    Extractive desulfurization properties of ionic liquid [bmim]BeS
    PIAO Xianglan,DU Xiao,ZHU Shenlin
    2007, 26(12):  1754. 
    Abstract ( 1642 )  
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    In this paper,water-soluble ionic liquid [bmim]BeS was used as extractant for sulfur compounds thiophene,2-methyl thiophene,benzothiophene,dibenzothiophene in simulated fuel and the feasible operation conditions were confirmed by extraction experiments. The results showed that the equlibrium of extraction was reached in three minutes;the operation temperature was 40~50 oC. By four stage extraction,the desulfurization ratio of the simulated system with thiophene,2-methyl thiophene,benzothiophene,dibenzothiophene was as high as 60%~90%.
    Flowability and characteristics of desulfurizing absorbent made by hydrated carbide slag and lime
    JIA Hanzhong,SONG Cunyi,YANG Xiaowei,HUANG Wentao
    2007, 26(12):  1758. 
    Abstract ( 1904 )  
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    Carbide slag was used as a highly effective low price desulfurizing absorbent,and the physical properties were analyzed. Carbide slag has a high CaO contents and high specific surface area. Hydrated carbide slag and lime were mixed,and the product had good flowability. At the mixing ratio of 1∶1.4,the product had the best desulfurization performance. Under the same flue gas condition,the compound absorbent had better desulfurization characteristics than other commonly used desulfurization agents of CaO and Ca(OH)2.
    Preparation and characterization of functional lysozyme loaded microspheres
    LIU Yuangang,ZHOU Changren
    2007, 26(12):  1761. 
    Abstract ( 1418 )  
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    To prepare lysozyme loaded microspheres with excellent properties for resolving the problem of degradation rate of chitosan in vivo,the preparation and characterization of lysozyme loaded microspheres were investigated from different angles systemically. The results showed that the yield was between 5.7% and 97.4%,the diameter was from 30µm to 100µm,the drug loading and the encapsulation efficiency were both ideal. Furthermore,the controlled release efficacy was obvious,the cumulative release ratio ranged from 20% to 70% in 16 days,which matched the first order kinetic model. Most importantly,the enzyme maintained its specific activity at above 90%.
    Properties of HNBR/OMMT nanocomposites
    GU Zheng,SONG Guojun,WANG Baojin,GAO Jianming
    2007, 26(12):  1767. 
    Abstract ( 1440 )  
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    The HNBR/OMMT nanocomposites were prepared by the melt intercalation method. The structure of the composites was studied by TEM and XRD. The behavior of stress-strain,aging resistance,solvent resistance and dynamic mechanical properties of HNBR/OMMT nanocomposites were investigated. The results of TEM and XRD showed that the OMMT layers were intercalated in the HNBR matrix. The composites possessed excellent aging resistance and solvent resistance,which was improved with increasing OMMT content. The dynamic mechanical analysis showed that Tg of HNBR/OMMT nanocomposites shifted to a higher temperature,and the nanocomposites had a good rolling resistance. The composites displayed better dynamic mechanical properties.
    Surface coating of BAM phosphor with MgF2
    SHEN Jingfei,WANG Haibo,HUANG Ruxi,ZHU Xianzhong,ZHU Yuehua
    2007, 26(12):  1771. 
    Abstract ( 1870 )  
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    In this work,BaMgAl10O17:Eu2+(BAM)phosphors were coated with MgF2 by the mechanical rubbing process. The surface morphology and the crystal structure were characterized by SEM,IR and XRD,respectively. The results indicated that the surface of BAM phosphors were evenly coated by MgF2 and the crystal structure of the coated BAM phosphors remained the same as the uncoated samples,i.e. after surface treatment,the luminance centre of Eu2+ did not shift,which still emitted wavelength of about 450 nm. The surface components of BAM phosphors coated with MgF2 were analyzed qualitatively by EDS. The emitting spectra of BAM phosphor particles coated with MgF2 and without coating were investigated under 254.7 nm excitation. The results demonstrated that the initial luminance of coated BAM phosphors was lower than the uncoated samples. But after roasting at 550℃ for 30min,the luminance degradation of the coated BAM phosphors was improved greatly. This method is simple,convenient and economical as compared with other methods.
    Amphiphilic of polycarboxylate superplasticizer
    MA Baoguo,TAN Hongbo,PAN Wei,LI Liang
    2007, 26(12):  1776. 
    Abstract ( 1353 )  
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    By introducing amphiphilic balance (P0),hydrophilic balance (k),and amphiphilic matching coefficient (l),the amphiphilic balance and comb-shaped copolymers of the polycarboxylate superplasticizer were investigated. The result showed that in the viscosity range (1.28-1.32),hydrophilicity and hydrophobicity of polycarboxylate superplasticizer of methacrylic acid showed a linear relationship:y=0.6327x+0.5078(R2=0.9535),amphiphilic balance P0=0.5078,hydrophilic balance k=0.6327. Under specific condition,the calculated matching coefficient could be used to predict the dispersing ability and monomer matching before synthesizing the copolymer.
    Synthesis of copolymer of waste poly(ethylene terephthalate)/dimer acid polyamide and analysis of process
    DU Ying,CAI Huabing,YANG Enhua,ZHANG Shoujun,GAO Guosheng
    2007, 26(12):  1779. 
    Abstract ( 1715 )  
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    The polyamide hot-melt adhesives for heat shrinkable joint closure,which can meet the demands of China telecommunication standard,were prepared with polyamide(010),waste poly(ethylene terephthalate) and glycol as primary raw materials. The reaction process,mechanisms and structure of products were investigated by using FTIR,DSC and SEM. The factors which affected the properties of copolymer were studied. The results showed that ester-amide exchange,alcoholysis and polycondensation were primary reactions. Ester-amide exchange was intensified if blending time was prolonged,resulting in higher softening point of product. The apparent viscosity of product increased with increasing polycondensation time or addition of glycol.
    Main factors influencing the thermal decomposition characteristics of medical waste
    MA Hongting,ZHANG Yufeng,DENG Na,GUO Xiaojuan,WEI Lili
    2007, 26(12):  1783. 
    Abstract ( 1655 )  
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    The main influence factors on thermal decomposition of medical waste,such as sample type,heating rate,sample mass,end-temperature and heat-insulation time,were investigated by using TG-DTA. The experiment indicated that different samples showed different parameters of initial,final and peak temperature as well as weight loss rate,which represented the thermal decomposition characteristics of medical waste. The heating rate and sample mass apparently affected the initial and final temperature but contributed little to peak temperature and weight loss rate. While the end-temperature and heat-insulation time mostly contributed to weight loss rate,i.e.,the higher the end-temperature and the longer heat-insulation time,the larger the weight loss rate. However,their effects on initial and finial temperatures were negligible.
    New method for synthesizing azobis(isobutylamidine hydrochloride)
    HU Zhiyong,CHENG Yuan,LI Lei,ZHANG Qiaoling
    2007, 26(12):  1790. 
    Abstract ( 1905 )  
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    The water soluble azo initiator—azobis(isobutylamidine hydrochloride)(AIBA) was synthesized using ABIN as material by base catalysis method. The effects of the preparation conditions,such as the concentration of ABIN-methanol solution,sodium methoxide dosage,ammonium chloride dosage,the effect of the first and second step reaction time on the yield of end product was investigated. Thermal decomposition reaction kinetics of AIBA was measured. The chemical structure of azobis(isobutylamidine hydrochloride) was characterized by Flourier-infrared spectra(FTIR) and 1HNMR.Finally,poly(vinyl acetate)(PVAc) was prepared using AIBA as initiator by emulsion polymerization. Meanwhile the relative molar mass of PVAc was tested by Gel Permission Chromatography(GPC). The experimental results indicate that:the thermal decomposition reaction grade of AIBA is 1,the decomposition activity energy is 67.39kJ/mol and the of PVAc reached 4949.
    Synthesis of 3-bromo-4-(trifluoromethoxy)phenol
    CHEN Binghe
    2007, 26(12):  1795. 
    Abstract ( 1592 )  
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    3-bromo-4-(trifluoromethoxy)phenol was synthesized from 2-(trifluoromethoxy)aniline by nitration to give 2-trifluoromethoxy-5-nitroaniline,which subjected to sandmeyer reaction,reduction and hydrolytic action with an overall yield of 26.2% and purity of 99%. The structure of the product was confirmed by MS and 1H NMR.
    应用技术
    Surplus activated sludge disposal by one-stage preheated autothermal themophilic aerobic digestion
    ZHANG Zhengrong,HUANG Shaobin,JIANG Ran,ZHANG Yongqing
    2007, 26(12):  1798. 
    Abstract ( 1764 )  
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    Surplus activated sludge was disposed of by a self-designed technology of one-stage preheated autothermal themophilic aerobic digestion. With the intermittent operating method,the influence of feed sludge concentration,agitation velocity,aeration and solid retention time (SRT) on sludge stability was investigated,and the effectiveness of sludge stability and harmlessness was evaluated,simultaneously,the dewatering function and pH were detected and analyzed. The results showed that when the total solid and VSS of feed sludge were 4.3%~6.4% and 33.4~44.1 g/L,agitation velocity was 100~110 r/min,aeration was 0.10~0.12 m3/h,SRT was 10 d,sludge digestion efficiency was the best,the temperature of inner tank was maintained at 54.5~56.8℃,the average removal rate of VSS reached 53.2%,the dehydrogenase activity (DHA) decreased by 74%,the inactivation rate of pathogens bacteria was 100%,the digested sludge met the class A biomass standard of US EPA. Under the best process conditions,sludge dewatering was worse,while pH increased,and this phenomenon was caused by cell lysis in the digestion process.
    Preparation and decolorization properties of activated carbon from sewage sludge
    FAN Xiaodan,ZHANG Xiangkai,YANG Hongying
    2007, 26(12):  1804. 
    Abstract ( 1673 )  
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    Activated carbon from sewage sludge was made by physical activation. The effects of pH,carbon amount,temperature and adsorption time on the decolorization of alkaline-black waste water and COD removal rate were investigated. The results showed good adsorption capacity of activated carbon from sewage sludge. The values of iodine and methylene blue were 254.36 mg/g and 20.26 mg/g,respectively. BET surface and total pore volume reached 25.1995 m2/g and 0.0399 m3/g,respectively. Then activated carbon from sewage sludge was used to adsorb alkaline-black. Decolorization by activated carbon from sewage sludge was similar to commercial activated carbon. The adsorption of alkaline-black followed Langmuir isotherm.
    Degradation behavior of printing and dyeing wastewater in ultrasonic airlift loop reactor
    LIU Yuenan,JIN Dong,LÜ Xiaoping,HAN Pingfang
    2007, 26(12):  1808. 
    Abstract ( 1591 )  
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    Ultrasonic airlift loop reactor (O3 for the reactant gas) shows potential,wide application for wastewater treatment. In this paper,ultrasonic airlift loop reactor was used to treat printing and dyeing waste water. The effects of reaction time,O3 flow rate and ultrasonic intensity on the decoloration rate and COD removal rate of printing and dyeing wastewater were investigated. The results showed that the decoloration rate and COD removal rate increased with reaction time. The optimum reaction time was 30 min. The decoloration rate and COD removal rate increased with increasing O3 flow rate. The optimum O3 flow rate was 200 L•h-1. The optimum ultrasonic intensity was 0.5 W·cm-2. Under this optimum experimental condition,the decoloration rate and COD removal rate increased to 74.8% and 35.6% respectively. It was concluded that the decoloration rate and COD removal rate of ultrasonic airlift loop reactor were better than the sum of separate use of O3 and ultrasound. The decoloration rate and COD removal rate increased by 23.0% and 6.5% respectively. Ultrasonic airlift loop reactor showed synergism of sonochemical advantage of ultrasonic and high gases transfer rate in the reactor.
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