Research progress in biorefinery and high value application of xylose

doi:10.16085/j.issn.1000-6613.2023-0947

Abstract

Abstract:

Xylose is the most abundant pentose in hemicellulose of lignocellulosic biomass, and its derivatives have a huge application market. Under the national“carbon peaking and carbon neutrality”strategic goal, the more green and efficient xylose refining process conforms to the national requirements of energy conservation, emission reduction and green cycle development, and can also effectively reduce the cost of xylose preparation and promote the high-value utilization of xylose. In this paper, the biological refining process of xylose is reviewed, and the development status and existing problems of different processes are analyzed. At the same time, the development of xylose hydrolysis and separation technology in recent years and the high-value applications of xylose in bio-based chemicals and bio-based materials are reviewed. Finally, suggestions for promoting the development of xylose biorefinery and prospects for high-value applications of xylose are proposed.

Key words: biorefinery, hemicellulose, xylose, high value application

摘要：

木糖作为木质纤维素生物质中半纤维素部分最丰富的戊糖，其衍生物具有巨大的应用市场。在国家“双碳”目标下，绿色高效的木糖炼制工艺不仅符合国家节能减排、绿色循环发展的要求，也能有效降低木糖制备成本并促进木糖的高值化利用。本文对木糖的生物炼制工艺进行了综述，并分析了不同工艺发展现状及存在的问题。同时综述了近年来木糖水解分离技术的进展以及木糖在生物基化学品和生物基材料的高值化应用，最后提出了促进木糖生物炼制发展的建议并对木糖高值化应用进行了展望。

关键词: 生物炼制, 半纤维素, 木糖, 高值化应用

CLC Number:

TQ353

SHU Gangwei, LIN Yucheng, ZHANG Weihong, ZHAO Shiqiang, ZHENG Xiaoyang, CHANG Chun. Research progress in biorefinery and high value application of xylose[J]. Chemical Industry and Engineering Progress, 2024, 43(7): 3798-3811.

舒岗韦, 林钰程, 张为宏, 赵世强, 郑晓阳, 常春. 木糖生物炼制与高值化应用研究进展[J]. 化工进展, 2024, 43(7): 3798-3811.

Figures/Tables 11

References 92

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名称	纤维素/%	半纤维素/%	木质素/%	参考文献
水葫芦	18~24	26~48	3~11	[4-5]
小麦秸秆	35~40.37	28~37.32	20~22.31	[17-18]
大麦壳	34.2	35.8	13.6~18.8	[19]
柳枝稷	45	31.4	12	[20]
毛竹	35~40	20~32	20~30	[21]
玉米芯	35.3~45	30.2~37	15.3~20.6	[22-23]
稻壳	27.9~35.4	11.8~29.4	15.3~19.9	[19]
玉米秸秆	30~39	21~26	17~25	[24-25]
杨木	49.8	24.4	23.3	[26]
巨菌草	41.3~43.9	22.9~25.8	17.3~18.6	[3,27]
核桃青皮	33.82	22.42	21.42	[28]

名称	纤维素/%	半纤维素/%	木质素/%	参考文献
水葫芦	18~24	26~48	3~11	[4-5]
小麦秸秆	35~40.37	28~37.32	20~22.31	[17-18]
大麦壳	34.2	35.8	13.6~18.8	[19]
柳枝稷	45	31.4	12	[20]
毛竹	35~40	20~32	20~30	[21]
玉米芯	35.3~45	30.2~37	15.3~20.6	[22-23]
稻壳	27.9~35.4	11.8~29.4	15.3~19.9	[19]
玉米秸秆	30~39	21~26	17~25	[24-25]
杨木	49.8	24.4	23.3	[26]
巨菌草	41.3~43.9	22.9~25.8	17.3~18.6	[3,27]
核桃青皮	33.82	22.42	21.42	[28]

原料	酸	酸浓度/%	温度/℃	物料比/g·mL^-1	时间/min	木糖质量产率/%	参考文献
玉米芯	硫酸	1.2	120	1∶10	90	86.36	[33]
油棕空壳	硫酸	6	120	1∶12.5	15	—	[34]
稻草	硝酸	1	121	1∶10	30	71.32	[35]
高粱秸秆	盐酸	6	122	1∶10	70	—	[36]
玉米秸秆	盐酸	0.7	120	1∶10	40	81.0	[37]
甘蔗渣	草酸	3.6	120	1∶20	10	93.2	[38]
玉米芯	草酸	1.2	130	1∶8	120	96.1	[6]
芒草	甲酸	88	100	1∶10	180	88.58	[39]
玉米芯	乙酸/乙酸钠	0.9	170	1∶10	60	74.8	[40]
杨木	乙酸/乙酸钠	0.9	170	—	60	55.7	[41]
玉米芯	丙酸	5	170	—	50	68.5	[42]

原料	酸	酸浓度/%	温度/℃	物料比/g·mL^-1	时间/min	木糖质量产率/%	参考文献
玉米芯	硫酸	1.2	120	1∶10	90	86.36	[33]
油棕空壳	硫酸	6	120	1∶12.5	15	—	[34]
稻草	硝酸	1	121	1∶10	30	71.32	[35]
高粱秸秆	盐酸	6	122	1∶10	70	—	[36]
玉米秸秆	盐酸	0.7	120	1∶10	40	81.0	[37]
甘蔗渣	草酸	3.6	120	1∶20	10	93.2	[38]
玉米芯	草酸	1.2	130	1∶8	120	96.1	[6]
芒草	甲酸	88	100	1∶10	180	88.58	[39]
玉米芯	乙酸/乙酸钠	0.9	170	1∶10	60	74.8	[40]
杨木	乙酸/乙酸钠	0.9	170	—	60	55.7	[41]
玉米芯	丙酸	5	170	—	50	68.5	[42]

原料	反应体系溶剂	固体酸/碳前体	催化剂负载量/g·g^-1	温度/℃	时间/min	木糖质量产率/%	参考文献
玉米芯	水	碳基固体酸/木质素磺酸钠	—	130	720	84.2	[43]
玉米芯	水	碳基固体酸/稻壳	0.5	160	180	48.65	[44]
玉米芯	水	碳基固体酸/微晶纤维素	0.25	140	360	78.1	[45]
木聚糖	水	碳基固体酸/微晶纤维素、棉纤维纸浆	—	150	240	58.8	[46]
桉木屑	水	碳基固体酸/蔗糖	0.05	200	5	40.7	[47]
玉米芯	水	磁性碳基固体酸/微晶纤维素	0.5	150	120	73.4	[8]
甘蔗渣	水	磁性碳基固体酸/微晶纤维素	1	170	10	91.62	[48]
玉米芯	水	SO₄^2-/TiO₂-ZrO₂/La³⁺	—	180	120	6.8	[49]
油茶果壳	水	碳基固体酸/油茶果壳	0.2	170	20	51.41	[50]
玉米芯	水	碳基固体酸/油茶果壳	0.2	160	20	41.04	[50]
甘蔗渣	水	碳基固体酸/油茶果壳	0.15	160	20	45.03	[50]
玉米秸秆	水	H-USY沸石	—	170	180	40	[51]
竹粉	水-甲苯	菱沸石（CHA）	—	170	120	—	[52]
玉米芯	水	ZrO₂	0.33	153	318	33	[53]
玉米芯	水	阳离子交换树脂（NKC-9）	5	131	42	47.7	[54]
甘蔗渣	水	硝酸浸渍的活性炭	0.03	120	—	50	[55]