Dehydration kinetics from xylose to furfural with ferric chloride as catalyst

doi:10.16085/j.issn.1000-6613.2015.01.019

Chemical Industry and Engineering Progree ›› 2015, Vol. 34 ›› Issue (1): 108-112.DOI: 10.16085/j.issn.1000-6613.2015.01.019

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Dehydration kinetics from xylose to furfural with ferric chloride as catalyst

MA Sai^1,2, LI Pingli^1,2, ZHU Tao^1,2, LIN Long^1,2

1 Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2 Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin 300072, China

Received:2014-06-20 Revised:2014-07-27 Online:2015-01-05 Published:2015-01-05

氯化铁催化木糖降解制备糠醛反应动力学

马赛^1,2, 李凭力^1,2, 朱涛^1,2, 林龙^1,2

1 天津大学化工学院化学工程研究所, 天津 300072;
2 天津市膜科学与海水淡化技术重点实验室, 天津 300072

通讯作者: 李凭力,副研究员,硕士生导师,主要研究方向为萃取精馏、海水淡化、生物质能源及膜技术。E-mail tdlpl@163.com。
作者简介:马赛(1988-),男,硕士研究生,研究方向为化工分离与生物质能源。

Abstract

Abstract: The dehydration kinetics from xylose to furfural with 0.1mol/L ferric chloride as catalyst was studied at temperature range from 443.15K to 483.15K. The kinetic model was established and tested, then the reaction rate constants of xylose dehydration, furfural degradation and condensation were obtained according to assumed kinetic model. The evaluated activation energies of these reactions were quantified via Arrhenius plots, and the values were 107.94kJ/mol, 65.86kJ/mol and 26.36kJ/mol, respectively. The experimental results showed that high temperature and short time were beneficial to improve the furfural yield, and the maximum furfural yield of 78% was obtained at 483.15K and 60min.

Key words: ferric chloride, xylose, furfural, reaction kinetics

摘要： 研究了温度在443.15～483.15K时0.1mol/L氯化铁催化木糖降解生成糠醛的反应动力学过程。首先建立并验证了反应的动力学模型,根据模型得到了木糖降解、糠醛降解和缩合反应的速率常数。由阿伦尼乌斯方程拟合得到其表观活化能分别为107.94kJ/mol、65.86 kJ/mol和26.36kJ/mol。结果表明,高温和较短反应时间有利于糠醛收率的提高,在反应温度483.15K、60min条件下,最大糠醛收率可达78%。

关键词: 氯化铁, 木糖, 糠醛, 反应动力学

CLC Number:

TQ013.2

MA Sai, LI Pingli, ZHU Tao, LIN Long. Dehydration kinetics from xylose to furfural with ferric chloride as catalyst[J]. Chemical Industry and Engineering Progree, 2015, 34(1): 108-112.

马赛, 李凭力, 朱涛, 林龙. 氯化铁催化木糖降解制备糠醛反应动力学[J]. 化工进展, 2015, 34(1): 108-112.

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Dehydration kinetics from xylose to furfural with ferric chloride as catalyst

氯化铁催化木糖降解制备糠醛反应动力学

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