Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (11): 5861-5870.DOI: 10.16085/j.issn.1000-6613.2022-2351
• Materials science and technology • Previous Articles
GUO Yaning1(), JI Junrong2, JIAO Yanhui1, ZHANG Qingnian2, ZHOU Zhou2, WEI Deen2, TONG Zhangfa1, LI Lishuo1()
Received:
2022-12-23
Revised:
2023-03-12
Online:
2023-12-15
Published:
2023-11-20
Contact:
LI Lishuo
郭亚宁1(), 季军荣2, 焦妍惠1, 张庆年2, 周洲2, 韦德恩2, 童张法1, 李立硕1()
通讯作者:
李立硕
作者简介:
郭亚宁(1999—),女,硕士研究生,研究方向为无机材料。E-mail:gyn426@126.com。
基金资助:
CLC Number:
GUO Yaning, JI Junrong, JIAO Yanhui, ZHANG Qingnian, ZHOU Zhou, WEI Deen, TONG Zhangfa, LI Lishuo. Preparation of calcium carbonate composite by mechanically activated of ground calcium carbonate and its adsorption properties on Cu2+ ions in solution[J]. Chemical Industry and Engineering Progress, 2023, 42(11): 5861-5870.
郭亚宁, 季军荣, 焦妍惠, 张庆年, 周洲, 韦德恩, 童张法, 李立硕. 机械活化重质碳酸钙制备复合碳酸钙及其对溶液中的Cu2+吸附性能[J]. 化工进展, 2023, 42(11): 5861-5870.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-2351
项目 | 不同碳酸钙 | ||||
---|---|---|---|---|---|
GCC | GCC10 | GCC-SP | CCC | PCC | |
比表面积/m2·g-1 | 4.25 | 8.40 | 6.92 | 20.50 | 35.20 |
项目 | 不同碳酸钙 | ||||
---|---|---|---|---|---|
GCC | GCC10 | GCC-SP | CCC | PCC | |
比表面积/m2·g-1 | 4.25 | 8.40 | 6.92 | 20.50 | 35.20 |
项目 | 不同碳酸钙 | ||||
---|---|---|---|---|---|
GCC | PCC | GCC-SP | GCC10 | CCC | |
吸附量/m2·g-1 | 2.23 | 36.10 | 56.54 | 62.05 | 65.53 |
项目 | 不同碳酸钙 | ||||
---|---|---|---|---|---|
GCC | PCC | GCC-SP | GCC10 | CCC | |
吸附量/m2·g-1 | 2.23 | 36.10 | 56.54 | 62.05 | 65.53 |
模型 | k/min-1 | q/mg·g-1 | R2 |
---|---|---|---|
伪一阶动力学模型 | 0.02987 | 62.50497 | 0.90587 |
伪二阶动力学模型 | 0.00067 | 66.87839 | 0.99190 |
模型 | k/min-1 | q/mg·g-1 | R2 |
---|---|---|---|
伪一阶动力学模型 | 0.02987 | 62.50497 | 0.90587 |
伪二阶动力学模型 | 0.00067 | 66.87839 | 0.99190 |
模型 | n | R2 | ||
---|---|---|---|---|
Langmuir模型 | 0.03012 | 76.21394 | — | 0.96225 |
Freundich模型 | 15.11485 | — | 3.69497 | 0.76707 |
Langmuir- Freundich 模型 | 0.03441 | 68.97473 | 0.68857 | 0.98725 |
模型 | n | R2 | ||
---|---|---|---|---|
Langmuir模型 | 0.03012 | 76.21394 | — | 0.96225 |
Freundich模型 | 15.11485 | — | 3.69497 | 0.76707 |
Langmuir- Freundich 模型 | 0.03441 | 68.97473 | 0.68857 | 0.98725 |
温度/K | ΔG/kJ·mol-1 | ΔHθ/kJ·mol-1 | ΔSθ/J·mol-1·K-1 | |
---|---|---|---|---|
298 | 2.66 | -6.58 | 43.60 | 170.01 |
300 | 2.93 | -7.31 | ||
303 | 3.23 | -8.13 | ||
308 | 3.38 | -8.66 |
温度/K | ΔG/kJ·mol-1 | ΔHθ/kJ·mol-1 | ΔSθ/J·mol-1·K-1 | |
---|---|---|---|---|
298 | 2.66 | -6.58 | 43.60 | 170.01 |
300 | 2.93 | -7.31 | ||
303 | 3.23 | -8.13 | ||
308 | 3.38 | -8.66 |
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