Preparation of calcium carbonate composite by mechanically activated of ground calcium carbonate and its adsorption properties on Cu2+ ions in solution

doi:10.16085/j.issn.1000-6613.2022-2351

Abstract

Abstract:

The surface modification of ground calcium carbonate (GCC) was accomplished by mechanically activated of GCC, sodium polyacrylate and nano calcium carbonate together and the CaCO₃ composite coated with nano calcium carbonate was applied to the adsorption of Cu²⁺ in solution. The adsorption properties were also investigated. The results showed that SEM and XRD analyses confirmed that the nano calcium carbonate was successfully coated on the surface of GCC. FTIR analysis found that the hydroxyl groups increased on the composite surface, and BET analysis indicated that the specific surface area of composite was 20.5m²/g with a mesoporous structure. The maximum adsorption capacity of composite calcium carbonate for Cu²⁺ was 65.5mg/g and the removal rate could reach 98%. The absorption process studies revealed that the adsorption kinetics followed the pseudo-second-order kinetic model and the adsorption isotherms followed the Langmuir-Freundich model, proving that the adsorption was dominated by ions exchange and was exothermal.

Key words: composite calcium carbonate, mechanical activation, adsorption, Cu²⁺ ions

摘要：

利用机械活化法对重质碳酸钙进行了纳米化表面改性，以聚丙烯酸钠和纳米碳酸钙为改性原料与重质碳酸钙进行混合研磨，成功制备了纳米碳酸钙包覆重质碳酸钙的复合钙，并考察了复合钙对溶液中的Cu²⁺的吸附性能。研究结果如下：扫描电子显微镜和X射线衍射仪分析证实了纳米碳酸钙包覆在重质碳酸钙表面，傅里叶变换红外光谱分析表明复合碳酸钙表面羟基明显增加，比表面积分析表明复合碳酸钙的比表面积为20.5m²/g，具有介孔结构。复合碳酸钙对Cu²⁺的最大吸附量为65.5mg/g，去除率可达98%。吸附性能研究表明，复合碳酸钙对Cu²⁺吸附动力学符合伪二阶动力学模型，等温吸附过程符合Langmuir-Freundich模型，证明吸附过程以离子交换反应为主，该过程为吸热反应。

关键词: 复合碳酸钙, 机械活化, 吸附, 二价铜离子

CLC Number:

TQ13

GUO Yaning, JI Junrong, JIAO Yanhui, ZHANG Qingnian, ZHOU Zhou, WEI Deen, TONG Zhangfa, LI Lishuo. Preparation of calcium carbonate composite by mechanically activated of ground calcium carbonate and its adsorption properties on Cu²⁺ ions in solution[J]. Chemical Industry and Engineering Progress, 2023, 42(11): 5861-5870.

郭亚宁, 季军荣, 焦妍惠, 张庆年, 周洲, 韦德恩, 童张法, 李立硕. 机械活化重质碳酸钙制备复合碳酸钙及其对溶液中的Cu²⁺吸附性能[J]. 化工进展, 2023, 42(11): 5861-5870.

Figures/Tables 18

项目	不同碳酸钙
项目	GCC	GCC10	GCC-SP	CCC	PCC
比表面积/m²·g^-1	4.25	8.40	6.92	20.50	35.20

项目	不同碳酸钙
项目	GCC	PCC	GCC-SP	GCC10	CCC
吸附量/m²·g^-1	2.23	36.10	56.54	62.05	65.53

模型	k/min^-1	q/mg·g^-1	R²
伪一阶动力学模型	0.02987	62.50497	0.90587
伪二阶动力学模型	0.00067	66.87839	0.99190

模型

$k L$ /L·min^-1

$k f$ /mg ⁿ⁺¹·L^-ⁿ ·g^-1

q e

R²

Langmuir- Freundich

模型

模型

$k L$ /L·min^-1

$k f$ /mg ⁿ⁺¹·L^-ⁿ ·g^-1

q e

/mg·g^-1

R²

Langmuir模型

0.03012

76.21394

—

0.96225

Freundich模型

15.11485

—

3.69497

0.76707

Langmuir- Freundich

模型

0.03441

68.97473

0.68857

0.98725

温度/K	$l n K f$	ΔG/kJ·mol^-1	ΔH^θ/kJ·mol^-1	ΔS^θ/J·mol^-1·K^-1
298	2.66	-6.58	43.60	170.01
300	2.93	-7.31
303	3.23	-8.13
308	3.38	-8.66

温度/K	$l n K f$	ΔG/kJ·mol^-1	ΔH^θ/kJ·mol^-1	ΔS^θ/J·mol^-1·K^-1
298	2.66	-6.58	43.60	170.01
300	2.93	-7.31
303	3.23	-8.13
308	3.38	-8.66

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Preparation of calcium carbonate composite by mechanically activated of ground calcium carbonate and its adsorption properties on Cu²⁺ ions in solution

机械活化重质碳酸钙制备复合碳酸钙及其对溶液中的Cu²⁺吸附性能

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