Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (7): 3611-3622.DOI: 10.16085/j.issn.1000-6613.2022-1732
• Materials science and technology • Previous Articles Next Articles
LI Jiyan(), JING Yanju, XING Guoyu, LIU Meichen, LONG Yong, ZHU Zhaoqi
Received:
2022-09-16
Revised:
2022-10-13
Online:
2023-08-14
Published:
2023-07-15
Contact:
LI Jiyan
通讯作者:
李吉焱
作者简介:
李吉焱(1986—),女,副教授,硕士生导师,研究方向为太阳能驱动界面蒸发。E-mail:lijiyan@lut.edu.cn。
基金资助:
CLC Number:
LI Jiyan, JING Yanju, XING Guoyu, LIU Meichen, LONG Yong, ZHU Zhaoqi. Research progress and challenges of salt-resistant solar-driven interface photo-thermal materials and evaporator[J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3611-3622.
李吉焱, 景艳菊, 邢郭宇, 刘美辰, 龙永, 朱照琪. 耐盐型太阳能驱动界面光热材料及蒸发器的研究进展[J]. 化工进展, 2023, 42(7): 3611-3622.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-1732
序号 | 光热材料 | 耐盐 方法 | 作用机制 | 蒸发速率 /kg·m-2·h-1 | 耐盐性能 | 参考 文献 |
---|---|---|---|---|---|---|
1 | 碳纤维包覆藜麦纤维素纳米片 | 1 | 直接冲洗盐晶体或自 清洁 | 3.2 | 3.5%和7.0% NaCl溶液,12h,表面的盐分别在熄灯7h和12h后自动溶解 | [ |
1 | ||||||
2 | 碳纳米管耦合棉织物 | 1.59 | 17.5% NaCl溶液,8h,洗涤后,表面非常干净,对织物无不利影响 | [ | ||
1 | ||||||
3 | 半球形双层水凝胶 | 2.03 | 25% NaCl溶液,10h,熄灯1h后盐颗粒完全溶解 | [ | ||
4 | 天然木材 | 2 | 通过设计蒸发器的结构来增强盐分的逆向扩散,盐分因浓度差异自动扩散回散装水 | 1.46 (3.6%NaCl) | 20% NaCl溶液,6h,无盐沉积,100h的连续试验期间,蒸发效率为75%;15% NaCl溶液,6h(1~5sun),未有盐积累 | [ |
5 | 聚丙烯酰胺/MnO2水凝胶 | 2 | 3.297 | 25%盐水,12h,只出现微小的盐颗粒,2.393kg/(m2·h);0.5g NaCl粉末90min后完全溶解 | [ | |
6 | N,S-掺杂多孔碳/壳聚糖 | 2 | 2.51 | 15% NaCl溶液,15h,无盐结晶;1.5g NaCl颗粒120min后完全溶解 | [ | |
7 | 疏水多孔碳纳米纤维膜 | 3 | 通过疏水作用阻断盐离子向光吸收表面的传输,以避免盐的形成 | 1.43 | 20%的海水,3h后,无可见盐;6h(2sun),1.41kg/(m2·h) | [ |
8 | SiO2/纤维素纳米材料 | 3 | 1.25 | 12% NaCl溶液,6h,无盐结晶生成 | [ | |
9 | Fe3O4/聚(N-异丙基丙烯酰胺)/聚丙烯腈 | 3 | 1.76 | 20% NaCl溶液,5天,性能稳定;1.5g NaCl,3h内完全溶解 | [ | |
10 | 铜和银纳米颗粒/生物质炭 | 4 | 调节材料的表面电荷,使盐溶液中的某一种离子被排斥,抑制盐结晶的产生 | 1.49 | 20% NaCl溶液,10h,没有盐结晶;5g盐4h内溶解 | [ |
11 | 聚合物水凝胶 | 4 | 2.76 | 3.5% NaCl溶液,蒸发60次,每次1.5h,无盐结晶,2.65kg/(m2·h);20% NaCl溶液,2.33kg/(m2·h);0.5g NaCl固体,180min后溶解 | [ | |
12 | 悬挂弧形织物 | 5 | 通过设计特殊的蒸发系统,在盐浓度达到结晶极限之前将浓缩后的盐水排出蒸发系统 | 1.94 | 21% NaCl溶液,1.9kg/m2·h,12h,样品表面没有盐积累 | [ |
13 | 聚丙烯腈@硫化铜织物 | 5 | 2.27(海水) | 海水,100h,无固体盐晶体 | [ | |
14 | 聚苯胺/纤维素 | 5 | 1.56(3.5%盐水) | 3.5%盐水,100h,性能没有下降;浓缩后的溶液盐度达到17.11% | [ | |
15 | 印刷空气铺设纸 | 6 | 通过控制盐结晶的位置,在空间上实现盐的结晶与水的蒸发的隔离 | 1.75 | 10%的盐水,900~1700W/m2下,蒸发效率80%;6.28kWh/d时,产盐速率约400g/(m2·d) | [ |
16 | 炭化绿藻 | 6 | 1.35 | 20% NaCl溶液,在自然光下15天可以收集到24.26g NaCl,表面没有结晶 | [ | |
17 | 复合树脂/碳纳米管 | 6 | 2.63(天然海水) | 25% NaCl溶液,盐结晶位于3D蒸发器的顶点 | [ | |
18 | 二氧化硅/炭/二氧化硅 (3D杯状) | 6 | 1.7 | 10%或15% NaCl溶液,24h,杯的内部底部无盐晶体沉淀;15% NaCl,75h,蒸发速率未下降 | [ | |
19 | 还原性氧化石墨烯和壳聚糖 包覆的织物 | 6 | 2.09 | 20% NaCl,90min,盐结晶开始出现在蜂窝单元顶部,1.92kg/m2·h;3.5%和9%盐水,没有明显的盐积累 | [ | |
20 | 椴木 | 7 | 采用热辐射和对流传热来代替热传导进行传热 | 0.67 | 20%海水,8h(2sun),1.04~1.19kg/(m2·h) | [ |
21 | 聚苯乙烯纤维素球体 | 8 | 盐结晶的析出促使蒸发器自动旋转,更新蒸发面以实现连续蒸发 | 2.6 | 20% NaCl溶液,30min后出现微小的盐结晶,在50min时驱动光热球旋转进行下一轮蒸发,8h的平均蒸发速率为2.06kg/(m2·h) | [ |
序号 | 光热材料 | 耐盐 方法 | 作用机制 | 蒸发速率 /kg·m-2·h-1 | 耐盐性能 | 参考 文献 |
---|---|---|---|---|---|---|
1 | 碳纤维包覆藜麦纤维素纳米片 | 1 | 直接冲洗盐晶体或自 清洁 | 3.2 | 3.5%和7.0% NaCl溶液,12h,表面的盐分别在熄灯7h和12h后自动溶解 | [ |
1 | ||||||
2 | 碳纳米管耦合棉织物 | 1.59 | 17.5% NaCl溶液,8h,洗涤后,表面非常干净,对织物无不利影响 | [ | ||
1 | ||||||
3 | 半球形双层水凝胶 | 2.03 | 25% NaCl溶液,10h,熄灯1h后盐颗粒完全溶解 | [ | ||
4 | 天然木材 | 2 | 通过设计蒸发器的结构来增强盐分的逆向扩散,盐分因浓度差异自动扩散回散装水 | 1.46 (3.6%NaCl) | 20% NaCl溶液,6h,无盐沉积,100h的连续试验期间,蒸发效率为75%;15% NaCl溶液,6h(1~5sun),未有盐积累 | [ |
5 | 聚丙烯酰胺/MnO2水凝胶 | 2 | 3.297 | 25%盐水,12h,只出现微小的盐颗粒,2.393kg/(m2·h);0.5g NaCl粉末90min后完全溶解 | [ | |
6 | N,S-掺杂多孔碳/壳聚糖 | 2 | 2.51 | 15% NaCl溶液,15h,无盐结晶;1.5g NaCl颗粒120min后完全溶解 | [ | |
7 | 疏水多孔碳纳米纤维膜 | 3 | 通过疏水作用阻断盐离子向光吸收表面的传输,以避免盐的形成 | 1.43 | 20%的海水,3h后,无可见盐;6h(2sun),1.41kg/(m2·h) | [ |
8 | SiO2/纤维素纳米材料 | 3 | 1.25 | 12% NaCl溶液,6h,无盐结晶生成 | [ | |
9 | Fe3O4/聚(N-异丙基丙烯酰胺)/聚丙烯腈 | 3 | 1.76 | 20% NaCl溶液,5天,性能稳定;1.5g NaCl,3h内完全溶解 | [ | |
10 | 铜和银纳米颗粒/生物质炭 | 4 | 调节材料的表面电荷,使盐溶液中的某一种离子被排斥,抑制盐结晶的产生 | 1.49 | 20% NaCl溶液,10h,没有盐结晶;5g盐4h内溶解 | [ |
11 | 聚合物水凝胶 | 4 | 2.76 | 3.5% NaCl溶液,蒸发60次,每次1.5h,无盐结晶,2.65kg/(m2·h);20% NaCl溶液,2.33kg/(m2·h);0.5g NaCl固体,180min后溶解 | [ | |
12 | 悬挂弧形织物 | 5 | 通过设计特殊的蒸发系统,在盐浓度达到结晶极限之前将浓缩后的盐水排出蒸发系统 | 1.94 | 21% NaCl溶液,1.9kg/m2·h,12h,样品表面没有盐积累 | [ |
13 | 聚丙烯腈@硫化铜织物 | 5 | 2.27(海水) | 海水,100h,无固体盐晶体 | [ | |
14 | 聚苯胺/纤维素 | 5 | 1.56(3.5%盐水) | 3.5%盐水,100h,性能没有下降;浓缩后的溶液盐度达到17.11% | [ | |
15 | 印刷空气铺设纸 | 6 | 通过控制盐结晶的位置,在空间上实现盐的结晶与水的蒸发的隔离 | 1.75 | 10%的盐水,900~1700W/m2下,蒸发效率80%;6.28kWh/d时,产盐速率约400g/(m2·d) | [ |
16 | 炭化绿藻 | 6 | 1.35 | 20% NaCl溶液,在自然光下15天可以收集到24.26g NaCl,表面没有结晶 | [ | |
17 | 复合树脂/碳纳米管 | 6 | 2.63(天然海水) | 25% NaCl溶液,盐结晶位于3D蒸发器的顶点 | [ | |
18 | 二氧化硅/炭/二氧化硅 (3D杯状) | 6 | 1.7 | 10%或15% NaCl溶液,24h,杯的内部底部无盐晶体沉淀;15% NaCl,75h,蒸发速率未下降 | [ | |
19 | 还原性氧化石墨烯和壳聚糖 包覆的织物 | 6 | 2.09 | 20% NaCl,90min,盐结晶开始出现在蜂窝单元顶部,1.92kg/m2·h;3.5%和9%盐水,没有明显的盐积累 | [ | |
20 | 椴木 | 7 | 采用热辐射和对流传热来代替热传导进行传热 | 0.67 | 20%海水,8h(2sun),1.04~1.19kg/(m2·h) | [ |
21 | 聚苯乙烯纤维素球体 | 8 | 盐结晶的析出促使蒸发器自动旋转,更新蒸发面以实现连续蒸发 | 2.6 | 20% NaCl溶液,30min后出现微小的盐结晶,在50min时驱动光热球旋转进行下一轮蒸发,8h的平均蒸发速率为2.06kg/(m2·h) | [ |
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