Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (4): 1797-1810.DOI: 10.16085/j.issn.1000-6613.2022-1042
• Industrial catalysis • Previous Articles Next Articles
GUO Pengju1,2(), HE Xiaobo1,2, YIN Fengxiang1,2()
Received:
2022-06-06
Revised:
2022-10-02
Online:
2023-05-08
Published:
2023-04-25
Contact:
YIN Fengxiang
通讯作者:
银凤翔
作者简介:
郭朋举(1992—),男,博士研究生,研究方向为电催化。E-mail:ppjuguo086@163.com。
基金资助:
CLC Number:
GUO Pengju, HE Xiaobo, YIN Fengxiang. Research progress in MOF-based catalysts for electrocatalytic nitrogen reduction to ammonia[J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1797-1810.
郭朋举, 何小波, 银凤翔. 电催化氮还原合成氨MOF基催化剂研究进展[J]. 化工进展, 2023, 42(4): 1797-1810.
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催化剂 | 电解质 | 氨产率 | 法拉第效率/% | 参考文献 |
---|---|---|---|---|
NH2-MIL-88B-Fe(Fe基MOF) | 0.1mol/L Na2SO4 | 1.205×10-10mol·s-1·cm-2 | 12.45 | [ |
Cu@Ce-MOF-2(铜网原位生长Ce-MOF) | 0.1mol/L KOH | 14.83μg·h-1·cm-2 | 10.81 | [ |
Defective UiO-66-NH2(缺陷型UiO-66-NH2) | 0.1mol/L Na2SO4 | 2.071×10-10mol·s-1·cm-2 | 85.21 | [ |
Fe-MOF(MIL-101-Fe) | 2mol/L KOH | 2.12×10-9mol·s-1·cm-2 | 1.43 | [ |
HKUST-1(MOF:铜-BTC) | 0.1mol/L Na2SO4 | 46.63μg·h-1·mgcat-1 | 2.45 | [ |
CuⅡ MOF(碳布自支撑CuⅡ-MOF催化剂) | 1mol/L Na2SO4 | 24.7mg·h-1·mgcat-1 | 11.9 | [ |
Co3HHTP2(Co3(六羟基三苯)2纳米粒子) | 0.5mol/L LiClO4 | 22.14μg·h-1·mgcat-1 | 3.34 | [ |
MIL-100-Al(Al基MOF) | 0.1mol/L KOH | 10.6μg·h-1·cm-2·mgcat-1 | 22.6 | [ |
UiO-66-HAc(缺陷型UiO-66) | 0.1mol/L Na2SO4 | 31.81μg·h-1·mgcat-1 | 48.06 | [ |
Co3Fe-MOF(二维双金属MOF纳米片) | 0.1mol/L KOH | 8.79μg·h-1·mgcat-1 | 25.64 | [ |
NiFe-MOF(零维双金属MOF) | 0.1mol/L NaHCO3 | 9.3μg·h-1mgcat-1 | 11.5 | [ |
MoS2@ZIF-71(ZIF-71封装MoS2纳米花) | 0.1mol/L Na2SO4 | 56.69μg·h-1·mgcat-1 | 30.91 | [ |
CNT@CAU-17(碳纳米管插入CAU-17) | 0.05mol/L H2SO4 | 11.92μg·h-1·mgcat-1 | 31.27 | [ |
MIL-101(Fe)/MoS3(纳米片杂化材料) | 0.1mol/L HCl | 25.7μg·h-1·mgcat-1 | 36.71 | [ |
Ag-Au@ZIF(ZIF-71封装Ag-Au) | 0.2mol/L LiCF3SO3 | 0.623μg·h-1·cm-2 | 18 | [ |
AuCu/ZIF-8(AuCu纳米合金负载ZIF-8) | 0.1mol/L HCl | 63.9μg·h-1·mgcat-1 | 14.2 | [ |
HT Au@MOF(疏水性MOF自支撑Au) | 0.1mol/L Na2SO4 | 49.5μg·h-1·mgcat-1 | 60.9 | [ |
Pt/Au@ZIF(ZIF-71封装Pt/Au) | 0.2mol/L LiCF3SO3 | 161μg·h-1·mgcat-1 | 44 | [ |
Au@ZIF-8(纳米金嵌入ZIF-8) | 0.1mol/L Na2SO4 | 28.7μg·h-1·cm-2 | 44 | [ |
催化剂 | 电解质 | 氨产率 | 法拉第效率/% | 参考文献 |
---|---|---|---|---|
NH2-MIL-88B-Fe(Fe基MOF) | 0.1mol/L Na2SO4 | 1.205×10-10mol·s-1·cm-2 | 12.45 | [ |
Cu@Ce-MOF-2(铜网原位生长Ce-MOF) | 0.1mol/L KOH | 14.83μg·h-1·cm-2 | 10.81 | [ |
Defective UiO-66-NH2(缺陷型UiO-66-NH2) | 0.1mol/L Na2SO4 | 2.071×10-10mol·s-1·cm-2 | 85.21 | [ |
Fe-MOF(MIL-101-Fe) | 2mol/L KOH | 2.12×10-9mol·s-1·cm-2 | 1.43 | [ |
HKUST-1(MOF:铜-BTC) | 0.1mol/L Na2SO4 | 46.63μg·h-1·mgcat-1 | 2.45 | [ |
CuⅡ MOF(碳布自支撑CuⅡ-MOF催化剂) | 1mol/L Na2SO4 | 24.7mg·h-1·mgcat-1 | 11.9 | [ |
Co3HHTP2(Co3(六羟基三苯)2纳米粒子) | 0.5mol/L LiClO4 | 22.14μg·h-1·mgcat-1 | 3.34 | [ |
MIL-100-Al(Al基MOF) | 0.1mol/L KOH | 10.6μg·h-1·cm-2·mgcat-1 | 22.6 | [ |
UiO-66-HAc(缺陷型UiO-66) | 0.1mol/L Na2SO4 | 31.81μg·h-1·mgcat-1 | 48.06 | [ |
Co3Fe-MOF(二维双金属MOF纳米片) | 0.1mol/L KOH | 8.79μg·h-1·mgcat-1 | 25.64 | [ |
NiFe-MOF(零维双金属MOF) | 0.1mol/L NaHCO3 | 9.3μg·h-1mgcat-1 | 11.5 | [ |
MoS2@ZIF-71(ZIF-71封装MoS2纳米花) | 0.1mol/L Na2SO4 | 56.69μg·h-1·mgcat-1 | 30.91 | [ |
CNT@CAU-17(碳纳米管插入CAU-17) | 0.05mol/L H2SO4 | 11.92μg·h-1·mgcat-1 | 31.27 | [ |
MIL-101(Fe)/MoS3(纳米片杂化材料) | 0.1mol/L HCl | 25.7μg·h-1·mgcat-1 | 36.71 | [ |
Ag-Au@ZIF(ZIF-71封装Ag-Au) | 0.2mol/L LiCF3SO3 | 0.623μg·h-1·cm-2 | 18 | [ |
AuCu/ZIF-8(AuCu纳米合金负载ZIF-8) | 0.1mol/L HCl | 63.9μg·h-1·mgcat-1 | 14.2 | [ |
HT Au@MOF(疏水性MOF自支撑Au) | 0.1mol/L Na2SO4 | 49.5μg·h-1·mgcat-1 | 60.9 | [ |
Pt/Au@ZIF(ZIF-71封装Pt/Au) | 0.2mol/L LiCF3SO3 | 161μg·h-1·mgcat-1 | 44 | [ |
Au@ZIF-8(纳米金嵌入ZIF-8) | 0.1mol/L Na2SO4 | 28.7μg·h-1·cm-2 | 44 | [ |
催化剂 | 电解质 | 氨产率 | 法拉第效率/% | 参考文献 |
---|---|---|---|---|
Co@NC(Co纳米粒子负载氮掺杂碳基底) | 0.1mol/L Na2SO4 | 1.57×10-11mol·s-1·cm-2 | 21.79 | [ |
Co/C-900(钴掺杂碳复合材料) | 0.1mol/L KOH | 4.66μmol·h-1·cm-2 | 11.53 | [ |
Bi NPs@CRs(原位衍生铋纳米粒子) | 0.1mol/L HCl | 20.80μg·h-1·mgcat-1 | 11.50 | [ |
Zn-Co3O4(Zn掺杂Co3O4纳米多面体) | 0.1mol/L HCl | 22.71μg·h-1·mgcat-1 | 11.9 | [ |
Co3O4@NCs(氮掺杂碳/Co3O4核壳结构) | 0.05mol/L H2SO4 | 42.58μg·h-1·mgcat-1 | 8.5 | [ |
Fe2O3@MoS2(双金属杂化材料) | 0.1mol/L Na2SO4 | 112.15μg·h-1·mgcat-1 | 8.62 | [ |
Fe1.89 Mo4.11O7/FeS2@C(双金属杂化材料) | 0.1mol/L KOH | 105.3μg·h-1·mgcat-1 | 54.7 | [ |
Mo-Co/NC(Mo-Co嵌入氮掺杂碳基底) | 0.1mol/L Na2SO4 | 89.8μmol·h-1·mgcat-1 | 13.5 | [ |
CoRu@NC(双金属氮掺杂碳杂化材料) | 0.1mol/L KOH | 56.82μg·h-1·mgcat-1 | 2.02 | [ |
CoP HNC(中空磷化钴纳米笼) | 0.1mol/L Na2SO4 | 10.78μg·h-1·mgcat-1 | 7.36 | [ |
MoFe-Pc微球(Pc磷掺杂碳) | 0.1mol/L HCl | 34.23μg·h-1·mgcat-1 | 16.83 | [ |
Ru SAc/N-C(Ru单原子催化剂) | 0.05mol/L H2SO4 | 120.9μg·h-1·mgcat-1 | 29.6 | [ |
Ni-N x -C(Ni单原子催化剂) | 0.5mol/L LiClO4 | 115μg·h-1·cm-2 | 21.9 | [ |
ISAS-Fe/NC(Fe单原子催化剂) | 0.1mol/L PBS | 62.9μg·h-1·mgcat-1 | 18.6 | [ |
Co/N-doped C(钴/氮掺杂碳材料) | 0.1mol/L KOH | 0.4μmol·h-1·cm-2 | 10.1 | [ |
Ru@ZrO2/NC(添加ZrO2的Ru单原子催化剂) | 0.1mol/L HCl | 3.665mg·h-1·mgRu-1 | 21 | [ |
Fe1-N-C(Fe单原子嵌入氮掺杂碳基底) | 0.1mol/L HCl | 1.56×10-11mol·s-1·cm-2 | 4.51 | [ |
NPC-750(氮掺杂多孔炭) | 0.05mol/L H2SO4 | 23.8μg·h-1·mgcat-1 | 1.42 | [ |
C-ZIF-1100-1h(氮掺杂纳米多孔炭) | 0.1mol/L Na2SO4 | 3.4×10-6mol·cm-2·h-1 | 10.2 | [ |
NP-C-MOF-5(氮、磷共掺杂多孔炭) | 0.1mol/L HCl | 1.08μg·h-1·mgcat-1 | 0.52 | [ |
S/N-MPC(硫改性的氮掺杂多孔炭) | 0.05mol/L H2SO4 | 45.51μg·h-1·mgcat-1 | 25.16 | [ |
催化剂 | 电解质 | 氨产率 | 法拉第效率/% | 参考文献 |
---|---|---|---|---|
Co@NC(Co纳米粒子负载氮掺杂碳基底) | 0.1mol/L Na2SO4 | 1.57×10-11mol·s-1·cm-2 | 21.79 | [ |
Co/C-900(钴掺杂碳复合材料) | 0.1mol/L KOH | 4.66μmol·h-1·cm-2 | 11.53 | [ |
Bi NPs@CRs(原位衍生铋纳米粒子) | 0.1mol/L HCl | 20.80μg·h-1·mgcat-1 | 11.50 | [ |
Zn-Co3O4(Zn掺杂Co3O4纳米多面体) | 0.1mol/L HCl | 22.71μg·h-1·mgcat-1 | 11.9 | [ |
Co3O4@NCs(氮掺杂碳/Co3O4核壳结构) | 0.05mol/L H2SO4 | 42.58μg·h-1·mgcat-1 | 8.5 | [ |
Fe2O3@MoS2(双金属杂化材料) | 0.1mol/L Na2SO4 | 112.15μg·h-1·mgcat-1 | 8.62 | [ |
Fe1.89 Mo4.11O7/FeS2@C(双金属杂化材料) | 0.1mol/L KOH | 105.3μg·h-1·mgcat-1 | 54.7 | [ |
Mo-Co/NC(Mo-Co嵌入氮掺杂碳基底) | 0.1mol/L Na2SO4 | 89.8μmol·h-1·mgcat-1 | 13.5 | [ |
CoRu@NC(双金属氮掺杂碳杂化材料) | 0.1mol/L KOH | 56.82μg·h-1·mgcat-1 | 2.02 | [ |
CoP HNC(中空磷化钴纳米笼) | 0.1mol/L Na2SO4 | 10.78μg·h-1·mgcat-1 | 7.36 | [ |
MoFe-Pc微球(Pc磷掺杂碳) | 0.1mol/L HCl | 34.23μg·h-1·mgcat-1 | 16.83 | [ |
Ru SAc/N-C(Ru单原子催化剂) | 0.05mol/L H2SO4 | 120.9μg·h-1·mgcat-1 | 29.6 | [ |
Ni-N x -C(Ni单原子催化剂) | 0.5mol/L LiClO4 | 115μg·h-1·cm-2 | 21.9 | [ |
ISAS-Fe/NC(Fe单原子催化剂) | 0.1mol/L PBS | 62.9μg·h-1·mgcat-1 | 18.6 | [ |
Co/N-doped C(钴/氮掺杂碳材料) | 0.1mol/L KOH | 0.4μmol·h-1·cm-2 | 10.1 | [ |
Ru@ZrO2/NC(添加ZrO2的Ru单原子催化剂) | 0.1mol/L HCl | 3.665mg·h-1·mgRu-1 | 21 | [ |
Fe1-N-C(Fe单原子嵌入氮掺杂碳基底) | 0.1mol/L HCl | 1.56×10-11mol·s-1·cm-2 | 4.51 | [ |
NPC-750(氮掺杂多孔炭) | 0.05mol/L H2SO4 | 23.8μg·h-1·mgcat-1 | 1.42 | [ |
C-ZIF-1100-1h(氮掺杂纳米多孔炭) | 0.1mol/L Na2SO4 | 3.4×10-6mol·cm-2·h-1 | 10.2 | [ |
NP-C-MOF-5(氮、磷共掺杂多孔炭) | 0.1mol/L HCl | 1.08μg·h-1·mgcat-1 | 0.52 | [ |
S/N-MPC(硫改性的氮掺杂多孔炭) | 0.05mol/L H2SO4 | 45.51μg·h-1·mgcat-1 | 25.16 | [ |
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