Chemical Industry and Engineering Progress ›› 2025, Vol. 44 ›› Issue (3): 1466-1484.DOI: 10.16085/j.issn.1000-6613.2024-0448
• Materials science and technology • Previous Articles Next Articles
SONG Ci1,2(
), LI Haiyan1,2, ZHANG Shizhen1,2, LIU Hongwei3, ZHANG Jianying1,2, QIU Jiahao1,2, CAO Renwei1,2, SUN Kun1,2, QIN Ying1,2, ZHU Mingxu1,2, GAO Mengyan1,2
Received:2024-03-18
Revised:2024-05-14
Online:2025-04-15
Published:2025-03-25
Contact:
SONG Ci
宋慈1,2(
), 李海燕1,2, 张世珍1,2, 刘洪伟3, 张建英1,2, 邱家浩1,2, 曹仁伟1,2, 孙坤1,2, 秦颖1,2, 朱明绪1,2, 高梦岩1,2
通讯作者:
宋慈
作者简介:宋慈(1993—),男,硕士,工程师,研究方向为防腐蚀涂料的制备和应用。E-mail:1021616229@qq.com。
CLC Number:
SONG Ci, LI Haiyan, ZHANG Shizhen, LIU Hongwei, ZHANG Jianying, QIU Jiahao, CAO Renwei, SUN Kun, QIN Ying, ZHU Mingxu, GAO Mengyan. Types and application status of the self-repairing anti-corrosion coatings[J]. Chemical Industry and Engineering Progress, 2025, 44(3): 1466-1484.
宋慈, 李海燕, 张世珍, 刘洪伟, 张建英, 邱家浩, 曹仁伟, 孙坤, 秦颖, 朱明绪, 高梦岩. 自修复防腐蚀涂层的类型及应用现状[J]. 化工进展, 2025, 44(3): 1466-1484.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2024-0448
| 类型 | 原理 | 优点 | 缺点 | 优化措施 |
|---|---|---|---|---|
| 外援型自修复防腐蚀涂层 | 内含承载修补剂/缓蚀剂载体材料,涂层破损时修补剂/缓蚀剂逸出,修补破损处或在金属暴露面形成缓蚀层 | 自修复响应条件温和,不需要外部能量;添加适量微胶囊/负载材料可提高整体韧性和防腐蚀介质渗透性 | 适用的载体材料种类不多;修补剂/缓蚀剂载体制备过程复杂烦琐,目前难以大规模生产;涂层自修复及长效防腐蚀性能受到微胶囊及负载材料分散性、相容性、修补剂/缓蚀剂承载量等因素的制约,较为恶劣环境中防腐性能力不足 | 通过结构改性和增大搅拌速率、时间,提升修补剂/缓蚀剂承载结构的分散性与相容性;根据涂层中最需要的位置进行设计和承载材料排列,提高自修复防腐蚀效率;保持合理粒径的前提下提升微胶囊及负载材料的负载能力,携带更多修补剂/缓蚀剂以延长涂层自修复及长效防腐蚀的时限 |
| 本征型自修复防腐蚀涂层 | 利用自身聚合物基体的物理化学结构实现涂层的自修复,并延续腐蚀防护性能 | 对外加修复剂的依赖低,可实现涂层的多次修复;具有修复均一性和大面积修复涂层微裂纹的潜力 | 自修复响应需要较高甚至苛刻的引发条件,实际使用中难以满足;基体树脂合成较复杂、基体树脂选择范围小;涂层存在力学性能较差、抗断裂能力较弱等风险;腐蚀防护方法较为单一 | 将非共价动态相互作用与动态共价键相结合,研制具有多种化学作用结构的涂层基体,达到涂层高力学性能与高自修复性能的最佳平衡;引入更为高效的光催化材料和光热转换材料,使实际使用环境亦可满足自修复相应条件;可适量加入缓蚀剂负载材料,进一步提升涂层的腐蚀防护能力 |
| 类型 | 原理 | 优点 | 缺点 | 优化措施 |
|---|---|---|---|---|
| 外援型自修复防腐蚀涂层 | 内含承载修补剂/缓蚀剂载体材料,涂层破损时修补剂/缓蚀剂逸出,修补破损处或在金属暴露面形成缓蚀层 | 自修复响应条件温和,不需要外部能量;添加适量微胶囊/负载材料可提高整体韧性和防腐蚀介质渗透性 | 适用的载体材料种类不多;修补剂/缓蚀剂载体制备过程复杂烦琐,目前难以大规模生产;涂层自修复及长效防腐蚀性能受到微胶囊及负载材料分散性、相容性、修补剂/缓蚀剂承载量等因素的制约,较为恶劣环境中防腐性能力不足 | 通过结构改性和增大搅拌速率、时间,提升修补剂/缓蚀剂承载结构的分散性与相容性;根据涂层中最需要的位置进行设计和承载材料排列,提高自修复防腐蚀效率;保持合理粒径的前提下提升微胶囊及负载材料的负载能力,携带更多修补剂/缓蚀剂以延长涂层自修复及长效防腐蚀的时限 |
| 本征型自修复防腐蚀涂层 | 利用自身聚合物基体的物理化学结构实现涂层的自修复,并延续腐蚀防护性能 | 对外加修复剂的依赖低,可实现涂层的多次修复;具有修复均一性和大面积修复涂层微裂纹的潜力 | 自修复响应需要较高甚至苛刻的引发条件,实际使用中难以满足;基体树脂合成较复杂、基体树脂选择范围小;涂层存在力学性能较差、抗断裂能力较弱等风险;腐蚀防护方法较为单一 | 将非共价动态相互作用与动态共价键相结合,研制具有多种化学作用结构的涂层基体,达到涂层高力学性能与高自修复性能的最佳平衡;引入更为高效的光催化材料和光热转换材料,使实际使用环境亦可满足自修复相应条件;可适量加入缓蚀剂负载材料,进一步提升涂层的腐蚀防护能力 |
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