Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (10): 5232-5248.DOI: 10.16085/j.issn.1000-6613.2022-2040
• Materials science and technology • Previous Articles Next Articles
CAI Mingwei1(), WANG Zhi1, LU Xiaochuang2, ZHUANG Junwei3, WU Jiahao1, ZHANG Shiyang1(), MIN Yonggang1()
Received:
2022-11-02
Revised:
2022-12-06
Online:
2023-11-11
Published:
2023-10-15
Contact:
ZHANG Shiyang, MIN Yonggang
蔡铭威1(), 王知1, 卢小闯2, 庄俊伟3, 吴嘉豪1, 张诗洋1(), 闵永刚1()
通讯作者:
张诗洋,闵永刚
作者简介:
蔡铭威(1999—),男,硕士研究生,研究方向为气体分离。E-mail:2112102037@mail2.gdut.edu.cn。
基金资助:
CLC Number:
CAI Mingwei, WANG Zhi, LU Xiaochuang, ZHUANG Junwei, WU Jiahao, ZHANG Shiyang, MIN Yonggang. Polyimide membranes for hydrogen separation: A review[J]. Chemical Industry and Engineering Progress, 2023, 42(10): 5232-5248.
蔡铭威, 王知, 卢小闯, 庄俊伟, 吴嘉豪, 张诗洋, 闵永刚. 聚酰亚胺薄膜在氢气分离中的研究进展[J]. 化工进展, 2023, 42(10): 5232-5248.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-2040
复合膜 | 渗透性/barrer | 选择性 | |||
---|---|---|---|---|---|
H2 | CO2 | CH4 | H2/CH4 | H2/CO2 | |
Matrimid 5218/20% DDR®[ | 34.9 | 0.093 | 375.27 | ||
Matrimid 5218/15% DDR®[ | 29.37 | 0.095 | 309.16 | ||
PI/ZIF-7-III[ | 322.01±28.66 | 74.08±1.73 | 1.87±0.07 | 172.24±8.50 | 4.35±0.29 |
PI/ZIF-7-I[ | 921.44±100.46 | 407.41±50.05 | 13.67±1.20 | 67.42±1.45 | 2.26±0.03 |
25% ZIF-8/6FDA-BI[ | 79.4±12.3 | 0.56±0.036 | 142.6±29.5 | ||
20% ZIF-8/6FDA-BI[ | 78.5±5.84 | 0.35±0.033 | 223.9±16.7 | ||
6FDA-DAM:DABA(3∶2)/10% ZIF-8-90(30)[ | 301 | 187 | 5.41 | 55.7 | 1.61 |
6FDA-DAM:DABA(3∶2)/10% ZIF-8-90(50)[ | 276 | 174 | 4.74 | 58.3 | 1.58 |
2% A-SWNT[ | 122±3 | 63±1 | 1.4±0.1 | 88±3 | 1.9±0.1 |
20%-COOH-PI/NH2-UiO-66[ | 1180 | 995 | 43 | 27.2 | 1.18 |
PSF/PI[ | 348 | 86 | 4.04 | ||
PI/PBI[ | 86 | 2.77 | 31 | ||
PI/TB 120℃,16h[ | 77.1 | 18.4 | 0.16 | 481.8 | 4.19 |
PI/TB 150℃,16h[ | 86.8 | 23.1 | 0.21 | 413.3 | 3.75 |
复合膜 | 渗透性/barrer | 选择性 | |||
---|---|---|---|---|---|
H2 | CO2 | CH4 | H2/CH4 | H2/CO2 | |
Matrimid 5218/20% DDR®[ | 34.9 | 0.093 | 375.27 | ||
Matrimid 5218/15% DDR®[ | 29.37 | 0.095 | 309.16 | ||
PI/ZIF-7-III[ | 322.01±28.66 | 74.08±1.73 | 1.87±0.07 | 172.24±8.50 | 4.35±0.29 |
PI/ZIF-7-I[ | 921.44±100.46 | 407.41±50.05 | 13.67±1.20 | 67.42±1.45 | 2.26±0.03 |
25% ZIF-8/6FDA-BI[ | 79.4±12.3 | 0.56±0.036 | 142.6±29.5 | ||
20% ZIF-8/6FDA-BI[ | 78.5±5.84 | 0.35±0.033 | 223.9±16.7 | ||
6FDA-DAM:DABA(3∶2)/10% ZIF-8-90(30)[ | 301 | 187 | 5.41 | 55.7 | 1.61 |
6FDA-DAM:DABA(3∶2)/10% ZIF-8-90(50)[ | 276 | 174 | 4.74 | 58.3 | 1.58 |
2% A-SWNT[ | 122±3 | 63±1 | 1.4±0.1 | 88±3 | 1.9±0.1 |
20%-COOH-PI/NH2-UiO-66[ | 1180 | 995 | 43 | 27.2 | 1.18 |
PSF/PI[ | 348 | 86 | 4.04 | ||
PI/PBI[ | 86 | 2.77 | 31 | ||
PI/TB 120℃,16h[ | 77.1 | 18.4 | 0.16 | 481.8 | 4.19 |
PI/TB 150℃,16h[ | 86.8 | 23.1 | 0.21 | 413.3 | 3.75 |
复合膜 | 渗透性/barrer | 选择性 | |||
---|---|---|---|---|---|
H2 | CO2 | CH4 | H2/CH4 | H2/CO2 | |
6F-AP/DA-400[ | 196.4±9.8 | 94.3±4.7 | 2.18±0.22 | 89.17 | 2.08 |
Co-80/20[ | 380 | 261 | 6.7 | 57 | 1.45 |
Co-50/50[ | 155 | 67 | 1.3 | 119 | 2.31 |
PES∶P84=75∶25[ | 105.6 | 15.36 | — | — | 6.87 |
PDA∶BuDA=0.8∶0.2[ | 91100 | 11619.89 | — | — | 7.84 |
Cross-linked P84[ | 47 | — | 3.35 | — | 14 |
HBIN-Is[ | 78.7 | 27.3 | 0.37 | 213 | 2.88 |
4MTBDA-PMDA[ | 3300 | — | 390 | 8.46 | — |
复合膜 | 渗透性/barrer | 选择性 | |||
---|---|---|---|---|---|
H2 | CO2 | CH4 | H2/CH4 | H2/CO2 | |
6F-AP/DA-400[ | 196.4±9.8 | 94.3±4.7 | 2.18±0.22 | 89.17 | 2.08 |
Co-80/20[ | 380 | 261 | 6.7 | 57 | 1.45 |
Co-50/50[ | 155 | 67 | 1.3 | 119 | 2.31 |
PES∶P84=75∶25[ | 105.6 | 15.36 | — | — | 6.87 |
PDA∶BuDA=0.8∶0.2[ | 91100 | 11619.89 | — | — | 7.84 |
Cross-linked P84[ | 47 | — | 3.35 | — | 14 |
HBIN-Is[ | 78.7 | 27.3 | 0.37 | 213 | 2.88 |
4MTBDA-PMDA[ | 3300 | — | 390 | 8.46 | — |
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