Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (07): 3332-3340.DOI: 10.16085/j.issn.1000-6613.2019-0227
• Materials science and technology • Previous Articles Next Articles
Hua XU,Hongjian WEN,Jianda LIN,Hongjun ZHOU,Huayao CHEN,Xinhua ZHOU()
Received:
2019-02-18
Revised:
2019-03-08
Online:
2019-07-05
Published:
2019-07-05
Contact:
Xinhua ZHOU
通讯作者:
周新华
作者简介:
徐华(1983—),男,博士,讲师。
基金资助:
CLC Number:
Hua XU, Hongjian WEN, Jianda LIN, Hongjun ZHOU, Huayao CHEN, Xinhua ZHOU. Adsorption performance of CTS-g-PAA/ATP composite on chlorpyrifos[J]. Chemical Industry and Engineering Progress, 2019, 38(07): 3332-3340.
徐华, 温洪坚, 林建达, 周红军, 陈铧耀, 周新华. 壳聚糖接枝聚丙烯酸/凹凸棒石复合材料对毒死蜱的吸附行为[J]. 化工进展, 2019, 38(07): 3332-3340.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2019-0227
热力学模型 | 方程式 | |
---|---|---|
Langmuir model | (3) | |
Freundlich model | (4) | |
Tempkin model | (5) |
热力学模型 | 方程式 | |
---|---|---|
Langmuir model | (3) | |
Freundlich model | (4) | |
Tempkin model | (5) |
温度/℃ | Langmuir等温吸附方程 | Freundlich等温吸附方程 | Tempkin等温吸附方程 | |||||||
---|---|---|---|---|---|---|---|---|---|---|
Qmax/mg·g-1 | KL/mg·g-1 | R2 | n | KF/mg·g-1·(L·mg-1)1/n | R2 | KT/L·mg-1 | B | bT/kJ·mol-1 | R2 | |
30 | 57.8 | 2.86×10-4 | 0.9724 | 1.21 | 4.15×10-2 | 0.9721 | 0.833 | 9.52 | 0.264 | 0.9539 |
35 | 54.3 | 3.38×10-4 | 0.9908 | 1.34 | 7.75×10-2 | 0.9777 | 0.829 | 9.28 | 0.276 | 0.9493 |
40 | 51.2 | 3.97×10-4 | 0.9863 | 1.37 | 8.99×10-2 | 0.9844 | 0.828 | 9.56 | 0.272 | 0.9532 |
温度/℃ | Langmuir等温吸附方程 | Freundlich等温吸附方程 | Tempkin等温吸附方程 | |||||||
---|---|---|---|---|---|---|---|---|---|---|
Qmax/mg·g-1 | KL/mg·g-1 | R2 | n | KF/mg·g-1·(L·mg-1)1/n | R2 | KT/L·mg-1 | B | bT/kJ·mol-1 | R2 | |
30 | 57.8 | 2.86×10-4 | 0.9724 | 1.21 | 4.15×10-2 | 0.9721 | 0.833 | 9.52 | 0.264 | 0.9539 |
35 | 54.3 | 3.38×10-4 | 0.9908 | 1.34 | 7.75×10-2 | 0.9777 | 0.829 | 9.28 | 0.276 | 0.9493 |
40 | 51.2 | 3.97×10-4 | 0.9863 | 1.37 | 8.99×10-2 | 0.9844 | 0.828 | 9.56 | 0.272 | 0.9532 |
动力学模型 | 方程式 | |
---|---|---|
准一级模型 | (6) | |
准二级模型 | (7) | |
Elovich方程 | (8) | |
内扩散模型 | (9) | |
Bangham扩散模型 | (10) |
动力学模型 | 方程式 | |
---|---|---|
准一级模型 | (6) | |
准二级模型 | (7) | |
Elovich方程 | (8) | |
内扩散模型 | (9) | |
Bangham扩散模型 | (10) |
浓度/mg·mL-1(温度/℃) | 准一级动力学 | 准二级动力学 | |||||
---|---|---|---|---|---|---|---|
qe,cal | qe,exp | k1 | R2 | qe | k2 | R2 | |
0.5 (30) | 5.60 | 6.03 | -0.0141 | 0.9417 | 9.30 | 7.70×10-4 | 0.9868 |
1.0 (30) | 9.32 | 11.32 | -0.0215 | 0.9600 | 23.32 | 2.11×10-4 | 0.9983 |
1.5 (30) | 15.95 | 26.48 | -0.0328 | 0.8836 | 69.59 | 3.85×10-5 | 0.9968 |
2.0 (30) | 18.95 | 27.67 | -0.0304 | 0.9282 | 42.28 | 1.56×10-4 | 0.9732 |
0.5 (35) | 6.50 | 6.92 | -0.0129 | 0.9857 | 15.34 | 2.73×10-4 | 0.9932 |
1.0 (35) | 10.06 | 13.01 | -0.0239 | 0.9290 | 15.77 | 6.74×10-4 | 0.9763 |
1.5 (35) | 16.43 | 24.05 | -0.0296 | 0.9305 | 58.48 | 6.03×10-5 | 0.9972 |
2.0 (35) | 19.80 | 31.60 | -0.0345 | 0.9085 | 42.37 | 1.79×10-4 | 0.9984 |
0.5 (40) | 6.80 | 9.11 | -0.0229 | 0.8413 | 17.39 | 2.74×10-4 | 0.9949 |
1.0 (40) | 10.95 | 13.52 | -0.0255 | 0.9515 | 16.57 | 8.11×10-4 | 0.9948 |
1.5 (40) | 16.70 | 23.89 | -0.0304 | 0.9475 | 52.91 | 8.09×10-5 | 0.9960 |
2.0 (40) | 21.00 | 27.18 | -0.0284 | 0.9513 | 34.61 | 3.48×10-4 | 0.9941 |
浓度/mg·mL-1(温度/℃) | 准一级动力学 | 准二级动力学 | |||||
---|---|---|---|---|---|---|---|
qe,cal | qe,exp | k1 | R2 | qe | k2 | R2 | |
0.5 (30) | 5.60 | 6.03 | -0.0141 | 0.9417 | 9.30 | 7.70×10-4 | 0.9868 |
1.0 (30) | 9.32 | 11.32 | -0.0215 | 0.9600 | 23.32 | 2.11×10-4 | 0.9983 |
1.5 (30) | 15.95 | 26.48 | -0.0328 | 0.8836 | 69.59 | 3.85×10-5 | 0.9968 |
2.0 (30) | 18.95 | 27.67 | -0.0304 | 0.9282 | 42.28 | 1.56×10-4 | 0.9732 |
0.5 (35) | 6.50 | 6.92 | -0.0129 | 0.9857 | 15.34 | 2.73×10-4 | 0.9932 |
1.0 (35) | 10.06 | 13.01 | -0.0239 | 0.9290 | 15.77 | 6.74×10-4 | 0.9763 |
1.5 (35) | 16.43 | 24.05 | -0.0296 | 0.9305 | 58.48 | 6.03×10-5 | 0.9972 |
2.0 (35) | 19.80 | 31.60 | -0.0345 | 0.9085 | 42.37 | 1.79×10-4 | 0.9984 |
0.5 (40) | 6.80 | 9.11 | -0.0229 | 0.8413 | 17.39 | 2.74×10-4 | 0.9949 |
1.0 (40) | 10.95 | 13.52 | -0.0255 | 0.9515 | 16.57 | 8.11×10-4 | 0.9948 |
1.5 (40) | 16.70 | 23.89 | -0.0304 | 0.9475 | 52.91 | 8.09×10-5 | 0.9960 |
2.0 (40) | 21.00 | 27.18 | -0.0284 | 0.9513 | 34.61 | 3.48×10-4 | 0.9941 |
浓度/mg·mL-1(温度/℃) | Elovich动力学 | 颗粒内扩散方程 | Bangham动力学 | ||||||
---|---|---|---|---|---|---|---|---|---|
a | b | R2 | kid | C | R2 | k3 | α | R2 | |
0.5 (30) | 0.0402 | 0.513 | 0.9166 | 0.433 | -0.407 | 0.9360 | 3.17×10-3 | 0.822 | 0.9708 |
1.0 (30) | 0.0224 | 0.272 | 0.9603 | 0.830 | -0.700 | 0.9600 | 3.27×10-3 | 0.800 | 0.9892 |
1.5 (30) | 0.0102 | 0.139 | 0.9696 | 1.545 | -1.605 | 0.9424 | 2.85×10-3 | 0.919 | 0.9878 |
2.0 (30) | 0.0099 | 0.122 | 0.9487 | 1.825 | -1.591 | 0.9479 | 3.26×10-3 | 0.824 | 0.9743 |
0.5 (35) | 0.0332 | 0.446 | 0.9598 | 0.487 | -0.494 | 0.9459 | 3.00×10-3 | 0.880 | 0.9917 |
1.0 (35) | 0.0224 | 0.256 | 0.9391 | 0.903 | -0.696 | 0.9641 | 3.75×10-3 | 0.750 | 0.9869 |
1.5 (35) | 0.0109 | 0.139 | 0.9773 | 1.577 | -1.444 | 0.9522 | 3.14×10-3 | 0.879 | 0.9847 |
2.0 (35) | 0.0110 | 0.122 | 0.9766 | 1.908 | -1.296 | 0.9710 | 3.76×10-3 | 0.767 | 0.9897 |
0.5 (40) | 0.0296 | 0.375 | 0.9493 | 0.593 | -0.550 | 0.9530 | 3.48×10-3 | 0.854 | 0.9901 |
1.0 (40) | 0.0278 | 0.251 | 0.9797 | 0.994 | -0.401 | 0.9900 | 4.75×10-3 | 0.663 | 0.9967 |
1.5 (40) | 0.0116 | 0.139 | 0.9835 | 1.614 | -1.277 | 0.9594 | 3.42×10-3 | 0.844 | 0.9783 |
2.0 (40) | 0.0138 | 0.126 | 0.9855 | 1.960 | -0.797 | 0.9859 | 4.59×10-3 | 0.678 | 0.9886 |
浓度/mg·mL-1(温度/℃) | Elovich动力学 | 颗粒内扩散方程 | Bangham动力学 | ||||||
---|---|---|---|---|---|---|---|---|---|
a | b | R2 | kid | C | R2 | k3 | α | R2 | |
0.5 (30) | 0.0402 | 0.513 | 0.9166 | 0.433 | -0.407 | 0.9360 | 3.17×10-3 | 0.822 | 0.9708 |
1.0 (30) | 0.0224 | 0.272 | 0.9603 | 0.830 | -0.700 | 0.9600 | 3.27×10-3 | 0.800 | 0.9892 |
1.5 (30) | 0.0102 | 0.139 | 0.9696 | 1.545 | -1.605 | 0.9424 | 2.85×10-3 | 0.919 | 0.9878 |
2.0 (30) | 0.0099 | 0.122 | 0.9487 | 1.825 | -1.591 | 0.9479 | 3.26×10-3 | 0.824 | 0.9743 |
0.5 (35) | 0.0332 | 0.446 | 0.9598 | 0.487 | -0.494 | 0.9459 | 3.00×10-3 | 0.880 | 0.9917 |
1.0 (35) | 0.0224 | 0.256 | 0.9391 | 0.903 | -0.696 | 0.9641 | 3.75×10-3 | 0.750 | 0.9869 |
1.5 (35) | 0.0109 | 0.139 | 0.9773 | 1.577 | -1.444 | 0.9522 | 3.14×10-3 | 0.879 | 0.9847 |
2.0 (35) | 0.0110 | 0.122 | 0.9766 | 1.908 | -1.296 | 0.9710 | 3.76×10-3 | 0.767 | 0.9897 |
0.5 (40) | 0.0296 | 0.375 | 0.9493 | 0.593 | -0.550 | 0.9530 | 3.48×10-3 | 0.854 | 0.9901 |
1.0 (40) | 0.0278 | 0.251 | 0.9797 | 0.994 | -0.401 | 0.9900 | 4.75×10-3 | 0.663 | 0.9967 |
1.5 (40) | 0.0116 | 0.139 | 0.9835 | 1.614 | -1.277 | 0.9594 | 3.42×10-3 | 0.844 | 0.9783 |
2.0 (40) | 0.0138 | 0.126 | 0.9855 | 1.960 | -0.797 | 0.9859 | 4.59×10-3 | 0.678 | 0.9886 |
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