Chemical Industry and Engineering Progress ›› 2024, Vol. 43 ›› Issue (1): 407-413.DOI: 10.16085/j.issn.1000-6613.2023-1318
• Industrial catalysis • Previous Articles
SUN Jin(), CHEN Xiaozhen, LIU Mingrui, LIU Li, NIU Shikun, GUO Rong(
)
Received:
2023-08-01
Revised:
2023-10-08
Online:
2024-02-05
Published:
2024-01-20
Contact:
GUO Rong
通讯作者:
郭蓉
作者简介:
孙进(1982—),男,硕士研究生,研究方向为工业催化。E-mail:sunjin.fshy@sinopec.com。
基金资助:
CLC Number:
SUN Jin, CHEN Xiaozhen, LIU Mingrui, LIU Li, NIU Shikun, GUO Rong. Deactivation mechanism of sodium poisoning hydrodesulfurization catalyst[J]. Chemical Industry and Engineering Progress, 2024, 43(1): 407-413.
孙进, 陈晓贞, 刘名瑞, 刘丽, 牛世坤, 郭蓉. 加氢脱硫催化剂钠中毒失活机理[J]. 化工进展, 2024, 43(1): 407-413.
样品 | C质量分数/% | Na2O质量分数/% |
---|---|---|
A | 5.35 | — |
B | 5.67 | — |
C | 10.54 | — |
RA | — | 1.11 |
RB | — | 0.51 |
RC | — | 0.02 |
样品 | C质量分数/% | Na2O质量分数/% |
---|---|---|
A | 5.35 | — |
B | 5.67 | — |
C | 10.54 | — |
RA | — | 1.11 |
RB | — | 0.51 |
RC | — | 0.02 |
样品 | 比表面积/m2·g-1 | 孔容/cm3·g-1 | 平均孔径/nm | 总酸/mmol·g-1 | B酸/mmol·g-1 | L酸/mmol·g-1 | B酸/L酸 |
---|---|---|---|---|---|---|---|
新鲜催化剂 | 149.3 | 0.35 | 6.51 | — | — | — | — |
RA | 138.1 | 0.32 | 6.88 | 0.326 | 0.289 | 0.037 | 0.13 |
RB | 143.8 | 0.33 | 6.82 | 0.424 | 0.368 | 0.056 | 0.15 |
RC | 145.0 | 0.34 | 6.55 | 0.545 | 0.462 | 0.083 | 0.18 |
样品 | 比表面积/m2·g-1 | 孔容/cm3·g-1 | 平均孔径/nm | 总酸/mmol·g-1 | B酸/mmol·g-1 | L酸/mmol·g-1 | B酸/L酸 |
---|---|---|---|---|---|---|---|
新鲜催化剂 | 149.3 | 0.35 | 6.51 | — | — | — | — |
RA | 138.1 | 0.32 | 6.88 | 0.326 | 0.289 | 0.037 | 0.13 |
RB | 143.8 | 0.33 | 6.82 | 0.424 | 0.368 | 0.056 | 0.15 |
RC | 145.0 | 0.34 | 6.55 | 0.545 | 0.462 | 0.083 | 0.18 |
参数 | D1 | D2 |
---|---|---|
密度(20℃)/cm3·g-1 | 0.8525 | 0.8657 |
总硫含量/μg·g-1 | 11900 | 19400 |
馏程/℃ | ||
初馏点(IBP) | 208.5 | 210.4 |
10%~30% | 273.6~292.1 | 283.2~203.8 |
50%~70% | 303.4~313.4 | 315.5~329.1 |
90%~95% | 329.5~336.9 | 348.9~360.9 |
终馏点(FBP) | 341.8 | 371.4 |
参数 | D1 | D2 |
---|---|---|
密度(20℃)/cm3·g-1 | 0.8525 | 0.8657 |
总硫含量/μg·g-1 | 11900 | 19400 |
馏程/℃ | ||
初馏点(IBP) | 208.5 | 210.4 |
10%~30% | 273.6~292.1 | 283.2~203.8 |
50%~70% | 303.4~313.4 | 315.5~329.1 |
90%~95% | 329.5~336.9 | 348.9~360.9 |
终馏点(FBP) | 341.8 | 371.4 |
硫化物 | 相对脱硫速率 | 沸点/℃ |
---|---|---|
噻吩 | 100 | 84.2 |
苯并噻吩 | 30 | 221 |
二苯并噻吩 | 30 | 333 |
甲基二苯并噻吩 | 5 | 339~351 |
二甲基二苯并噻吩 | 1 | 357~369 |
三甲基二苯并噻吩 | 1 | 370~387 |
硫化物 | 相对脱硫速率 | 沸点/℃ |
---|---|---|
噻吩 | 100 | 84.2 |
苯并噻吩 | 30 | 221 |
二苯并噻吩 | 30 | 333 |
甲基二苯并噻吩 | 5 | 339~351 |
二甲基二苯并噻吩 | 1 | 357~369 |
三甲基二苯并噻吩 | 1 | 370~387 |
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