Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (11): 6235-6245.DOI: 10.16085/j.issn.1000-6613.2020-2356
• Materials science and technology • Previous Articles Next Articles
TANG Rui1(), ZHANG Hanbing2, LU Caimei2, LIU Kun1, WANG Zhongkai2, YU Sishan2, TONG Zhangfa1,3(), JI Junrong4
Received:
2020-11-25
Revised:
2021-03-10
Online:
2021-11-19
Published:
2021-11-05
Contact:
TONG Zhangfa
汤睿1(), 张寒冰2, 陆彩妹2, 刘坤1, 王忠凯2, 余思珊2, 童张法1,3(), 季军荣4
通讯作者:
童张法
作者简介:
汤睿(1994—),男,博士研究生,研究方向为工业废水处理。E-mail:基金资助:
CLC Number:
TANG Rui, ZHANG Hanbing, LU Caimei, LIU Kun, WANG Zhongkai, YU Sishan, TONG Zhangfa, JI Junrong. Adsorption of ciprofloxacin and tetracycline by organically modified magnetic bentonite[J]. Chemical Industry and Engineering Progress, 2021, 40(11): 6235-6245.
汤睿, 张寒冰, 陆彩妹, 刘坤, 王忠凯, 余思珊, 童张法, 季军荣. 有机磁性膨润土对环丙沙星和四环素的吸附性能[J]. 化工进展, 2021, 40(11): 6235-6245.
Add to citation manager EndNote|Ris|BibTeX
URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2020-2356
组分 | 质量分数/% |
---|---|
Al2O3 | 16.84 |
SiO2 | 61.35 |
Fe2O3 | 3.12 |
MgO | 2.63 |
Na2O | 4.79 |
CaO | 1.81 |
K2O | 0.37 |
其他 | 9.09 |
组分 | 质量分数/% |
---|---|
Al2O3 | 16.84 |
SiO2 | 61.35 |
Fe2O3 | 3.12 |
MgO | 2.63 |
Na2O | 4.79 |
CaO | 1.81 |
K2O | 0.37 |
其他 | 9.09 |
样品 | 比表面积/m2?g-1 | 孔容/cm3?g-1 | 平均孔径/nm |
---|---|---|---|
MB | 64 | 0.26 | 17 |
MB-CC | 56 | 0.74 | 26 |
样品 | 比表面积/m2?g-1 | 孔容/cm3?g-1 | 平均孔径/nm |
---|---|---|---|
MB | 64 | 0.26 | 17 |
MB-CC | 56 | 0.74 | 26 |
吸附过程 | Langmuir模型 | Freundlich模型 | qm,exp/mg·g?1 | ||||
---|---|---|---|---|---|---|---|
KL/L·mg?1 | qm,cal/mg·g?1 | R2 | Kf /mg·g?1 | 1/n | R2 | ||
MB-CC | |||||||
CIP | 1.27 | 182 | 0.999 | 51.3 | 0.41 | 0.939 | 170 |
TC | 1.31 | 189 | 0.999 | 68.2 | 0.43 | 0.955 | 179 |
MB | |||||||
CIP | 0.28 | 147 | 0.999 | 36.1 | 0.37 | 0.937 | 127 |
TC | 0.55 | 136 | 0.999 | 45.7 | 0.39 | 0.958 | 126 |
吸附过程 | Langmuir模型 | Freundlich模型 | qm,exp/mg·g?1 | ||||
---|---|---|---|---|---|---|---|
KL/L·mg?1 | qm,cal/mg·g?1 | R2 | Kf /mg·g?1 | 1/n | R2 | ||
MB-CC | |||||||
CIP | 1.27 | 182 | 0.999 | 51.3 | 0.41 | 0.939 | 170 |
TC | 1.31 | 189 | 0.999 | 68.2 | 0.43 | 0.955 | 179 |
MB | |||||||
CIP | 0.28 | 147 | 0.999 | 36.1 | 0.37 | 0.937 | 127 |
TC | 0.55 | 136 | 0.999 | 45.7 | 0.39 | 0.958 | 126 |
吸附材料 | 准一级动力学模型 | 准二级动力学模型 | qe,exp/mg·g?1 | ||||
---|---|---|---|---|---|---|---|
k1×0.01/min?1 | qe,cal/mg·g?1 | R2 | k2×0.01/g·mg?1·min?1 | qe,cal/mg·g?1 | R2 | ||
MB-CC | |||||||
CIP | 0.003 | 92 | 0.466 | 0.36 | 181 | 0.999 | 170 |
TC | 0.006 | 103 | 0.588 | 0.41 | 191 | 0.999 | 179 |
MB | |||||||
CIP | 0.002 | 68 | 0.582 | 0.32 | 102 | 0.999 | 127 |
TC | 0.005 | 77 | 0.673 | 0.35 | 119 | 0.999 | 126 |
吸附材料 | 准一级动力学模型 | 准二级动力学模型 | qe,exp/mg·g?1 | ||||
---|---|---|---|---|---|---|---|
k1×0.01/min?1 | qe,cal/mg·g?1 | R2 | k2×0.01/g·mg?1·min?1 | qe,cal/mg·g?1 | R2 | ||
MB-CC | |||||||
CIP | 0.003 | 92 | 0.466 | 0.36 | 181 | 0.999 | 170 |
TC | 0.006 | 103 | 0.588 | 0.41 | 191 | 0.999 | 179 |
MB | |||||||
CIP | 0.002 | 68 | 0.582 | 0.32 | 102 | 0.999 | 127 |
TC | 0.005 | 77 | 0.673 | 0.35 | 119 | 0.999 | 126 |
1 | OLUSEGUN S J, MOHALLEM N D S. Comparative adsorption mechanism of doxycycline and Congo red using synthesized kaolinite supported CoFe2O4 nanoparticles[J]. Environmental Pollution, 2020, 260: 114019. |
2 | 张延, 严晓菊, 孙越, 等. 中国抗生素滥用现状及其在环境中的分布情况[J]. 当代化工, 2019, 48(11): 2660-2662, 2666. |
ZHANG Yan, YAN Xiaoju, SUN Yue, et al. Current situation of antibiotic abuse in China and its residues distribution in the environment[J]. Contemporary Chemical Industry, 2019, 48(11): 2660-2662, 2666. | |
3 | 汤雨晴, 叶倩, 郑维义. 抗生素类药物的研究现状和进展[J]. 国外医药(抗生素分册), 2019, 40(4): 295-301. |
TANG Yuqing, YE Qian, ZHENG Weiyi. Research status and development of antibiotics[J]. World Notes on Antibiotics, 2019, 40(4): 295-301. | |
4 | 秦松岩, 李杭, 山丹, 等. 四环素类抗生素生产废水处理现状与研究进展[J]. 天津理工大学学报, 2016, 32(2): 50-54, 60. |
QIN Songyan, LI Hang, SHAN Dan, et al. The present situation and research progress in the treatment of tetracycline antibiotic manufacturing wastewater[J]. Journal of Tianjin University of Technology, 2016, 32(2): 50-54, 60. | |
5 | 王元宏, 魏群山, 季有知, 等. 聚硅酸铝镁锌混凝剂的制备及去除抗生素性能和机理初探[J]. 安全与环境学报, 2017, 17(3): 1057-1063. |
WANG Yuanhong, WEI Qunshan, JI Youzhi, et al. Preparation of inorganic polymer coagulant—PSAMZ and the mechanism for its antibiotics removing performance[J]. Journal of Safety and Environment, 2017, 17(3): 1057-1063. | |
6 | SOUZA P R, DOTTO G L, SALAU N P G, et al. Analysis of intraparticle diffusion on adsorption of crystal violet on bentonite[J]. Chemical Engineering Communications, 2019, 206(11): 1474-1484. |
7 | 施华顺, 韦朝海, 杨清玉, 等. 诺氟沙星水溶液的湿式氧化分解及其产物的生成途径[J]. 环境工程学报, 2011, 5(6): 1257-1262. |
SHI Huashun, WEI Chaohai, YANG Qingyu, et al. Wet-oxidized decomposition of norfloxacin solution and its product formation pathways[J]. Chinese Journal of Environmental Engineering, 2011, 5(6): 1257-1262. | |
8 | 王迎亚, 施华珍, 张寒冰, 等. 磁性柠檬酸膨润土对六价铬吸附性能的研究[J]. 高校化学工程学报, 2017, 31(3): 726-732. |
WANG Yingya, SHI Huazhen, ZHANG Hanbing, et al. Research on Cr(Ⅵ) adsorption with magnetic citric acid bentonite[J]. Journal of Chemical Engineering of Chinese Universities, 2017, 31(3): 726-732. | |
9 | 姚培, 李树白, 刘媛, 等. HTMAC/KH550/膨润土吸附剂的制备、表征及其在甲基橙废水的吸附行为[J]. 化工进展, 2017, 36(4): 1374-1380. |
YAO Pei, LI Shubai, LIU Yuan, et al. Preparation, characterization of HTMAC/KH550/bentonite adsorbent and its adsorption behavior on methyl orange wastewater[J]. Chemical Industry and Engineering Progress, 2017, 36(4): 1374-1380. | |
10 | 李敏, 徐韶足, 陈雯莉, 等. 鱼腥蓝细菌PCC 7120对Mn2+的吸附[J]. 华中农业大学学报, 2018, 37(1): 1-6. |
LI Min, XU Shaozu, CHEN Wenli, et al. Assaying Mn2+ biosorption of Anabaena sp. strain PCC 7120[J]. Journal of Huazhong Agricultural University, 2018, 37(1): 1-6. | |
11 | YU Y, CHOI Y H, CHOI J, et al. Multi-barrier approach for removing organic micropollutants using mobile water treatment systems[J]. Science of the Total Environment, 2018, 639: 331-338. |
12 | CAZZORLA C, BENSI G, BIASUCCI G, et al. Living with phenylketonuria in adulthood: the PKU ATTITUDE study[J]. Molecular Genetics and Metabolism Reports, 2018, 16: 39-45. |
13 | WANG H D, WANG L, YE S Y, et al. Construction of Bi2WO6-TiO2/starch nanocomposite films for visible-light catalytic degradation of ethylene[J]. Food Hydrocolloids, 2019, 88: 92-100. |
14 | XU L Q, XU X J, CAO G Z, et al. Optimization and assessment of Fe-electrocoagulation for the removal of potentially toxic metals from real smelting wastewater[J]. Journal of Environmental Management, 2018, 218: 129-138. |
15 | ZHENG J, LUO D J, QIAO Y H, et al. Surface complexation modeling of U(VI) sorption on GMZ bentonite in the presence of fulvic acid[J]. Radiochimica Acta, 2017, 105(1): 33-41. |
16 | FU F L, WANG Q. Removal of heavy metal ions from wastewaters: a review[J]. Journal of Environmental Management, 2011, 92(3): 407-418. |
17 | COLANGELO D, TORCHIO F, DE FAVERI D M, et al. The use of chitosan as alternative to bentonite for wine fining: effects on heat-stability, proteins, organic acids, colour, and volatile compounds in an aromatic white wine[J]. Food Chemistry, 2018, 264: 301-309. |
18 | ALGHAMDI M M, EL-ZAHHAR A A, IDRIS A M, et al. Synthesis, characterization, and application of a novel polymeric-bentonite-magnetite composite resin for water softening[J]. Separation and Purification Technology, 2019, 224: 356-365. |
19 | PENTRÁK M, HRONSKÝ V, PÁLKOVÁ H, et al. Alteration of fine fraction of bentonite from Kopernica (Slovakia) under acid treatment: a combined XRD, FTIR, MAS NMR and AES study[J]. Applied Clay Science, 2018, 163: 204-213. |
20 | SAID M, UTAMI H P, HAYATI F. Insertion of bentonite with organometallic [Fe3O(OOC6H5)6(H2O)3(NO3)·nH2O] as adsorbent of Congo red[J]. IOP Conference Series: Materials Science and Engineering, 2018, 299: 012086. |
21 | NAEIMI S, FAGHIHIAN H. Application of novel metal organic framework, MIL-53(Fe) and its magnetic hybrid: for removal of pharmaceutical pollutant, doxycycline from aqueous solutions[J]. Environmental Toxicology and Pharmacology, 2017, 53: 121-132. |
22 | AMROLLAHI A, MASSINAEI M, ZERAATKAR MOGHADDAM A. Removal of the residual xanthate from flotation plant tailings using bentonite modified by magnetic nano-particles[J]. Minerals Engineering, 2019, 134: 142-155. |
23 | KONG Y, WANG L, GE Y Y, et al. Lignin xanthate resin-bentonite clay composite as a highly effective and low-cost adsorbent for the removal of doxycycline hydrochloride antibiotic and mercury ions in water[J]. Journal of Hazardous Materials, 2019, 368: 33-41. |
24 | CHEN G N, SHAH K J, SHI L, et al. Removal of Cd(Ⅱ) and Pb(Ⅱ) ions from aqueous solutions by synthetic mineral adsorbent: performance and mechanisms[J]. Applied Surface Science, 2017, 409: 296-305. |
25 | DE MELO FIORI A P S, CAMANI P H, SANTOS ROSA D DOS, et al. Combined effects of clay minerals and polyethylene glycol in the mechanical and water barrier properties of carboxymethylcellulose films[J]. Industrial Crops and Products, 2019, 140: 111644. |
26 | GONCHARUK V V, DUBROVINA L V, MAKAROVA E V, et al. Bound water in hydrogels of carboxymethylcellulose and bentonite[J]. Journal of Applied Spectroscopy, 2018, 85(4): 594-599. |
27 | 文永林, 刘攀, 汤琪. 农林废弃物吸附脱除废水中重金属研究进展[J]. 化工进展, 2016, 35(4): 1208-1215. |
WEN Yonglin, LIU Pan, TANG Qi. Review of removal of heavy metal ions from wastewater with agricultural and forestry waste as adsorbent[J]. Chemical Industry and Engineering Progress, 2016, 35(4): 1208-1215. | |
28 | JIN M J, LONG M C, SU H R, et al. Magnetically separable maghemite/montmorillonite composite as an efficient heterogeneous Fenton-like catalyst for phenol degradation[J]. Environmental Science and Pollution Research, 2017, 24(2): 1926-1937. |
29 | OLIVO-ALANIS D, GARCIA-REYES R B, ALVAREZ L H, et al. Mechanism of anaerobic bio-reduction of azo dye assisted with lawsone-immobilized activated carbon[J]. Journal of Hazardous Materials, 2018, 347: 423-430. |
30 | ZAIDI S, CHAABANE T, SIVASANKAR V, et al. Performance efficiency of electro-coagulation coupled electro-flotation process (EC-EF) versus adsorption process in doxycycline removal from aqueous solutions[J]. Process Safety and Environmental Protection, 2016, 102: 450-461. |
31 | 曹晓强, 张燕, 邱俊, 等. 膨润土对溶液中镍离子的吸附特性及机理[J]. 硅酸盐学报, 2014, 42(11): 1448-1454. |
CAO Xiaoqiang, ZHANG Yan, QIU Jun, et al. Adsorption and mechanism of nickel ions from aqueous solution by bentonite[J]. Journal of the Chinese Ceramic Society, 2014, 42(11): 1448-1454. | |
32 | ELKHALIFAH A E I, BUSTAM M A, AZMI M S, et al. Carbon dioxide retention on bentonite clay adsorbents modified by mono-, di- and triethanolamine compounds[J]. Advanced Materials Research, 2014, 917: 115-122. |
33 | 邓雅雯, 晏彩霞, 聂明华, 等. 生物炭对抗生素的吸附/解吸研究进展[J]. 环境污染与防治, 2020, 42(3): 376-384. |
DENG Yawen, YAN Caixia, NIE Minghua, et al. Study on the antibiotic adsorption/desorption of biochar: a review[J]. Environmental Pollution & Control, 2020, 42(3): 376-384. | |
34 | WANG J Q, CHEN Z, SHAO D D, et al. Adsorption of U(VI) on bentonite in simulation environmental conditions[J]. Journal of Molecular Liquids, 2017, 242: 678-684. |
35 | 李亚娟, 赵传起, 洪沛东, 等. 磁性还原石墨烯的制备及其对抗生素的吸附性能[J]. 环境工程学报, 2018, 12(1): 15-24. |
LI Yajuan, ZHAO Chuanqi, HONG Peidong, et al. Fabrication of magnetic reduced graphene and its adsorption performance for antibiotics[J]. Chinese Journal of Environmental Engineering, 2018, 12(1): 15-24. | |
36 | 李飞虹, 李霞章, 陆晓旺, 等. 钒掺杂磷酸铋/蒙脱石复合材料的制备及可见光催化脱硫性能[J]. 硅酸盐学报, 2018, 46(2): 275-280. |
LI Feihong, LI Xiazhang, LU Xiaowang, et al. Preparation of vanadium doped bismuth phosphate/montmoril lonite nanocomposites for visible light photocatalytic desulfurization[J]. Journal of the Chinese Ceramic Society, 2018, 46(2): 275-280. | |
37 | 马茜茜, 吴天威, 赵明月, 等. ATP@Fe3O4复合材料催化过硫酸盐降解四环素[J]. 环境工程学报, 2020, 14(9): 2463-2473. |
MA Xixi, WU Tianwei, ZHAO Mingyue, et al. Catalytic degradation of tetracycline by ATP@Fe3O4 composite material activated persulfate[J]. Chinese Journal of Environmental Engineering, 2020, 14(9): 2463-2473. |
[1] | WANG Shengyan, DENG Shuai, ZHAO Ruikai. Research progress on carbon dioxide capture technology based on electric swing adsorption [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 233-245. |
[2] | CUI Shoucheng, XU Hongbo, PENG Nan. Simulation analysis of two MOFs materials for O2/He adsorption separation [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 382-390. |
[3] | CHEN Chongming, CHEN Qiu, GONG Yunqian, CHE Kai, YU Jinxing, SUN Nannan. Research progresses on zeolite-based CO2 adsorbents [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 411-419. |
[4] | XU Chunshu, YAO Qingda, LIANG Yongxian, ZHOU Hualong. Research progress on functionalization strategies of covalent organic frame materials and its adsorption properties for Hg(Ⅱ) and Cr(Ⅵ) [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 461-478. |
[5] | GU Yongzheng, ZHANG Yongsheng. Dynamic behavior and kinetic model of Hg0 adsorption by HBr-modified fly ash [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 498-509. |
[6] | GUO Qiang, ZHAO Wenkai, XIAO Yonghou. Numerical simulation of enhancing fluid perturbation to improve separation of dimethyl sulfide/nitrogen via pressure swing adsorption [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 64-72. |
[7] | GE Yafen, SUN Yu, XIAO Peng, LIU Qi, LIU Bo, SUN Chengying, GONG Yanjun. Research progress of zeolite for VOCs removal [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4716-4730. |
[8] | YANG Ying, HOU Haojie, HUANG Rui, CUI Yu, WANG Bing, LIU Jian, BAO Weiren, CHANG Liping, WANG Jiancheng, HAN Lina. Coal tar phenol-based carbon nanosphere prepared by Stöber method for adsorption of CO2 [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 5011-5018. |
[9] | ZHANG Zhen, LI Dan, CHEN Chen, WU Jinglan, YING Hanjie, QIAO Hao. Separation and purification of salivary acids with adsorption resin [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4153-4158. |
[10] | JIANG Jing, CHEN Xiaoyu, ZHANG Ruiyan, SHENG Guangyao. Research progress of manganese-loaded biochar preparation and its application in environmental remediation [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4385-4397. |
[11] | YU Jingwen, SONG Luna, LIU Yanchao, LYU Ruidong, WU Mengmeng, FENG Yu, LI Zhong, MI Jie. An indole-bearing hypercrosslinked polymer In-HCP for iodine adsorption from water [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3674-3683. |
[12] | LI Yanling, ZHUO Zhen, CHI Liang, CHEN Xi, SUN Tanglei, LIU Peng, LEI Tingzhou. Research progress on preparation and application of nitrogen-doped biochar [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3720-3735. |
[13] | BAI Yadi, DENG Shuai, ZHAO Ruikai, ZHAO Li, YANG Yingxia. Exploration on standardized test scheme and experimental performance of temperature swing adsorption carbon capture unit [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3834-3846. |
[14] | ZHANG Xuewei, HUANG Yaji, XU Yueyang, CHENG Haoqiang, ZHU Zhicheng, LI Jinlei, DING Xueyu, WANG Sheng, ZHANG Rongchu. Adsorption characteristics of SO3 from coal flue gas by alkaline adsorbent [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3855-3864. |
[15] | WANG Zhicai, LIU Weiwei, ZHOU Cong, PAN Chunxiu, YAN Honglei, LI Zhanku, YAN Jingchong, REN Shibiao, LEI Zhiping, SHUI Hengfu. Synthesis and performance of a superplasticizer based on coal-based humic acid [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3634-3642. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 Copyright © Chemical Industry and Engineering Progress, All Rights Reserved. E-mail: hgjz@cip.com.cn Powered by Beijing Magtech Co. Ltd |