Preparation and adsorption performance of rosin-based amination polymer microspheres

doi:10.16085/j.issn.1000-6613.2017-1031

Chemical Industry and Engineering Progress ›› 2018, Vol. 37 ›› Issue (03): 1105-1110.DOI: 10.16085/j.issn.1000-6613.2017-1031

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Preparation and adsorption performance of rosin-based amination polymer microspheres

BIAN Feng¹, YU Caili¹, ZHANG Shufen^1,2, CHEN Yong¹, XU Jianben¹, ZHANG Faai³

1 College of Chemistry and Biology Engineering, Guilin University of Technology, Guilin 541004, Guangxi, China;
2 State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116204, Liaoning, China;
3 College of Material Science and Engineering, Guilin University of Technology, Guilin 541004, Guangxi, China

Received:2017-05-31 Revised:2017-09-17 Online:2018-03-05 Published:2018-03-05

松香基氨基化聚合物微球的制备及吸附性能

边峰¹, 余彩莉¹, 张淑芬^1,2, 陈勇¹, 许建本¹, 张发爱³

1 桂林理工大学化学与生物工程学院, 广西桂林 541004;
2 大连理工大学精细化工重点实验室, 辽宁大连 116024;
3 桂林理工大学材料科学与工程学院, 广西桂林 541004

通讯作者: 张发爱,教授,主要从事聚合物纳米复合材料和天然高分子材料研究。
作者简介:边峰(1992-),男,硕士研究生。E-mail:bianfengyb@163.com。
基金资助:
国家自然科学基金（31160148）、广西自然科学基金重点项目（2012GXNSFDA053006）及广西特聘专家专项项目。

Abstract

Abstract: Amino silane coupling agent(KH-792) was used to modify rosin-based hydroxylated polymer microspheres,the effect of reaction temperature,reaction time,and the amount of KH-792 on the performance of the microspheres was studied. The polymer microspheres were characterized by Fourier Transform Infrared Spectroscope(FTIR),Thermogravimetry Analysis(TGA),Scanning Electron Microscope(SEM) and X-ray Photoelectron Spectroscopy(XPS),amino contents of the microspheres were tested by the conductometric titration method. The adsorption of the ethyl violet on the polymeric microspheres with different amino contents was investigated. The results showed that the rosin-based amination polymer microspheres were prepared successfully,which possessed good spherical shapes and monodispersities. The thermal stability of the polymer microspheres was higher than that of the hydroxylated polymer microspheres. The amino content of the microspheres was 181 μmol/g when the amount of KH-792 was 70%,based on the hydroxylated polymer microspheres,after reaction at 90℃ for 10h. For 5min,the maximum adsorption capacity of the microspheres to the ethyl violet was 57.02mg/g at 328K,with the ratio of the solid to liquid at 1 g/L and the pH=9.5.

Key words: silane coupling agent, amination, rosin, polymer microspheres, adsorption, ethyl violet

摘要： 利用氨基硅烷偶联剂（KH-792）对松香基羟基化聚合物微球进行接枝改性，研究了反应温度、反应时间和KH-792用量对聚合物微球性能的影响。利用红外光谱（FTIR）、热重分析（TGA）、扫描电镜（SEM）和X-射线光电子能谱（XPS）对聚合物微球进行测试表征，利用电导滴定法测定了聚合物微球的氨基含量。探讨了不同氨基含量的聚合物微球对乙基紫的吸附作用。结果表明：成功制备了松香基氨基化聚合物微球，改性前后聚合物微球形态均无明显变化且球形及单分散性好，热稳定性高于松香基羟基化聚合物微球。较优制备条件为：KH-792用量为松香基羟基化聚合物微球质量的70%，在90℃下反应10h，聚合物微球氨基含量达到181μmol/g。当固液比为1 g/L，pH=9.5，在328 K下吸附5min时，微球对乙基紫的吸附量为57.02 mg/g。

关键词: 硅烷偶联剂, 氨基化, 松香, 聚合物微球, 吸附, 乙基紫

CLC Number:

TQ316.6⁺5

BIAN Feng, YU Caili, ZHANG Shufen, CHEN Yong, XU Jianben, ZHANG Faai. Preparation and adsorption performance of rosin-based amination polymer microspheres[J]. Chemical Industry and Engineering Progress, 2018, 37(03): 1105-1110.

边峰, 余彩莉, 张淑芬, 陈勇, 许建本, 张发爱. 松香基氨基化聚合物微球的制备及吸附性能[J]. 化工进展, 2018, 37(03): 1105-1110.

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Preparation and adsorption performance of rosin-based amination polymer microspheres

松香基氨基化聚合物微球的制备及吸附性能

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