餐饮油烟中典型VOCs催化氧化研究进展

doi:10.16085/j.issn.1000-6613.2020-2039

化工进展 ›› 2021, Vol. 40 ›› Issue (10): 5730-5746.DOI: 10.16085/j.issn.1000-6613.2020-2039

餐饮油烟中典型VOCs催化氧化研究进展

隗晶慧¹(), 冯勇超¹, 于庆君¹^,²(), 易红宏¹^,², 唐晓龙¹^,², 张媛媛¹, 孟宪政¹, 袁雨婷¹

^1.北京科技大学能源与环境工程学院，北京 100083
^2.工业典型污染物资源化处理北京市重点实验室，北京 100083

收稿日期:2020-10-10 修回日期:2021-03-17 出版日期:2021-10-10 发布日期:2021-10-25
通讯作者: 于庆君
作者简介:隗晶慧（1996—），女，硕士研究生，研究方向为大气污染控制。E-mail：weijh0523@163.com。
基金资助:
北京市科技计划（首都蓝天行动培育专项）(Z181100005418008);中央高校基本科研业务费专项资金(FRF-TP-18-011A3);中央引导地方科技发展专项资金(19943816G);重质油国家重点实验室开放基金(SKLOP202002001)

Research progress of catalytic oxidation of typical VOCs in cooking oil fumes

WEI Jinghui¹(), FENG Yongchao¹, YU Qingjun¹^,²(), YI Honghong¹^,², TANG Xiaolong¹^,², ZHANG Yuanyuan¹, MENG Xianzheng¹, YUAN Yuting¹

^1.School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China
^2.Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants, Beijing 100083, China

Received:2020-10-10 Revised:2021-03-17 Online:2021-10-10 Published:2021-10-25
Contact: YU Qingjun

摘要/Abstract

摘要：

近年来，餐饮油烟逐渐成为城市大气污染的主要来源之一，油烟中挥发性有机化合物（VOCs）对人体及环境均产生非常大的危害，对其治理刻不容缓。催化燃烧技术因具备去除效率高、无二次污染等优点在有机废气治理方面有着广阔的应用前景。鉴于此，本文首先总结并分析了油烟中典型挥发性有机物的成分，发现油烟中烃类、醛酮类污染物含量较高，其次包括酸酯类、醇类和少量的多环芳烃类污染物。在此基础上，重点综述了催化燃烧技术对净化上述典型挥发性有机污染物的研究进展，并对近年来常用的催化剂包括贵金属催化剂、非贵金属催化剂及特定结构的催化剂进行了归纳和整理。最后结合油烟VOCs成分及其特点，总结了不同种类型的催化剂在油烟治理中的适用性，并对催化燃烧技术在油烟治理方面的研究前景作出了展望。

关键词: 餐饮油烟, 催化氧化, 烃, 醛酮, 酸酯, 挥发性有机化合物

Abstract:

In recent years, cooking oil fumes (COFs) have gradually become a major source of air pollution in cities. Volatile organic compounds (VOCs) in cooking oil fumes do great harm to both human body and environment, which need to be purified as much as possible. Catalytic combustion is an efficient and widely used technology for removing various organic compounds due to its high removal efficiency as well as environment friendliness. In this paper, the compositions of typical volatile organic compounds in COFs were firstly summarized and analyzed based recent researches. It was found that hydrocarbons, aldehydes and ketones are the major components in COFs, followed by esters, alcohols and a small amount of polycyclic aromatic hydrocarbons. Then, the research development on the catalytic oxidation of these typical VOCs in COFs was reviewed systemically. Particularly, the catalysts commonly used for the catalytic combustion, including precious metal catalysts, non-precious metal catalysts and catalysts with specific structure, were summarized. Finally, the feasibility of different types of catalysts for purifying the VOCs from COFs was analyzed based on the review above. Moreover, the application of catalytic combustion technology in the treatment of COFs was prospected.

Key words: cooking oil fumes (COFs), catalytic oxidation, hydrocarbon, aldehyde ketone, ester, volatile organic compounds (VOCs)

中图分类号:

X511

隗晶慧, 冯勇超, 于庆君, 易红宏, 唐晓龙, 张媛媛, 孟宪政, 袁雨婷. 餐饮油烟中典型VOCs催化氧化研究进展[J]. 化工进展, 2021, 40(10): 5730-5746.

WEI Jinghui, FENG Yongchao, YU Qingjun, YI Honghong, TANG Xiaolong, ZHANG Yuanyuan, MENG Xianzheng, YUAN Yuting. Research progress of catalytic oxidation of typical VOCs in cooking oil fumes[J]. Chemical Industry and Engineering Progress, 2021, 40(10): 5730-5746.

图/表 14

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VOCs	组分	油烟来源	参考文献（年份）
烃类（49%~100%）	正庚烷、正辛烷、正戊烷、辛烯、柠檬烯、庚烯、甲苯、二甲苯、乙苯等	花生油、葵花子油、大豆油、调和油、橄榄油	［13］（2013）
	十二烷、十三烷、十五烷、十六烷、十二烷烯、十六烷烯、十七烷烯、十八烷烯、十基环氧己烷、壬基环丙烷等	大豆油	［14］（2002）
	十一烷、十二烷、十八烷、二十烷、甲苯、二甲苯、丙乙烯等	大豆油、菜籽油、玉米油、花生油	［23］（2012）
	正己烷、甲基环戊烷、环己烷、正庚烷、苯、甲苯、乙苯等	大豆油、调和油、花生油	［24］（2020）
醛酮类（50%~80%）	戊醛、己醛、庚烯醛、壬醛、庚醛、丙烯醛、癸烯醛等	花生油、葵花子油、大豆油、调和油、橄榄油等	［13］（2013）
	甲醛、丙醛、戊醛、丁烯醛等	大豆油	［14］（2002）
	己醛、己烯醛、庚醛、庚烯醛、辛醛、庚二烯醛等	色拉油、猪油	［21］（2001）
	正己醛、2-乙基己醛、正辛醛、正壬醛、正癸醛等	大豆油、调和油、花生油	［24］（2020）
	己醛、3-甲基-2-丁烯醛、庚醛、辛醛等	菜籽油、色拉油、豆油、猪油	［15］（2010）
酸酯类	棕榈酸、油酸乙酯等	花生油、葵花子油、大豆油、调和油、橄榄油等	［13］（2013）
酸酯类	苯二甲酸二丁酯、壬酸甲酯、9-十八碳烯酸甲酯、15-十八碳烯酸甲酯、油酸、亚麻酸等	大豆油	［14］（2002）
醇类	戊醇、乙基乙醇、十二醇等	花生油、葵花子油、大豆油、调和油、橄榄油	［13］（2013）

VOCs	组分	油烟来源	参考文献（年份）
烃类（49%~100%）	正庚烷、正辛烷、正戊烷、辛烯、柠檬烯、庚烯、甲苯、二甲苯、乙苯等	花生油、葵花子油、大豆油、调和油、橄榄油	［13］（2013）
	十二烷、十三烷、十五烷、十六烷、十二烷烯、十六烷烯、十七烷烯、十八烷烯、十基环氧己烷、壬基环丙烷等	大豆油	［14］（2002）
	十一烷、十二烷、十八烷、二十烷、甲苯、二甲苯、丙乙烯等	大豆油、菜籽油、玉米油、花生油	［23］（2012）
	正己烷、甲基环戊烷、环己烷、正庚烷、苯、甲苯、乙苯等	大豆油、调和油、花生油	［24］（2020）
醛酮类（50%~80%）	戊醛、己醛、庚烯醛、壬醛、庚醛、丙烯醛、癸烯醛等	花生油、葵花子油、大豆油、调和油、橄榄油等	［13］（2013）
	甲醛、丙醛、戊醛、丁烯醛等	大豆油	［14］（2002）
	己醛、己烯醛、庚醛、庚烯醛、辛醛、庚二烯醛等	色拉油、猪油	［21］（2001）
	正己醛、2-乙基己醛、正辛醛、正壬醛、正癸醛等	大豆油、调和油、花生油	［24］（2020）
	己醛、3-甲基-2-丁烯醛、庚醛、辛醛等	菜籽油、色拉油、豆油、猪油	［15］（2010）
酸酯类	棕榈酸、油酸乙酯等	花生油、葵花子油、大豆油、调和油、橄榄油等	［13］（2013）
酸酯类	苯二甲酸二丁酯、壬酸甲酯、9-十八碳烯酸甲酯、15-十八碳烯酸甲酯、油酸、亚麻酸等	大豆油	［14］（2002）
醇类	戊醇、乙基乙醇、十二醇等	花生油、葵花子油、大豆油、调和油、橄榄油	［13］（2013）

催化剂	污染物	体积分数 /×10^-6	空速 /h^-1	转化温度 /℃	转化率 /%	参考文献
Au/CeO₂	丙烯	1000	35000	100	90	［32］
CeO₂/Au/Al₂O₃	正己烷	120	9700	370	100	［35］
Mn-Pt/Al₂O₃	正己烷	1500	17500	247	80	［36］
Cu₁Co₄	正庚烷	1800	15000	185.61	90	［42］
La₁Co₄	正庚烷	1800	15000	152	90	［43］
Mn_0.9Ce_0.1	正庚烷	1000	11000	330	90	［44］

催化剂	污染物	体积分数 /×10^-6	空速 /h^-1	转化温度 /℃	转化率 /%	参考文献
Au/CeO₂	丙烯	1000	35000	100	90	［32］
CeO₂/Au/Al₂O₃	正己烷	120	9700	370	100	［35］
Mn-Pt/Al₂O₃	正己烷	1500	17500	247	80	［36］
Cu₁Co₄	正庚烷	1800	15000	185.61	90	［42］
La₁Co₄	正庚烷	1800	15000	152	90	［43］
Mn_0.9Ce_0.1	正庚烷	1000	11000	330	90	［44］

催化剂	污染物	体积分数/×10^-6	空速/h^-1	转化温度/℃	转化率/%	参考文献
Pt/Al₂O₃	甲苯	1000	24000	180	100	［47］
Pt-R/meso-KZSM-5	甲苯	1000	60000	175	98	［48］
Pt-1.2/Al₂O₃	苯	2800	32000	145	99	［49］
Pt-1.9/ZSM-5	甲苯	1000	3000	155	98	［50］
Pt/MnO₂（单原子）	甲苯	10	300	80	100	［53］
Pt/meso-Fe₂O₃（单原子）	苯	1000	20000	198	90	［54］
Pt-SA/MgO	甲苯	1000	36000	220	90	［55］
CeO₂（棒状）	邻二甲苯	250	60000	239	90	［59］
Pt/CeO₂（棒状）	甲苯	1000	48000	150	90	［60］
MnO₂（棒状）	甲苯	800	99200	176	90	［61］

餐饮油烟中典型VOCs催化氧化研究进展

Research progress of catalytic oxidation of typical VOCs in cooking oil fumes

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催化剂	污染物	体积分数 /×10^-6	空速 /h^-1	转化温度 /℃	转化率 /%	参考文献
Pt-Ce/TiO₂	丙酮	1000	30000	243	100	［63］
MnCe/Al-MSP	乙醛	—	18000	150	100	［66］
MnO_x/TiO₂	丙酮	500	36000	290	90	［71］
Cu15-Mn15/TiO₂	己醛	500	25000	225	90	［68］
MnCe/Al-MSP	丙酮	1000	15000	195	99	［70］
SrMn_0.8Ce_0.2O₃	丙酮	1000	5100	200	90	［69］
5∶1CoAlO-300	丙酮	1000	33000	222	90	［72］
5∶1CoAlO-200	丙酮	1000	33000	225	90	［72］

项目	转化温度/℃
项目	甲苯	丙酮	乙酸乙酯
单组分
T₅₀	155	150	125
T₉₀	270	252	223
双组分
T₅₀	164	163	133
T₉₀	290	299	237

催化剂	污染物	体积分数/×10^-6	空速/h^-1	转化温度/℃	转化率/%	参考文献
0.1Pd/γ-Al₂O₃	油烟	—	28000	360	93.1	［93］
2%CeO₂- 0.1Pd/γ-Al₂O₃	油烟	—	28000	300	93.7	［93］
Fe-MEL	油烟	2000	20000	400	96	［97］
La_0.8Ce_0.2CoO₃/Al₂O₃	油烟	—	—	300	88	［98］
Mn-MEL	油烟	2000	20000	400	99	［96］
Mn/堇青石	油烟	5000	12000	400	87.8	［94］
Mn-CeO_x/MeO_x	油烟	1500	12000	400	93.6	［95］

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