合成气经含氧化合物中间体一步法制芳烃研究进展

doi:10.16085/j.issn.1000-6613.2020-2069

化工进展 ›› 2021, Vol. 40 ›› Issue (10): 5535-5546.DOI: 10.16085/j.issn.1000-6613.2020-2069

合成气经含氧化合物中间体一步法制芳烃研究进展

尚蕴山¹(), 王前进², 杨加义³, 袁德林¹, 张凡¹, 刘华¹, 邢爱华¹(), 季生福⁴

^1.北京低碳清洁能源研究院，北京 102209
^2.中国矿业大学(北京)化学与环境工程学院，北京 100083
^3.宁夏煤业有限责任公司煤制油分公司，宁夏银川 751400
^4.北京化工大学化学工程学院，北京 100029

收稿日期:2020-10-14 修回日期:2021-01-07 出版日期:2021-10-10 发布日期:2021-10-25
通讯作者: 邢爱华
作者简介:尚蕴山（1986—），男，博士，研究方向为合成气一步法制高附加值烃类催化剂开发。E-mail：yunshan.shang@chnenergy.com.cn。

Recent advance in directing synthesis of aromatic hydrocarbon from syngas via oxygenated compound intermediates

SHANG Yunshan¹(), WANG Qianjin², YANG Jiayi³, YUAN Delin¹, ZHANG Fan¹, LIU Hua¹, XING Aihua¹(), JI Shengfu⁴

^1.National Institute of Clean-and-Low-Carbon Energy Beijing, Beijing 102209, China
^2.School of Chemical & Environmental Engineering, China University of Mining and Technology-Beijing, Beijing 100083, China
^3.Shenhua Ningxia Coal Industry Group Co. , Ltd. , Yinchuan 751400, Ningxia, China
^4.School of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Received:2020-10-14 Revised:2021-01-07 Online:2021-10-10 Published:2021-10-25
Contact: XING Aihua

摘要/Abstract

摘要：

相比于合成气（CO/H₂）经甲醇制芳烃的路线，合成气一步法制芳烃（STA）具有路线短、设备投资低等优势，是一条具有广阔应用前景的技术路线。本文首先简单陈述了合成气一步法制芳烃的基本过程，详细总结了合成气一步法制芳烃催化剂开发的进展。重点讨论了金属氧化物组成、双金属配比、晶型晶粒尺寸、氧化物与分子筛的配比以及分子筛的酸性、扩散性等物化性质对反应性能的影响规律。然后归纳了反应温度、反应压力、反应空速等反应工艺条件对反应性能的影响规律。接着总结了双功能催化剂上含氧中间体的形态及其形成机理，同时阐述了催化剂的失活研究以及抑制CO₂选择性的方法。最后分析了合成气一步法制芳烃存在的问题和面临的挑战，指出高性能催化剂的开发是今后的主要研究方向。

关键词: 合成气, 芳烃, 双功能催化剂, 催化（作用）, 反应中间体, 机理

Abstract:

Compared with the syngas to aromatics through methanol route, the one-step syngas to aromatics (namely STA) is a very promising non-petroleum base route, because of its advantages of low cost and short process. In this paper, the research progresses in the development of bi-functional catalyst for the one-step synthesis of aromatics were reviewed. Firstly, the process of one-step conversion of syngas to aromatic was introduced, with the focus on the preparing methods of various catalysts used. The impacts of the physical and chemical properties of metal oxide and zeolite on the catalytic behavior were summarized, including the composition of metal oxides, ratio of two metals, crystal morphology, crystal size, ratio of metal oxides to zeolite, and acidity and diffusivity of zeolite. Furthermore, it introduced the forms and formation mechanisms of different intermediates on bifunctional catalyst. Finally, this paper reviewed current issues and challenges on one-step conversion of syngas to aromatic, and pointed out that the development of high-performance catalyst is the main research direction in the future.

Key words: syngas, aromatic, bi-functional catalyst, catalysis, intermediate, mechanism

中图分类号:

TQ241

尚蕴山, 王前进, 杨加义, 袁德林, 张凡, 刘华, 邢爱华, 季生福. 合成气经含氧化合物中间体一步法制芳烃研究进展[J]. 化工进展, 2021, 40(10): 5535-5546.

SHANG Yunshan, WANG Qianjin, YANG Jiayi, YUAN Delin, ZHANG Fan, LIU Hua, XING Aihua, JI Shengfu. Recent advance in directing synthesis of aromatic hydrocarbon from syngas via oxygenated compound intermediates[J]. Chemical Industry and Engineering Progress, 2021, 40(10): 5535-5546.

图/表 6

参考文献 49

1	CHANG C D, SILVESTRI A J. The conversion of methanol and other O-compounds to hydrocarbons over zeolite catalysts[J]. Journal of Catalysis, 1977, 47(2): 249-259.
2	CHANG C D, LANG W H, SILVESTRI A J. Synthesis gas conversion to aromatic hydrocarbons[J]. Journal of Catalysis, 1979, 56(2): 268-273.
3	YAN Q, DOAN P T, TOGHIANI H, et al. Synthesis gas to hydrocarbons over CuO-CoO-Cr₂O₃/H-ZSM-5 bifunctional catalysts[J]. The Journal of Physical Chemistry C, 2008, 112(31): 11847-11858.
4	YANG J, PAN X, JIAO F, et al. Direct conversion of syngas to aromatics[J]. Chemical Communications, 2017, 53(81): 11146-11149.
5	ARSLAN M T, QURESHI B A, GILANI S Z A, et al. Single-step conversion of H₂-deficient syngas into high yield of tetramethylbenzene[J]. ACS Catalysis, 2019, 9(3): 2203-2212.
6	XU Y, LIU J, WANG J, et al. Selective conversion of syngas to aromatics over Fe₃O₄@MnO₂ and hollow HZSM-5 bifunctional catalysts[J]. ACS Catalysis, 2019, 9(6): 5147-5156.
7	ZHAO B, ZHAI P, WANG P, et al. Direct transformation of syngas to aromatics over Na-Zn-Fe₅C₂ and hierarchical HZSM-5 tandem catalysts[J]. Chem., 2017, 3(2): 323-333.
8	XU Y, WANG J, MA G, et al. Hollow zeolite nanoparticles combined with Fe₃O₄@MnO₂ tandem catalyst for converting syngas to aromatics-rich gasoline[J]. ACS Applied Nano Materials, 2020, 3(3): 2857-2866.
9	SUN T, LIN T, AN Y, et al. Syngas conversion to aromatics over the Co₂C-based catalyst and HZSM-5 via a tandem system[J]. Industrial & Engineering Chemistry Research, 2020, 59(10): 4419-4427.
10	LI M, NAWAZ M A, SONG G, et al. Influential role of elemental migration in a composite iron-zeolite catalyst for the synthesis of aromatics from syngas[J]. Industrial & Engineering Chemistry Research, 2020, 59(19): 9043-9054.
11	WANG Y, ZHAN W, CHEN Z, et al. Advanced 3D hollow-out ZnZrO@C combined with hierarchical zeolite for highly active and selective CO hydrogenation to aromatics[J]. ACS Catalysis, 2020, 10(13): 7177-7187.
12	YANG X, SUN T, MA J, et al. The Influence of intimacy on the ‘iterative reactions’ during OX-ZEO process for aromatic production[J]. Journal of Energy Chemistry, 2019, 35: 60-65.
13	YANG J, GONG K, MIAO D, et al. Enhanced aromatic selectivity by the sheet-like ZSM-5 in syngas conversion[J]. Journal of Energy Chemistry, 2019, 35: 44-48.
14	LIU C, LIU S, ZHOU H, et al. Selective conversion of syngas to aromatics over metal oxide/HZSM-5 catalyst by matching the activity between CO hydrogenation and aromatization[J]. Applied Catalysis A: General, 2019, 585: 117206.
15	ZHANG P, TAN L, YANG G, et al. One-pass selective conversion of syngas to para-xylene[J]. Chemical Science, 2017, 8(12): 7941-7946.
16	SONG W, HOU Y, CHEN Z, et al. Process simulation of the syngas-to-aromatics processes: technical economics aspects[J]. Chemical Engineering Science, 2020, 212: 115328.
17	YANG X, SU X, CHEN D, et al. Direct conversion of syngas to aromatics: a review of recent studies[J]. Chinese Journal of Catalysis, 2020, 41(4): 561-573.
18	KASIPANDI S, BAE J W. Recent advances in direct synthesis of value-added aromatic chemicals from syngas by cascade reactions over bifunctional catalysts[J]. Advanced Materials, 2019, 31(34): 1803390.
19	NIMZ M, LIETZ G, VöLTER J, et al. Direct conversion of syngas to aromatics on FePd/SiO₂ catalyst[J]. Catalysis Letters, 1988, 1(4): 93-98.
20	FU Y, NI Y, ZHU W, et al. Enhancing syngas-to-aromatics performance of ZnO&H-ZSM-5 composite catalyst via Mn modulation[J]. Journal of Catalysis, 2020, 383: 97-102.
21	杨成, 张成华, 许健, 等. 氧化锆催化合成气直接转化制芳烃[J]. 燃料化学学报, 2016, 44(7): 837-844.
	YANG Cheng, ZHANG Chenghua, XU Jian, et al. One-step catalytic conversion of syngas to aromatics over ZrO₂ catalyst[J]. Journal of Fuel Chemistry and Technology, 2016, 44(7): 837-844.
22	LIU J, HE Y, YAN L, et al. Nano-sized ZrO₂ derived from metal-organic frameworks and their catalytic performance for aromatic synthesis from syngas[J]. Catalysis Science & Technology, 2019, 9(11): 2982-2992.
23	LIU J, HE Y, YAN L, et al. Nano-ZrO₂ as hydrogenation phase in bi-functional catalyst for syngas aromatization[J]. Fuel, 2020, 263: 116803.
24	GILANI S Z A, LU L, ARSLAN M T, et al. Two-way desorption coupling to enhance the conversion of syngas into aromatics by MnO/H-ZSM-5[J]. Catalysis Science & Technology, 2020, 10: 3366-3375.
25	YANG T, CHENG L, LI N, et al. Effect of metal active sites on the product distribution over composite catalysts in the direct synthesis of aromatics from syngas[J]. Industrial & Engineering Chemistry Research, 2017, 56(41): 11763-11772.
26	CHENG K, ZHOU W, KANG J, et al. Bifunctional catalysts for one-step conversion of syngas into aromatics with excellent selectivity and stability[J]. Chem., 2017, 3(2): 334-347.
27	HUANG Z, WANG S, QIN F, et al. Ceria-zirconia/zeolite bifunctional catalyst for highly selective conversion of syngas into aromatics[J]. ChemCatChem, 2018, 10(20): 4519-4524.
28	ZHOU W, SHI S, WANG Y, et al. Selective conversion of syngas to aromatics over a Mo-ZrO₂/H-ZSM-5 bifunctional catalyst[J]. ChemCatChem, 2019, 11(6): 1681-1688.
29	MIAO D, DING Y, YU T, et al. Selective synthesis of benzene, toluene, and xylenes from syngas[J]. ACS Catalysis, 2020: 7389-7397.
30	SANTOS V P, POLLEFEYT G, YANCEY D F, et al. Direct conversion of syngas to light olefins (C₂-C₃) over a tandem catalyst CrZn-SAPO-34: tailoring activity and stability by varying the Cr/Zn ratio and calcination temperature[J]. Journal of Catalysis, 2020, 381, 108-120.
31	ZHOU C, SHI J, ZHOU W, et al. Highly active ZnO-ZrO₂ aerogels integrated with H-ZSM-5 for aromatics synthesis from carbon dioxide[J]. ACS Catalysis, 2020, 10(1): 302-310.
32	ZHOU W, ZHOU C, YIN H, et al. Direct conversion of syngas into aromatics over a bifunctional catalyst: inhibiting net CO₂ release[J]. Chemical Communications, 2020, 56(39): 5239-5242.
33	SONG H, LAUDENSCHLEGER D, CAREY J J, et al. Spinel-structured ZnCr₂O₄ with excess Zn is the active ZnO/Cr₂O₃ catalyst for high-temperature methanol synthesis[J]. ACS Catalysis, 2017, 7(11): 7610-7622.
34	HUANG Y, QIAN W, MA H, et al. Impact of Zn/Cr ratio on ZnCrO_x-SAPO-34 bifunctional catalyst for direct conversion of syngas to light olefins[J]. International Journal of Chemical and Molecular Engineering, 2018, 12(10): 557-563.
35	WANG X, CAO R, CHEN K, et al. Synthesis gas conversion to lower olefins over ZnCr-SAPO-34 catalysts: role of ZnO-ZnCr₂O₄ interface[J]. ChemCatChem, 2020, 12(17): 4387-4395.
36	KOUVA S, HONKALA K, LEFFERTS L, et al. Review: monoclinic zirconia, its surface sites and their interaction with carbon monoxide[J]. Catalysis Science & Technology, 2015, 5(7): 3473-3490.
37	PIERO G D, TRIFIRO F, VACCARI A. Non-stoicheiometric Zn-Cr spinel as active phase in the catalytic synthesis of methanol[J]. Journal of the Chemical Society, Chemical Communications, 1984(10): 656-658.
38	TIAN S, DING S, YANG Q, et al. The role of non-stoichiometric spinel for iso-butanol formation from biomass syngas over Zn-Cr based catalysts [J]. RSC Advances, 2017, 7(33): 20135-20145.
39	BERTOLDI M, FUBINI B, GIAMELLO E, et al. Structure and reactivity of zinc-chromium mixed oxides. Part 1. The role of non-stoichiometry on bulk and surface properties[J]. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1988, 84(5): 1405-1421.
40	ARSLAN M T, ALI B, GILANI S Z A, et al. Selective conversion of syngas into tetramethylbenzene via an aldol-aromatic mechanism[J]. ACS Catalysis, 2020, 10(4): 2477-2488.
41	TAN L, WANG F, ZHANG P, et al. Design of a core-shell catalyst: an effective strategy for suppressing side reactions in syngas for direct selective conversion to light olefins[J]. Chemical Science, 2020, 11(16): 4097-4105.
42	FUJIMOTO K, KUDO Y, TOMINAGA H O. Synthesis gas conversion utilizing mixed catalyst composed of CO reducing catalyst and solid acid: Ⅱ. Direct synthesis of aromatic hydrocarbons from synthesis gas[J]. Journal of Catalysis, 1984, 87(1): 136-143.
43	JIAO F, LI J, PAN X, et al. Selective conversion of syngas to light olefins[J]. Science, 2016, 351(6277): 1065-1068.
44	MA Y, CAI D, LI Y, et al. The influence of straight pore blockage on the selectivity of methanol to aromatics in nanosized Zn/ZSM-5: an atomic Cs-corrected stem analysis study[J]. RSC Advances, 2016, 6(78): 74797-74801.
45	EL-MALKI E M, SANTEN R A VAN, SACHTLER W M H. Introduction of Zn, Ga, and Fe into HZSM-5 cavities by sublimation: identification of acid sites[J]. The Journal of Physical Chemistry B, 1999, 103(22): 4611-4622.
46	ONO Y, ADACHI H, SENODA Y. Selective conversion of methanol into aromatic hydrocarbons over zinc-exchanged ZSM-5 zeolites[J]. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1988, 84(4): 1091-1099.
47	YU B, DING C, WANG J, et al. Dual effects of zinc species on active sites in bifunctional composite catalysts Zr/H[Zn]ZSM-5 for alkylation of benzene with syngas[J]. The Journal of Physical Chemistry C, 2019, 123(31): 18993-19004.
48	冯丽梅, 徐亚荣, 张力, 等. 甲醇芳构化反应的热力学研究[J]. 石化技术与应用, 2017, 35(2): 101-105.
	FENG Limei, XU Yarong, ZHANG Li, et al. Study on thermodynamics of methanol to aromatic reaction[J]. Petrochemical Technology & Application, 2017, 35(2): 101-105.
49	CHEN Zhiyang, NI Youming, ZHI Yuchun, et al. Coupling of methanol and carbon monoxide over H-ZSM-5 to form aromatics[J]. Angewandte Chemie International Edition, 2018, 57(38): 12549-12553.

氧化物	优点	缺点
CuO-ZnO-Al₂O₃	活性高，CO转化率高，经济实惠	无法高温长周期运行，高温不可逆失活
ZnCr₂O₄	活性适中，经济实惠	Cr有毒，Zn在反应过程逐渐脱除晶体结构，稳定性差
金属掺杂ZrO₂	热稳定好，潜在的再生性好	活性相对较低，价格昂贵，成本高
纳米ZnO	经济、环保	活性低

氧化物	优点	缺点
CuO-ZnO-Al₂O₃	活性高，CO转化率高，经济实惠	无法高温长周期运行，高温不可逆失活
ZnCr₂O₄	活性适中，经济实惠	Cr有毒，Zn在反应过程逐渐脱除晶体结构，稳定性差
金属掺杂ZrO₂	热稳定好，潜在的再生性好	活性相对较低，价格昂贵，成本高
纳米ZnO	经济、环保	活性低

催化剂组成	反应条件				转化率 /%	选择性/%	选择性（扣除CO₂）/%				中间体	参考文献
催化剂组成	H₂/CO比	压力 /MPa	温度 /K	空速 /mL·h^-1·g^-1	转化率 /%	CO₂	CH₄	C₂~C₄	C₅₊	芳烃	中间体	参考文献
ZnCr₂O₄&ZSM-5	1	8.3	700	1780	44.10	34.00	2.50	14.50	37.7	36.68	—^③	［2］
ZnCr₂O₄&ZSM-5	1	4	623	1500	16.00	48.00	1.70	15.10	2.7	73.90	乙烯酮	［4］
ZnCr₂O₄&Zn-Z5@S1	2.1	5	673	20.7	55.00	55.00	4.40	29.70		62.00	甲醇	［15］
ZnCr₂O₄&ZSM-5	1	2	668	4000	11.10	40.70	2.50	24.10		72.40	—	［14］
ZnCr₂O₄&Zn-ZSM-5	1	2	668	4000	13.20	40.00	2.10	24.40		73.50	—	［14］
ZrO₂&ZSM-5	1	3	673	500	26.20	12.50	24.50	38.20	37.4	53.00	—	［21］
Zn-ZrO₂&ZSM-5	2	3	673	500	21.00	2.00	<3.00	22.60	2.0	80.00	甲醇	［26］
CeZrO₂&HZSM-5	1	2	653	3500	8.10					83.10	甲醇、C₂₊醇、 C₆₊烯烃	［27］
CeZrO₂&HZSM-5	1	2	723	3500	22.40					56.30	甲醇、C₂₊醇、 C₆₊烯烃	［27］
Mo-ZrO₂&H-ZSM-5	2	4	673	3000	22.00	41.00	3.40	18.00	2.7	76.00	甲醇	［28］
ZrO₂&ZSM-5	1	6	623	3000	11.67	42.64	2.98	31.52	65.50	94.89^①	甲醇	［22］
ZrO₂&ZSM-5	1	6	673	1200	21.59	44.27	22.90	22.07	55.30	95.13^①	甲醇	［23］
ZnZrO₂@C&ZSM-5	2	3	633	3600	35.2		3.40			73.1	甲醇	［11］
ZnCr₂O₄&ZSM-5	1	2	668	4000	11.00	48.50	2.80	12.70		82.50	甲醇/乙烯酮	［13］
CAZ&ZSM-5	1	2	633	500	71.90					86.80^①	甲醇	［29］
CZA/Co-Nb&HZSM-5	2	4	603	1813	95.69	11.61			30.59	46.65	甲醇	［25］
CZA/Co-Nb&HZSM-5	2	4	623	1500	94.79	12.73			33.52	41.08
CZA&Nb-Ni-ZSM-5	2	4	603	1813	99.00					46.55
ZnO&ZSM-5	1	3	603	750	14.80					80.10	甲醇	［20］
MnCrO_x&ZSM-5-USY	1	4	703	1658	13.30	46.20	6.70	22.00		87.70^②	—	［29］

催化剂组成	反应条件				转化率 /%	选择性/%	选择性（扣除CO₂）/%				中间体	参考文献
催化剂组成	H₂/CO比	压力 /MPa	温度 /K	空速 /mL·h^-1·g^-1	转化率 /%	CO₂	CH₄	C₂~C₄	C₅₊	芳烃	中间体	参考文献
ZnCr₂O₄&ZSM-5	1	8.3	700	1780	44.10	34.00	2.50	14.50	37.7	36.68	—^③	［2］
ZnCr₂O₄&ZSM-5	1	4	623	1500	16.00	48.00	1.70	15.10	2.7	73.90	乙烯酮	［4］
ZnCr₂O₄&Zn-Z5@S1	2.1	5	673	20.7	55.00	55.00	4.40	29.70		62.00	甲醇	［15］
ZnCr₂O₄&ZSM-5	1	2	668	4000	11.10	40.70	2.50	24.10		72.40	—	［14］
ZnCr₂O₄&Zn-ZSM-5	1	2	668	4000	13.20	40.00	2.10	24.40		73.50	—	［14］
ZrO₂&ZSM-5	1	3	673	500	26.20	12.50	24.50	38.20	37.4	53.00	—	［21］
Zn-ZrO₂&ZSM-5	2	3	673	500	21.00	2.00	<3.00	22.60	2.0	80.00	甲醇	［26］
CeZrO₂&HZSM-5	1	2	653	3500	8.10					83.10	甲醇、C₂₊醇、 C₆₊烯烃	［27］
CeZrO₂&HZSM-5	1	2	723	3500	22.40					56.30	甲醇、C₂₊醇、 C₆₊烯烃	［27］
Mo-ZrO₂&H-ZSM-5	2	4	673	3000	22.00	41.00	3.40	18.00	2.7	76.00	甲醇	［28］
ZrO₂&ZSM-5	1	6	623	3000	11.67	42.64	2.98	31.52	65.50	94.89^①	甲醇	［22］
ZrO₂&ZSM-5	1	6	673	1200	21.59	44.27	22.90	22.07	55.30	95.13^①	甲醇	［23］
ZnZrO₂@C&ZSM-5	2	3	633	3600	35.2		3.40			73.1	甲醇	［11］
ZnCr₂O₄&ZSM-5	1	2	668	4000	11.00	48.50	2.80	12.70		82.50	甲醇/乙烯酮	［13］
CAZ&ZSM-5	1	2	633	500	71.90					86.80^①	甲醇	［29］
CZA/Co-Nb&HZSM-5	2	4	603	1813	95.69	11.61			30.59	46.65	甲醇	［25］
CZA/Co-Nb&HZSM-5	2	4	623	1500	94.79	12.73			33.52	41.08
CZA&Nb-Ni-ZSM-5	2	4	603	1813	99.00					46.55
ZnO&ZSM-5	1	3	603	750	14.80					80.10	甲醇	［20］
MnCrO_x&ZSM-5-USY	1	4	703	1658	13.30	46.20	6.70	22.00		87.70^②	—	［29］

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合成气经含氧化合物中间体一步法制芳烃研究进展

Recent advance in directing synthesis of aromatic hydrocarbon from syngas via oxygenated compound intermediates

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