化工进展 ›› 2019, Vol. 38 ›› Issue (11): 4930-4940.DOI: 10.16085/j.issn.1000-6613.2019-0112
收稿日期:
2019-01-16
出版日期:
2019-11-05
发布日期:
2019-11-05
通讯作者:
王锐
作者简介:
王锐(1978—),女,博士,高级工程师,研究方向为工业催化。E-mail:Received:
2019-01-16
Online:
2019-11-05
Published:
2019-11-05
Contact:
Rui WANG
摘要:
硫酸化氧化锆固体酸(SO42-/ZrO2)烷烃异构化催化剂兼具高活性、可再生和环境友好的优点,具有广阔的应用前景。本文综述了SO42-/ZrO2催化剂在轻质烷烃异构化中的工业应用进展,包括市场现状、现有技术、经济性等方面,并对专利和文献中报道的催化剂制备技术进行了论述总结。重点针对催化剂的关键制备参数以及对催化剂结构和异构化性能的影响进行了深入分析和探讨,包括氢氧化物前体的沉淀和焙烧条件、助剂的添加和改性作用、催化剂预处理条件和原料水含量的影响等。最后对催化剂开发和工业化中的难点给出了分析和建议,并展望了未来的催化剂发展方向,指出拓宽催化剂的原料适应性、发展新型制备技术和助剂体系、结合催化剂再生等工艺研究是未来的发展方向。
中图分类号:
王锐,阳雪,缪平. SO42-/ZrO2轻质烷烃异构化催化剂的制备和工业应用进展[J]. 化工进展, 2019, 38(11): 4930-4940.
Rui WANG,Xue YANG,Ping MIAO. Progress in preparation research and industrial application of SO42-/ZrO2catalysts for light paraffin isomerization[J]. Chemical Industry and Engineering Progress, 2019, 38(11): 4930-4940.
序号 | 装置 | 产能 /万吨 | 技术来源/工艺名称 | 年份 | 说明 |
---|---|---|---|---|---|
1 | 宁夏宝塔化纤 | 26 | UOP/Par-Isom | 2015 | 合同签约 |
2 | 庆阳石化 | 20 | UOP/Par-Isom | 2017 | 工程建设 |
3 | 中石油克拉玛依 | 15 | UOP/Par-Isom | 2017 | 工程建设 |
4 | 山东金诚石化 | 25 | UOP/Par-Isom | 2017 | 工程竣工 |
5 | 山东汇丰石化集团 | 22 | UOP/Par-Isom | 2018 | 工程竣工 |
6 | 湛江东兴石油 | 18 | 中国石化石油化工科学研究院 | 2016 | 开车运行 |
7 | 恒力石化 | 50 | GTC/Isomalk-2 | 2015 | 合同执行 |
8 | 山东诚信化工 | 42 | GTC/Isomalk-2 | 2018 | 合同执行 |
9 | 山东利丰达生物科技 | 8 | GTC/Isomalk-2 | 2018 | 合同执行 |
10 | 山东东方华龙工贸集团 | 33 | GTC/Isomalk-2 | 2018 | 合同执行 |
11 | 利华益集团股份 | 22 | UOP/Par-Isom | 2017 | 试车运行 |
12 | 珠海市虹彩精细化工 | 20 | UOP/Par-Isom | 2018 | 环评公示 |
表1 国内SO42-/ZrO2催化剂异构化装置
序号 | 装置 | 产能 /万吨 | 技术来源/工艺名称 | 年份 | 说明 |
---|---|---|---|---|---|
1 | 宁夏宝塔化纤 | 26 | UOP/Par-Isom | 2015 | 合同签约 |
2 | 庆阳石化 | 20 | UOP/Par-Isom | 2017 | 工程建设 |
3 | 中石油克拉玛依 | 15 | UOP/Par-Isom | 2017 | 工程建设 |
4 | 山东金诚石化 | 25 | UOP/Par-Isom | 2017 | 工程竣工 |
5 | 山东汇丰石化集团 | 22 | UOP/Par-Isom | 2018 | 工程竣工 |
6 | 湛江东兴石油 | 18 | 中国石化石油化工科学研究院 | 2016 | 开车运行 |
7 | 恒力石化 | 50 | GTC/Isomalk-2 | 2015 | 合同执行 |
8 | 山东诚信化工 | 42 | GTC/Isomalk-2 | 2018 | 合同执行 |
9 | 山东利丰达生物科技 | 8 | GTC/Isomalk-2 | 2018 | 合同执行 |
10 | 山东东方华龙工贸集团 | 33 | GTC/Isomalk-2 | 2018 | 合同执行 |
11 | 利华益集团股份 | 22 | UOP/Par-Isom | 2017 | 试车运行 |
12 | 珠海市虹彩精细化工 | 20 | UOP/Par-Isom | 2018 | 环评公示 |
参数 | Penex OT 氯化型 | Par-Isom OT SO42-/ZrO2 | Penex DIH 氯化型 | Par-Isom DIH SO42-/ZrO2 |
---|---|---|---|---|
原料流量/桶·天-1 | 10000 | 10000 | 10000 | 10000 |
辛烷值 | 83.4 | 83.4 | 88.0 | 88.0 |
辛烷桶 | 81040 | 81040 | 84520 | 84500 |
总CAPEX/×106USD | 36.5 | 32.7 | 56.9 | 47.5 |
公用消耗 | 基础 | 基础×0.56 | 基础×1.82 | 基础×1.36 |
表2 10000桶/天轻石脑油异构化装置经济性对比
参数 | Penex OT 氯化型 | Par-Isom OT SO42-/ZrO2 | Penex DIH 氯化型 | Par-Isom DIH SO42-/ZrO2 |
---|---|---|---|---|
原料流量/桶·天-1 | 10000 | 10000 | 10000 | 10000 |
辛烷值 | 83.4 | 83.4 | 88.0 | 88.0 |
辛烷桶 | 81040 | 81040 | 84520 | 84500 |
总CAPEX/×106USD | 36.5 | 32.7 | 56.9 | 47.5 |
公用消耗 | 基础 | 基础×0.56 | 基础×1.82 | 基础×1.36 |
1 | 张晓华, 孙会东, 邢定峰, 等. 浅谈轻石脑油异构化在国内炼油厂的应用[J]. 石油规划设计, 2015, 26(5): 26-28. |
ZHANGXiaohua, SUNHuidong, XINGDingfeng, et al. The application of light naphtha isomerization in domestic refineries [J]. Petroleum Planning & Engineering, 2015, 26(5): 26-28. | |
2 | 马爱增, 于中伟, 张秋平, 等. 从石脑油和轻烃资源增产汽油的技术及措施[J]. 石油炼制与化工, 2009, 40(11): 1-7. |
MAAizeng, YUZhongwei, ZHANGQiuping, et al. Technologies for increasing gasoline production from naphtha and light hydrocarbons[J]. Petroleum Processing and Petrochemicals, 2009, 40(11): 1-7. | |
3 | 赵文康, 樊洁, 朱博超, 等. 异构化制清洁汽油工艺及催化剂[J]. 化工进展, 2016, 35(8): 2455-2463. |
ZHAOWenkang, FANJie, ZHUBochao, et al. Isomerization process for producing clean gasoline and the catalyst[J]. Chemical Industry and Engineering Progress, 2016, 35(8): 2455-2463. | |
4 | KIMURAT. Development of Pt/SO42-/ZrO2, catalyst for isomerization of light naphtha[J]. Catalysis Today, 2003, 81(1): 57-63. |
5 | 钱伯章. 新型异构化催化剂获应用[J]. 精细石油化工进展, 2004, 34(7): 19. |
QIANBozhang. Application of new type isomerization catalyst [J]. Advances in Fine Petrochemicals, 2004, 34(7): 19. | |
6 | Worldwide Refinery Processing. Review: 4Q 2014 review fluid catalytic cracking and isomerization[R]. US: Hydrocarbon Publishing Company, 2013. |
7 | 田爱珍, 杨周侠, 汪毅, 等. 轻石脑油异构化工艺技术研究进展[J]. 应用化工, 2015(3): 558-562. |
TIANAizhen, YANGZhouxia, WANGYi, et al. Advanced research progress of light naphtha isomerization technology[J]. Applied Chemical Industry, 2015(3): 558-562. | |
8 | 威海市环境保护科学研究所有限公司. 山东金诚石化集团有限公司油品质量(国Ⅴ)升级及配套改造项目环境影响评价变更报告[EB/OL]. 2016-04. . |
Weihai Environment Protection Science Institute Company Limited. Report on the change of environmental impact assessment on the project “fuel quality upgrading (national Ⅴ) and its associated revamping” of shandong jincheng petrochemical group company limited[EB/OL]. 2016-04. . | |
9 | 许建耘. 用于C5、C6和C7轻石脑油的异构化技术Isomalk[J]. 石油炼制与化工, 2015(7): 77. |
XUJianyun. C5, C6, C7 light naphtha isomerization technology isomalk[J]. Petroleum Processing and Petrochemicals, 2015(7): 77. | |
10 | SHAKUNA N, FEDOROVAM L. Isomerization of light gasoline fractions: the efficiency of different catalysts and technologies[J]. Catalysis in Industry, 2014, 6(4): 298-306. |
11 | 钱伯章. GTC技术公司在中国转让异构化工艺[J]. 石油炼制与化工, 2014(7): 86. |
QIANBozhang. GTC licensed isomerization technology to company in China[J]. Petroleum Processing and Petrochemicals, 2014(7): 86. | |
12 | SULLIVAND, METROS, PUJADÓP R. Isomerization in petroleum processing[M]. Berlin: Springer International Publishing, 2014. |
13 | 杜云散. C5/C6固体酸异构化的反应建模与工艺条件研究[J]. 科技创新导报, 2018(26): 93-96. |
DUYunsan. Study on the reaction modeling and process parameters for C5/C6 isomerization catalyzed by solid acid[J]. Science and Technology Innovation Herald, 2018(26): 93-96. | |
14 | 王昊, 刘彦, 李劭, 等. C5/C6烷烃异构化装置的技术流程选择[J]. 当代化工, 2019, 48(1): 166-169. |
WANGHao, LIUYan, LIShao, et al. Process selection of C5/C6 isomerization unit[J]. Contemporary Chemical Industry, 2019, 48(1): 166-169. | |
15 | 中国石化石油化工科学研究院科研处. “固体超强酸C5/C6异构化技术开发及工业试验”项目通过评审[J]. 石油炼制与化工, 2017, 48(6): 13. |
Research Office of Sinopec Research Institute of Petroleum Processing. Project of “solid acid C5/C6 isomerization development and industrial” passed evaluation[J]. Petroleum Processing and Petrochemicals, 2017, 48(6): 13. | |
16 | 中国石化石油化工科学研究院科研处. 国内首套固体超强酸C5、C6异构化装置顺利投产[J]. 石油炼制与化工, 2016(11): 72. |
Research Office of Sinopec Research Institute of Petroleum Processing. First solid superacid acid C5/C6 isomerization unit in China started production successfully[J]. Petroleum Processing and Petrochemicals, 2016(11): 72. | |
17 | 章红艳, 宋月芹, 倪海微, 等. 固体超强酸C5/C6异构化催化剂成型及寿命研究[J]. 石油炼制与化工, 2018, 49(9): 82-89. |
ZHANGHongyan, SONGYueqin, NIHaiwei, et al. Modeling and lifetime test of solid superacid catalyst for n-C5/C6 isomerization[J]. Petroleum Processing and Petrochemicals, 2018, 49(9):82-89. | |
18 | 倪海微, 宋月芹, 周思侬, 等. 氧化铝成型的Pt-SO42-/ZrO2-Al2O3上n-C50/C60的异构化性能[J]. 化工进展, 2019, 38(6): 2806-2812. |
NIHaiwei, SONGYueqin, ZHOUSinong, et al. n-C50/C60 isomerization performance over alumina-shaped Pt-SO42-/ZrO2-Al2O3 catalyst[J]. Chemical Industry and Engineering Progress, 2019, 38(6): 2806-2812. | |
19 | BABAS, SHIBATAY, KAWAMURAT, et al. Solid strong acid catalyst process for the production of the same and use there of: US5036035A[P]. 1991-07-30. |
20 | GILLESPIER D, COHNM J. High-activity isomerization catalyst and process: US6706659B2[P]. 2004-03-16. |
21 | 潘晖华, 于中伟, 濮仲英. 一种固体超强酸催化剂及制备方法: CN1168533C[P]. 2004-09-29. |
PANHuihua, YUZhongwei, PUZhongying. A solid superacid catalysts and its preparation method: CN1168533C[P]. 2004-09-29. | |
22 | SCHMIDTF. New catalyst preparation technologies-observed from an industrial viewpoint[J]. Applied Catalysis A: General, 2001, 221(1): 15-21. |
23 | 范书信, 于中伟, 濮仲英. 固体超强酸催化剂及其制备方法: CN1159099C[P]. 2004-07-28. |
FANShuxin, YUZhongwei, PUZhongying. Solid superacid catalysts and its preparation method: CN1159099C[P]. 2004-07-28. | |
24 | SHAKUNA N, FedorovaM L. Method of isomerization of light gasoline fractions: RU2321575[P]. 2006-06-19. |
25 | 亚历山德·尼基托维奇·沙昆. 轻汽油馏分的异构化方法: CN101365667B[P]. 2009-02-11. |
SHAKUNA N. Method of isomerization of light gasoline fractions: CN101365667B[P]. 2009-02-11. | |
26 | URZHUNTSEVG A, OVCHINNIKOVAE V, CHUMACHENKOV A, et al. Isomerization of n-butane over Pd-SO42-/ZrO2 catalyst: prospects for commercial application[J]. Chemical Engineering Journal, 2014, 238: 148-156. |
27 | LIX, NAGAOKAK, LERCHERJ A. Labile sulfates as key components in active sulfated zirconia for n-butane isomerization at low temperatures[J]. Journal of Catalysis, 2004, 227(1): 130-137. |
28 | KLOSEB S, JENTOFTF C, JOSHIP, et al. In situ spectroscopic investigation of activation, start-up and deactivation of promoted sulfated zirconia catalysts[J]. Catalysis Today, 2006, 116(2): 121-131. |
29 | 汪颖军, 刘成双, 李小辉. SO42-/ZrO2催化烷烃异构化反应的研究进展[J]. 石油化工, 2010, 39(1): 94-106. |
WANGYingjun, LIUChengshuang, LIXiaohui. Research progress of SO42-/ZrO2 catalyst in alkanes isomerization[J]. Petrochemical Technology, 2010, 39(1): 94-106. | |
30 | 缪长喜, 陈建民, 高滋. SO42-/ZrO2超强酸制备方法的改进[J]. 高等学校化学学报, 1995(4): 591-594. |
MIAOChangxi, CHENJianmin, GAOZi. An improvement on the preparation of SO42-/ZrO2 superacid [J]. Chemical Journal of Chinese Universities, 1995(4): 591-594. | |
31 | 范书信. 正戊烷异构化固体超强酸催化剂的研究[D]. 北京: 中国石化石油化工科学研究院, 2001. |
FANShuxin. Study on solid superacid catalyst for n-pentane isomerization[D]. Beijing: Sinopec Research Institute of Petroleum Processing, 2001. | |
32 | SERRAJ M, CHICAA, CORMAA. Development of a low temperature light paraffin isomerization catalysts with improved resistance to water and sulphur by combinatorial methods[J]. Applied Catalysis A: General, 2003, 239(1): 5-42. |
33 | BELSKAYAO B, DANILOVAI G, KAZAKOVM O, et al. Investigation of active metal species formation in Pd-promoted sulfated zirconia isomerization catalyst[J]. Applied Catalysis A: General, 2010, 387(1): 1-12. |
34 | 乐晓光, 徐俊, 宋月芹, 等. 制备条件对Pt/SO42-/ZrO2-Al2O3异构化性能的影响[J]. 化工进展, 2015, 34(2): 419-424. |
LEXiaoguang, XUJun, SONGYueqin, et al. Effect of preparation conditions on isomerization performance of Pt/SO42-/ZrO2-Al2O3 catalyst[J]. Chemical Industry and Engineering Progress, 2015, 34(2): 419-424. | |
35 | 曹崇江. Al、Ga促进的SO42-/ZrO2烷烃异构化催化剂研究[D]. 南京:南京工业大学, 2005. |
CAOChongjiang. Studies on Al- and Ga- promoted sulfated zirconia for alkane isomerization [D]. Nanjing: Nanjing University of Technology, 2005. | |
36 | AFANASIEVP, THIOLLIERA, BREYSSEM, et al. Control of the textural properties of zirconium oxide[J]. Topics in Catalysis, 1999, 8(3/4): 147-160. |
37 | 李文, 殷元骐. 制备条件对ZrO2晶相结构的影响[J]. 分子催化, 1999(4): 275-276. |
LIWen, YINYuanqi. Effect of preparation conditions on the crystalline structure of ZrO2[J]. Journal of Molecular Catalysis (China), 1999(4): 275-276. | |
38 | CORMAA, FORNESV, JUANRAJADELLM I, et al. Influence of preparation conditions on the structure and catalytic properties of SO42-/ZrO2 superacid catalysts[J]. Applied Catalysis A: General, 1994, 25(51): 151-163. |
39 | KUZNETSOVP N, KUZNETSOVAL I, TVERDOKHLEBOVV P, et al. Method of preparing n-butane-into-isobutane isomerization catalyst: RU2236291C1[P]. 2002-12-26. |
40 | KUZNETSOVP N, KUZNETSOVAL I, KAZBANOVAA V. Catalytic isomerisation of alkanes on anion-modified forms of zirconium dioxide[J]. Chemistry for Sustainable Development, 2010, 18: 253-264. |
41 | XUJ, YINGJ Y. A highly active and selective nanocomposite catalyst for C7+ paraffin isomerization[J]. Angewandte Chemie, 2006, 118(40): 6852-6856. |
42 | 王泽彬, 孙越, 王岷, 等. 粉末状氢氧化锆的制备[J]. 稀有金属快报, 2005, 24(1): 28-29. |
WANGZebin, SUNYue, WANGMin, et al. Production of zirconium hydroxide powder[J]. Rare Metals Letters, 2005, 24(1): 28-29. | |
43 | 潘晖华, 于中伟, 濮仲英. 水热法改性氢氧化锆制备Pt-SO42-/ZrO2固体酸催化剂Ⅰ. 水热温度的影响[J]. 催化学报, 2003, 24(3):193-197. |
PANHuihua, YUZhongwei, PUZhongying. Preparation of Pt-SO42-/ZrO2 solid acid catalyst through hydrothermal modification of zirconium hydroxide Ⅰ. Influence of hydrothermal temperature[J]. Chinese Journal of Catalysis, 2003, 24(3): 193-197. | |
44 | 曹崇江, 陈长林, 徐南平. 水热改性SO42-/Al2O3/ZrO2的制备及其对正丁烷异构化反应的催化性能[J]. 应用化学, 2007, 24(11): 1240-1244. |
CAOChongjiang, CHENChanglin, XUNanping. Preparation of SO42-/Al2O3/ZrO2 through digestion modification and its catalytic activity in n-butane isomerization[J]. Chinese Journal of Applied Chemistry, 2007, 24(11): 1240-1244. | |
45 | 尹双凤, 徐柏庆. 碱液回流老化制备高表面积二氧化锆[J]. 催化学报, 2002, 23(3): 214-218. |
YINShuangfeng, XUBoqing. Preparation of high surface area zirconia by reflux-digestion in basic solutions[J]. Chinese Journal of Catalysis, 2002, 23(3): 214-218. | |
46 | YINShuangfeng, XUBoqing. On the preparation of high-surface-area nano-zirconia by reflux-digestion of hydrous zirconia gel in basic solution[J]. ChemPhysChem, 2003, 4(6): 277-281. |
47 | BUSTOM, SHIMIZUK, VERAC R, et al. Influence of hydrothermal aging on the catalytic activity of sulfated zirconia[J]. Applied Catalysis A: General, 2008, 348(2): 173-182. |
48 | LIX, NAGAOKAK, OLINDOR, et al. Synthesis of highly active sulfated zirconia by sulfation with SO3[J]. Journal of Catalysis, 2006, 238(1): 39-45. |
49 | LIX, NAGAOKAK, SIMONL J, et al. Influence of calcination procedure on the catalytic property of sulfated zirconia[J]. Catalysis Letters, 2007, 113(1/2): 34-40. |
50 | HAHNA H P, RESSLERT, JENTOFTR E, et al. The role of the "glow phenomenon" in the preparation of sulfated zirconia catalysts[J]. Chemical Communications, 2001, 6(6): 537-538. |
51 | HAHNA H P, JENTOFTR E, RESSLERT, et al. Rapid genesis of active phase during calcination of promoted sulfated zirconia catalysts[J]. Journal of Catalysis, 2005, 236(2): 324-334. |
52 | EBITANIK, KONISHIJ, HATTORIH. Skeletal isomerization of hydrocarbons over zirconium oxide promoted by platinum and sulfate ion[J]. Journal of Catalysis, 1991, 130(1): 257-267. |
53 | DAVISB H, KEOGHR A, SRINIVASANR. Sulfated zirconia as a hydrocarbon conversion catalyst[J]. Catalysis Today, 1994, 20(2): 219-256. |
54 | GARINF, ANDRIAMASINOROD, ABDULSAMADA, et al. Conversion of butane over the solid superacid ZrO2/SO42- in the presence of hydrogen[J]. Journal of Catalysis, 1991, 131(1): 199-203. |
55 | SIGNORETTOM, PINNAF, STRUKULG, et al. Platinum-promoted and unpromoted sulfated zirconia catalysts prepared by a one-step aerogel procedure[J]. Journal of Catalysis, 1997, 167(2): 522-532. |
56 | 杨丹. 贵金属改性SO42-/ZrO2催化剂制备和异构化性能的研究[D]. 上海: 华东理工大学, 2014. |
YANGDan. Preparation and isomerization performance of SO42-/ZrO2 catalyst modified by noble metals[D]. Shanghai: East China University of Science and Technology, 2014. | |
57 | VIJAYS, WolfE.E. A highly active and stable platinum-modified sulfated zirconia catalyst: 1. Preparation and activity for n-pentane isomerization[J]. Applied Catalysis A: General, 2004, 264(1): 117-124. |
58 | VIJAYS, WOLFE E, MILLERJ T, et al. A highly active and stable platinum-modified sulfated zirconia catalyst: Part 2. EXAFS studies of the effect of pretreatment on the state of platinum[J]. Applied Catalysis A: General, 2004, 264(1):125-130. |
59 | SONGH, WANGN, SONGH L, et al. La–Ni modified S2O82-/ZrO2-Al2O3 catalyst in n-pentane hydroisomerization[J]. Catalysis Communications, 2015, 59: 61-64. |
60 | HSU C Y, HEIMBUCHC R, ARMESC T, et al. A highly active solid superacid catalyst for n-butane lsomerization: a sulfated oxide containing iron, manganese and zirconium[J]. Journal of the Chemical Society Chemical Communications, 1992: 1645-1646. |
61 | GAOZ, XIAY, HUAW, et al. New catalyst of SO42-/Al2O3-ZrO2, for n-butane isomerization[J]. Topics in Catalysis, 1998, 6(1/2/3/4):101-106. |
62 | HUAW, XIAY, YUEY, et al. Promoting Effect of Al on SO42-/MxOy(M=Zr,Ti,Fe) catalysts[J]. Journal of Catalysis, 2000, 196(1): 104-114. |
63 | XIAY, HUAW, MIAOC, et al. n-butane isomerization on Al-promoted sulfated zirconia catalysts[J]. Chinese Journal of Catalysis, 1998, 19(2): 97-98. |
64 | 夏勇德, 华伟明. A1促进SO42-/MxOy(M=Zr,Ti,Fe)固体强酸的研究[J]. 化学学报, 2000, 58(1): 86-91. |
XIADeyong, HUAWeiming. Studies on strong solid acids of Al-Promoted SO42-/MxOy(M=Zr,Ti,Fe)[J]. Acta Chimica Sinica, 2000, 58(1): 86-91. | |
65 | JENTOFTF C, HAHNA, KRÖHNERTJ, et al. Incorporation of manganese and iron into the zirconia lattice in promoted sulfated zirconia catalysts[J]. Journal of Catalysis, 2004, 224(1): 124-137. |
66 | KLOSEB S, JENTOFTF C, SCHLÖGLR, et al. Effect of Mn and Fe on the reactivity of sulfated zirconia toward H2 and n-butane: a diffuse reflectance IR spectroscopic investigation[J]. Langmuir, 2005, 21(23): 10564-10572. |
67 | LIP, CHENI, PENNER-HAHNJ E. Effect of dopants on zirconia stabilization—An X-ray absorption study: 1, Trivalent dopants [J]. Journal of the American Ceramic Society, 1994, 77(1): 128. |
68 | ARATAK. Solid superacids[J]. Advances in Catalysis, 1990, 37: 165-211. |
69 | 田静, 宋月芹, 冯敏超, 等. 活化条件对正己烷在Pt/SO42-/ZrO2-Al2O3上的异构化活性影响[J]. 化工进展, 2012, 31(12): 2714-2719. |
TIANJing, SONGYueqin, FENGMinchao, et al. Effect of activation condition on n-hexane isomerization performance of Pt/SO42-/ZrO2-Al2O3 catalyst[J]. Chemical Industry and Engineering Progress, 2012, 31(12): 2714-2719. | |
70 | 任坚强, 于中伟, 孙义兰, 等. 一种固体超强酸催化剂的预处理方法: CN102649093B[P]. 2014-05-28. |
RENJianqiang, YUZhongwei, SUNYilan, et al. Method for pretreatment of solid superacid catalyst: CN102649093B[P]. 2014-05-28. | |
71 | FEDOROVAM L, SHAKUNA N. Method of isomerising light petrol fractions with catalyst preactivation: RU2394804C2[P]. 2008-09-26. |
72 | SONGS X, KYDDR A. The effect of pretreatment procedures on the activities of Fe- and Mn-promoted sulfated zirconia catalysts[J]. Catalysis Letters, 1998, 51(1/2): 95-100. |
73 | 张娟娟. 正已烷异构化Pt- SO42-/ZrO2固体超强酸催化剂的研究[D]. 上海: 华东理工大学, 2011. |
ZHANGJuanjuan. Study on n-hexane isomerization over Pt-SO42-/ZrO2 solid acid catalyst[D]. Shanghai: East China University of Science and Technology, 2011. | |
74 | SONGS X, KYDDR A. Activation of sulfated zirconia catalysts effect of water content on their activity in n-butane isomerization[J]. Journal of the Chemical Society Faraday Transactions, 1998, 94(9): 1333-1338. |
75 | GONZÁLEZM R, KOBEJ M, FOGASHK B, et al. Promotion of n-butane isomerization activity by hydration of sulfated zirconia[J]. Journal of Catalysis, 1996, 160(2): 290–298. |
76 | ANDERSONG C, ROSINR R, STINEM A. New solutions for light Paraffin isomerization[R]. Des Plaines: UOP LLC, 2004. |
77 | 张锐, 刘耀芳. 水对SO42-/ZrO2型固体超强酸催化正戊烷异构化反应的影响[J]. 石油与天然气化工, 2000(2): 53-55. |
ZHANGRui, LIUYaofang. The influence of water on SO42-/ZrO2 typed solid super acid catalyzed pentane isomerization[J]. Chemical Engineering of Oil and Gas, 2000(2): 53-55. | |
78 | 孔晓翠. 固体超强酸催化正戊烷异构化失活因素的考察[D]. 北京: 石油化工科学研究院, 1998. |
KONGXiaocui. Investigation on deactivation of solid superacid catalyst in n-pentane isomerization reaction[D]. Beijing: Research Institute of Petroleum Processing, 1998. | |
79 | FURUTAS. The effect of electric type of platinum complex ion on the isomerization activity of Pt-loaded sulfated zirconia-alumina[J]. Applied Catalysis A: General, 2003, 251(2): 285-293. |
80 | 任坚强, 于中伟, 张新宽, 等. 因原料水含量过高而失活的固体超强酸催化剂的活化方法: CN104437591A[P]. 2016-08-24. |
RENJianqiang, YUZhongwei, ZHANGXinkuan, et al. A method of activation on the solid superacid catalysts deactivated due to the high water content in the feed: CN104437591A[P]. 2016-08-24. |
[1] | 张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286. |
[2] | 时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298. |
[3] | 谢璐垚, 陈崧哲, 王来军, 张平. 用于SO2去极化电解制氢的铂基催化剂[J]. 化工进展, 2023, 42(S1): 299-309. |
[4] | 杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318. |
[5] | 王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497. |
[6] | 邓丽萍, 时好雨, 刘霄龙, 陈瑶姬, 严晶颖. 非贵金属改性钒钛基催化剂NH3-SCR脱硝协同控制VOCs[J]. 化工进展, 2023, 42(S1): 542-548. |
[7] | 程涛, 崔瑞利, 宋俊男, 张天琪, 张耘赫, 梁世杰, 朴实. 渣油加氢装置杂质沉积规律与压降升高机理分析[J]. 化工进展, 2023, 42(9): 4616-4627. |
[8] | 王鹏, 史会兵, 赵德明, 冯保林, 陈倩, 杨妲. 过渡金属催化氯代物的羰基化反应研究进展[J]. 化工进展, 2023, 42(9): 4649-4666. |
[9] | 高彦静. 单原子催化技术国际研究态势分析[J]. 化工进展, 2023, 42(9): 4667-4676. |
[10] | 张启, 赵红, 荣峻峰. 质子交换膜燃料电池中氧还原反应抗毒性电催化剂研究进展[J]. 化工进展, 2023, 42(9): 4677-4691. |
[11] | 王伟涛, 鲍婷玉, 姜旭禄, 何珍红, 王宽, 杨阳, 刘昭铁. 醛酮树脂基非金属催化剂催化氧气氧化苯制备苯酚[J]. 化工进展, 2023, 42(9): 4706-4715. |
[12] | 葛亚粉, 孙宇, 肖鹏, 刘琦, 刘波, 孙成蓥, 巩雁军. 分子筛去除VOCs的研究进展[J]. 化工进展, 2023, 42(9): 4716-4730. |
[13] | 毛善俊, 王哲, 王勇. 基团辨识加氢:从概念到应用[J]. 化工进展, 2023, 42(8): 3917-3922. |
[14] | 向阳, 黄寻, 魏子栋. 电催化有机合成反应的活性和选择性调控研究进展[J]. 化工进展, 2023, 42(8): 4005-4014. |
[15] | 王耀刚, 韩子姗, 高嘉辰, 王新宇, 李思琪, 杨全红, 翁哲. 铜基催化剂电还原二氧化碳选择性的调控策略[J]. 化工进展, 2023, 42(8): 4043-4057. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 版权所有 © 《化工进展》编辑部 地址:北京市东城区青年湖南街13号 邮编:100011 电子信箱:hgjz@cip.com.cn 本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn |