金属有机骨架UiO-66在催化领域的应用

doi:10.16085/j.issn.1000-6613.2019-1106

摘要/Abstract

摘要： 金属有机骨架（MOFs）经过二十多年的快速发展，已经合成了成千上万种，然而MOFs材料普遍具有较低的稳定性，在一定程度上限制了MOFs的发展。UiO-66的合成是MOFs材料稳定性的一个突破，其在催化领域的发展尤为迅速。本文首先介绍了理想及实际状态下UiO-66的结构特征，并说明了配体缺失导致的节点空位处的元素组成。然后综述了利用UiO-66特殊的结构特征或将其功能化用于催化反应的研究，包括节点空位、功能化节点空位、负载金属纳米颗粒、功能化配体等。最后，考虑到可以综合利用UiO-66的特殊结构，对UiO-66在未来多功能催化剂的设计合成领域所能发挥的作用进行展望。

关键词: 金属有机骨架, UiO-66, 复合材料, 纳米结构, 催化

Abstract: Thousands of metal-organic frameworks (MOFs) have been synthesized after more than two decades of rapid development. However, MOFs generally have low stability, which limits the development of MOFs to some extent. The synthesis of UiO-66 is a breakthrough in the stability of MOFs materials, and its development in the field of catalysis is particularly rapid. This paper first introduces the structural characteristics of UiO-66 under ideal and actual conditions, and illustrates the elemental composition of the node vacancies caused by ligand loss. Then, the UiO-66 itself or their functionalization for catalytic reactions are reviewed, including node vacancies, functionalized node vacancies, supported metal nanoparticles, and functionalized ligands. Finally, considering the comprehensive utilization for the structure of UiO-66, the role of UiO-66 in the design and synthesis of multifunctional catalysts in the future is expected.

Key words: metal-organic frameworks, UiO-66, composites, nanostructure, catalysis

中图分类号:

TB333

于吉行, 俞俊, 薛晓雅, 韩颖, 毛海舫, 毛东森. 金属有机骨架UiO-66在催化领域的应用[J]. 化工进展, 2019, 38(s1): 144-151.

YU Jihang, YU Jun, XUE Xiaoya, HAN Ying, MAO Haifang, MAO Dongsen. Applications in the field of catalysis of metal organic framework UiO-66[J]. Chemical Industry and Engineering Progress, 2019, 38(s1): 144-151.

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