低温等离子体协同催化降解挥发性有机物的研究进展

doi:10.16085/j.issn.1000-6613.2018-2485

摘要/Abstract

摘要：

低温等离子体协同催化技术在挥发性有机物（VOCs）治理中因具有反应高效、反应条件温和、设备简易等优点而受到广泛的研究和应用。文章介绍了低温等离子体协同催化降解VOCs的基本原理、技术研究进展，简述了低温等离子体的高反应活性在与催化剂的高反应选择性结合后所产生的协同作用，二者的结合不但提高了VOCs的降解效率、减少有害副产物生成，还弥补了单一使用低温等离子体技术的高能耗、副产物多的缺陷。此外，分析了低温等离子体与催化剂的联合方式及特点、低温等离子体与催化剂之间的相互作用和影响以及低温等离子体联合不同类型催化剂的协同原理。指出了研究中对完整机理分析的欠缺以及应用过程中对中间过程监测分析的困难，这也是低温等离子体协同催化降解挥发性有机物研究中的重要内容。

关键词: 低温等离子体, 催化剂, 催化, 挥发性有机物, 降解

Abstract:

Non-thermal plasma cooperating catalyst technology has been widely researched and applied in the treatment of volatile organic compounds (VOCs) due to its high efficiency, mild reaction conditions and simple equipment. The basic principle for non-thermal plasma synergistic catalytic degradation of VOCs and the research progress of the technology were introduced in this paper. It briefly describes the synergistic effect between the high reactivity of non-thermal plasma and the high-reaction selectivity of the catalyst, which improves the degradation efficiency of VOCs and cuts down the generation of harmful by-products as well. It also compensates the defects of high energy consumption and many by-products of single-use non-thermal plasma technology. In addition, it has been summarized including the combination mode and characteristics of non-thermal plasma combined with catalytic, the interaction and influence between non-thermal plasma and catalyst and the synergistic principle of non-thermal plasma combined with different types of catalysts. Complete mechanism analysis of non-thermal plasma cooperating catalyst technology is still unclear, and monitoring and analyzing the intermediate process are difficult in the application process, which are the important points in research of non-thermal plasma cooperating catalyst technology.

Key words: non-thermal plasma, catalyst, catalysis, volatile organic compounds, degradation

中图分类号:

X511

陈鹏,陶雷,谢怡冰,郭梦雪,马懿星,王学谦,宁平,王郎郎. 低温等离子体协同催化降解挥发性有机物的研究进展[J]. 化工进展, 2019, 38(9): 4284-4294.

Peng CHEN,Lei TAO,Yibing XIE,Mengxue GUO,Yixing MA,Xueqian WANG,Ping NING,Langlang WANG. Non-thermal plasma cooperating catalyst degradation of the volatile organic compounds: a review[J]. Chemical Industry and Engineering Progress, 2019, 38(9): 4284-4294.

图/表 6

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放置方式	作者	方法
直接将催化剂负载在电极上	Karuppiah等^[34]	采用烧结金属纤维（SMF）作为DBD反应器的内电极，通过浸渍法直接将过渡金属氧化物催化剂负载在SMF上来降解低浓度的苯
将催化剂涂覆在反应器的内表面	李国平等^[35]	采用电晕放电结合TiO₂催化剂，将TiO₂粉末混合后的浆液均匀涂覆在反应器内铝箔内表面上降解二氯甲烷
将催化剂放置于电极之间的空隙内	吴军良^[36]	将制备的Mn/Ni/Cr基催化剂通过石英棉固定于DBD等离子体反应器放电区后段降解甲苯
将催化剂放置于电极之间的空隙内	李静^[37]	以Mn作为活性组分负载在Al₂O₃、TiO₂、ZSM-5载体上，置于DBD电极空隙间，与低温等离子体协同降解甲苯

放置方式	作者	方法
直接将催化剂负载在电极上	Karuppiah等^[34]	采用烧结金属纤维（SMF）作为DBD反应器的内电极，通过浸渍法直接将过渡金属氧化物催化剂负载在SMF上来降解低浓度的苯
将催化剂涂覆在反应器的内表面	李国平等^[35]	采用电晕放电结合TiO₂催化剂，将TiO₂粉末混合后的浆液均匀涂覆在反应器内铝箔内表面上降解二氯甲烷
将催化剂放置于电极之间的空隙内	吴军良^[36]	将制备的Mn/Ni/Cr基催化剂通过石英棉固定于DBD等离子体反应器放电区后段降解甲苯
将催化剂放置于电极之间的空隙内	李静^[37]	以Mn作为活性组分负载在Al₂O₃、TiO₂、ZSM-5载体上，置于DBD电极空隙间，与低温等离子体协同降解甲苯

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