化工进展 ›› 2019, Vol. 38 ›› Issue (9): 4284-4294.DOI: 10.16085/j.issn.1000-6613.2018-2485
陈鹏(),陶雷,谢怡冰,郭梦雪,马懿星(),王学谦(),宁平,王郎郎
收稿日期:
2018-12-27
出版日期:
2019-09-05
发布日期:
2019-09-05
通讯作者:
马懿星,王学谦
作者简介:
陈鹏(1996—),男,硕士研究生,研究方向为低温等离子体技术与大气污染控制。E-mail:基金资助:
Peng CHEN(),Lei TAO,Yibing XIE,Mengxue GUO,Yixing MA(),Xueqian WANG(),Ping NING,Langlang WANG
Received:
2018-12-27
Online:
2019-09-05
Published:
2019-09-05
Contact:
Yixing MA,Xueqian WANG
摘要:
低温等离子体协同催化技术在挥发性有机物(VOCs)治理中因具有反应高效、反应条件温和、设备简易等优点而受到广泛的研究和应用。文章介绍了低温等离子体协同催化降解VOCs的基本原理、技术研究进展,简述了低温等离子体的高反应活性在与催化剂的高反应选择性结合后所产生的协同作用,二者的结合不但提高了VOCs的降解效率、减少有害副产物生成,还弥补了单一使用低温等离子体技术的高能耗、副产物多的缺陷。此外,分析了低温等离子体与催化剂的联合方式及特点、低温等离子体与催化剂之间的相互作用和影响以及低温等离子体联合不同类型催化剂的协同原理。指出了研究中对完整机理分析的欠缺以及应用过程中对中间过程监测分析的困难,这也是低温等离子体协同催化降解挥发性有机物研究中的重要内容。
中图分类号:
陈鹏,陶雷,谢怡冰,郭梦雪,马懿星,王学谦,宁平,王郎郎. 低温等离子体协同催化降解挥发性有机物的研究进展[J]. 化工进展, 2019, 38(9): 4284-4294.
Peng CHEN,Lei TAO,Yibing XIE,Mengxue GUO,Yixing MA,Xueqian WANG,Ping NING,Langlang WANG. Non-thermal plasma cooperating catalyst degradation of the volatile organic compounds: a review[J]. Chemical Industry and Engineering Progress, 2019, 38(9): 4284-4294.
放置方式 | 作者 | 方法 |
---|---|---|
直接将催化剂负载在 电极上 | Karuppiah等[ | 采用烧结金属纤维(SMF)作为DBD反应器的内电极,通过浸渍法直接将过渡金属氧化物催化剂负载在SMF上来降解低浓度的苯 |
将催化剂涂覆在反应器 的内表面 | 李国平等[ | 采用电晕放电结合TiO2催化剂,将TiO2粉末混合后的浆液均匀涂覆在反应器内铝箔内表面上降解二氯甲烷 |
将催化剂放置于电极 之间的空隙内 | 吴军良[ | 将制备的Mn/Ni/Cr基催化剂通过石英棉固定于DBD等离子体反应器放电区后段降解甲苯 |
李静[ | 以Mn作为活性组分负载在Al2O3、TiO2、ZSM-5载体上,置于DBD电极空隙间,与低温等离子体协同降解甲苯 |
表1 催化剂在一段式反应器内的放置方式
放置方式 | 作者 | 方法 |
---|---|---|
直接将催化剂负载在 电极上 | Karuppiah等[ | 采用烧结金属纤维(SMF)作为DBD反应器的内电极,通过浸渍法直接将过渡金属氧化物催化剂负载在SMF上来降解低浓度的苯 |
将催化剂涂覆在反应器 的内表面 | 李国平等[ | 采用电晕放电结合TiO2催化剂,将TiO2粉末混合后的浆液均匀涂覆在反应器内铝箔内表面上降解二氯甲烷 |
将催化剂放置于电极 之间的空隙内 | 吴军良[ | 将制备的Mn/Ni/Cr基催化剂通过石英棉固定于DBD等离子体反应器放电区后段降解甲苯 |
李静[ | 以Mn作为活性组分负载在Al2O3、TiO2、ZSM-5载体上,置于DBD电极空隙间,与低温等离子体协同降解甲苯 |
催化剂类型 | 主要活性组分 | 主要协同原理 | 共有特性 |
---|---|---|---|
金属催化剂 | 贵金属:Pt、Pd、Rh、Au、Ag等; 过渡金属:Cu、Co、Fe、Mn等 | 金属组分将低温等离子体产生的O3分解,产生活性氧原子、羟基等活性物质促进了VOCs降解,此外,部分多组分金属催化剂还可提高介电常数,增加气体电离和电子能量 | 3种催化剂都能吸附污染物,增强活性粒子与污染物的碰撞概率,同时延长了污染物的停留时间,提供氧活性位点 |
金属氧化物 催化剂 | FeOx、MnOx、CuO、CoOx、Al2O3等 | 催化剂中晶格氧易被低温等离子体激活,促进氧在催化剂表面的氧化反应,从而促进降解 | |
光催化剂 | TiO2 | 低温等离子体产生紫外光,光致空穴具有很强的氧化性,能在反应过程中吸附OH-和H2O发生反应生成氧化能力极强的羟基自由基,从而加速降解 |
表2 3种类型催化剂原理和特性
催化剂类型 | 主要活性组分 | 主要协同原理 | 共有特性 |
---|---|---|---|
金属催化剂 | 贵金属:Pt、Pd、Rh、Au、Ag等; 过渡金属:Cu、Co、Fe、Mn等 | 金属组分将低温等离子体产生的O3分解,产生活性氧原子、羟基等活性物质促进了VOCs降解,此外,部分多组分金属催化剂还可提高介电常数,增加气体电离和电子能量 | 3种催化剂都能吸附污染物,增强活性粒子与污染物的碰撞概率,同时延长了污染物的停留时间,提供氧活性位点 |
金属氧化物 催化剂 | FeOx、MnOx、CuO、CoOx、Al2O3等 | 催化剂中晶格氧易被低温等离子体激活,促进氧在催化剂表面的氧化反应,从而促进降解 | |
光催化剂 | TiO2 | 低温等离子体产生紫外光,光致空穴具有很强的氧化性,能在反应过程中吸附OH-和H2O发生反应生成氧化能力极强的羟基自由基,从而加速降解 |
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