化工进展 ›› 2019, Vol. 38 ›› Issue (01): 122-137.DOI: 10.16085/j.issn.1000-6613.2018-1249
陈少奇1(),邵媛媛1,马可颖1(),郑莹2,祝京旭1,2()
收稿日期:
2018-06-16
修回日期:
2018-09-19
出版日期:
2019-01-05
发布日期:
2019-01-05
通讯作者:
马可颖,祝京旭
作者简介:
陈少奇(1996—),男,硕士研究生,研究方向为多相流态化及其过程强化。E-mail:<email>chen_shaoqi@tju.edu.cn</email>。|马可颖,博士,研究方向为多相流态化及其过程强化。E-mail:<email>keyingma@tju.edu.cn</email>|祝京旭,博士,教授,研究方向为颗粒学及流态化技术与装备。E-mail:<email>jessezhu@tju.edu.cn</email>
基金资助:
Shaoqi CHEN1(),Yuanyuan SHAO1,Keying MA1(),Ying ZHENG2,Jingxu ZHU1,2()
Received:
2018-06-16
Revised:
2018-09-19
Online:
2019-01-05
Published:
2019-01-05
Contact:
Keying MA,Jingxu ZHU
摘要:
液固循环流化床(LSCFB)是近三十年来发展起来的一种新型流化床反应器,具有传质传热效率高、操作强度大、占地面积小、可同时进行两种反应等优点,在传统化工过程集成和强化中具有广阔的应用前景。本文主要结合液固循环流化床的特点,介绍了液固循环流化床的发展历程、装置结构及基本特性,并结合几个应用实例重点阐述液固循环流化床如何在蛋白质的提取、乳酸发酵与分离、含酚废水中去除苯酚、污水生物处理等方面实现过程集成与强化。最后对液固循环流化床未来的发展进行了展望,提出了在未来的工业生产过程中,可根据工艺的需要并结合反应器的特点,将反应器进行有效地组合改进,从而实现多个反应过程的集成与强化,为今后生产模式的改变提供了新的思路。
中图分类号:
陈少奇, 邵媛媛, 马可颖, 郑莹, 祝京旭. 液固循环流化床的开发与应用——过程集成与强化[J]. 化工进展, 2019, 38(01): 122-137.
Shaoqi CHEN, Yuanyuan SHAO, Keying MA, Ying ZHENG, Jingxu ZHU. Development and applications of liquid-solid circulating fluidized beds—Process integration and intensification[J]. Chemical Industry and Engineering Progress, 2019, 38(01): 122-137.
操作条件 | 数值 |
---|---|
洗脱液的流量/L·h-1 | 30 |
乳清进料流量/L·h-1 | 5.7 |
上行床顶部冲洗水流流量/L·h-1 | 1.8 |
下行床底部冲洗水流流量/L·h-1 | 2.1 |
颗粒循环量/kg·m-2·s-1 | 1.42 |
进料乳清浓度/g·L-1 | 70 |
表1 在液固循环流化床离子交换系统中提取乳清蛋白质的操作条件及参数[32]
操作条件 | 数值 |
---|---|
洗脱液的流量/L·h-1 | 30 |
乳清进料流量/L·h-1 | 5.7 |
上行床顶部冲洗水流流量/L·h-1 | 1.8 |
下行床底部冲洗水流流量/L·h-1 | 2.1 |
颗粒循环量/kg·m-2·s-1 | 1.42 |
进料乳清浓度/g·L-1 | 70 |
操作条件 | 数值 |
---|---|
洗脱液流量/L·min-1 | 0.3 |
进料流量/L·min-1 | 0.64 |
上行床表观液速/mm·s-1 | 11.3 |
下行床表观液速/mm·s-1 | 0.6 |
颗粒循环量/kg·m-2·s-1 | 1.42 |
进料中牛血清蛋白浓度/g·L-1 | 2 |
上行床固含率 | 0.035 |
下行床固含率 | 0.34 |
表2 在液固循环流化床离子交换系统中提取牛血清蛋白的特定操作条件及参数[33]
操作条件 | 数值 |
---|---|
洗脱液流量/L·min-1 | 0.3 |
进料流量/L·min-1 | 0.64 |
上行床表观液速/mm·s-1 | 11.3 |
下行床表观液速/mm·s-1 | 0.6 |
颗粒循环量/kg·m-2·s-1 | 1.42 |
进料中牛血清蛋白浓度/g·L-1 | 2 |
上行床固含率 | 0.035 |
下行床固含率 | 0.34 |
参数 | 进水/mg·L-1 | 出水/mg·L-1 |
---|---|---|
COD | 273 | 26 |
SCOD | 73 | 21 |
NH4 +-N | 19 | 0.7 |
NO3 –-N | 0.5 | 6.5 |
TN | 31.2 | 8.6 |
TP | 3.8 | 0.8 |
TSS | 144 | 4 |
VSS | 118 | 3 |
表3 CFBBR-Ⅰ系统进出水水质[59]
参数 | 进水/mg·L-1 | 出水/mg·L-1 |
---|---|---|
COD | 273 | 26 |
SCOD | 73 | 21 |
NH4 +-N | 19 | 0.7 |
NO3 –-N | 0.5 | 6.5 |
TN | 31.2 | 8.6 |
TP | 3.8 | 0.8 |
TSS | 144 | 4 |
VSS | 118 | 3 |
参数 | 进水/mg·L-1 | 出水/mg·L-1 |
---|---|---|
COD | 262 | 20 |
SCOD | 234 | 9.5 |
NH4 +-N | 26.1 | 0.5 |
NO3 –-N | 0.7 | 3.9 |
TN | 29.5 | 5.4 |
TP | 4.4 | 3.8 |
TSS | 27 | 16.3 |
VSS | 19 | 12 |
表4 CFBBR-Ⅱ系统的进出水水质[60]
参数 | 进水/mg·L-1 | 出水/mg·L-1 |
---|---|---|
COD | 262 | 20 |
SCOD | 234 | 9.5 |
NH4 +-N | 26.1 | 0.5 |
NO3 –-N | 0.7 | 3.9 |
TN | 29.5 | 5.4 |
TP | 4.4 | 3.8 |
TSS | 27 | 16.3 |
VSS | 19 | 12 |
参数 | CFBBR-Ⅰ[ | CFBBR-Ⅱ[ | 中试 CFBBR[ |
---|---|---|---|
HRT/h | 2.04 | 2.88 | 2.03 |
EBCT/h | 0.82 | 0.98 | 1.5 |
SRT/d | 44~56 | 72~108 | 20~39 |
OLR/kg·m-3·d-1 | 3.36 | 2.23 | 4.12 |
COD/% | 91 | 97 | 90 |
N/% | 78 | 84 | 80 |
P/% | 85 | 12 | 70 |
生物产量/mgVSS·(mgCOD)-1 | 0.12~0.135 | 0.071 | 0.12~0.16 |
表5 几种生物反应器的BNR效果总结[51]
参数 | CFBBR-Ⅰ[ | CFBBR-Ⅱ[ | 中试 CFBBR[ |
---|---|---|---|
HRT/h | 2.04 | 2.88 | 2.03 |
EBCT/h | 0.82 | 0.98 | 1.5 |
SRT/d | 44~56 | 72~108 | 20~39 |
OLR/kg·m-3·d-1 | 3.36 | 2.23 | 4.12 |
COD/% | 91 | 97 | 90 |
N/% | 78 | 84 | 80 |
P/% | 85 | 12 | 70 |
生物产量/mgVSS·(mgCOD)-1 | 0.12~0.135 | 0.071 | 0.12~0.16 |
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