氯的脱除对丙烷脱氢PtSnNa/Al2O3催化剂结构的影响

doi:10.16085/j.issn.1000-6613.2017-2047

化工进展 ›› 2018, Vol. 37 ›› Issue (09): 3424-3429.DOI: 10.16085/j.issn.1000-6613.2017-2047

氯的脱除对丙烷脱氢PtSnNa/Al₂O₃催化剂结构的影响

张海娟¹, 赵悦², 万海², 高杰¹, 高文艺¹, 赵珍珍¹

1 辽宁石油化工大学化学化工与环境学部, 辽宁抚顺 113001;
2 中国石油抚顺石化公司, 辽宁抚顺 113001

收稿日期:2017-09-30 修回日期:2018-01-23 出版日期:2018-09-05 发布日期:2018-09-05
通讯作者: 张海娟(1973-),女,副教授。
作者简介:张海娟(1973-),女,副教授。E-mail:zhj_w@163.com。
基金资助:
辽宁省自然基金项目（20170540584）。

The effect of chlorine elimination on the structure of PtSnNa/Al₂O₃ catalyst for propane dehydrogenation

ZHANG Haijuan¹, ZHAO Yue², WAN Hai², GAO Jie¹, GAO Wenyi¹, ZHAO Zhenzhen¹

1 Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, Liaoning, China;
2 Fushun Petrochemical Company, China National Petroleum Corporation, Fushun 113001, Liaoning, China

Received:2017-09-30 Revised:2018-01-23 Online:2018-09-05 Published:2018-09-05

摘要/Abstract

摘要： 考察了氯的脱除对丙烷脱氢铂锡催化剂结构和反应性能的影响，并采用XRD、N₂吸脱附、TPR、NH₃-TPD、TEM和Raman等方法进行表征。结果表明，氯的脱除温度显著影响催化剂的酸性、孔体积、比表面积、孔径和Pt颗粒尺寸。随着处理温度的提高，催化剂酸性、比表面积、孔体积都呈现下降的趋势，平均孔径增加，Pt颗粒的烧结程度加剧。随着处理温度的增加，催化剂初活性逐渐降低，丙烯选择性增加，稳定性出现先增加后降低趋势。研究表明，氯的较佳的脱除温度为540℃，催化剂具有很好的脱氢性能和稳定性，收率最高。

关键词: 丙烷, 氢, 水热, 处理温度, 氯的脱除, 烧结

Abstract: The effect of chlorine elimination on the catalytic performance and structure of PtSnNa/Al₂O₃ catalyst for propane dehydrogenation was studied. The catalysts were characterized by XRD, N₂ adsorption-desorption, TPR, NH₃-TPD, TEM and Raman spectroscopy, respectively. The results showed that the chlorine elimination temperature affected the properties of the catalysts greatly, such as acidity, specific surface area, pore volume, mean pore diameter and the size of Pt particle. With the increase of the treatment temperature, the acidity the specific surface area and pore volume of the catalyst,dramatically decreased, whereas the mean pore diameter increased. Meantime, the extent of Pt sintering was aggravated. At higher treatment temperature, the catalyst has lower initial activity and higher propylene selectivity. But the stability increased firstly and then decreased with the raising of treatment temperature. The highest yield of propylene was obtained with the treatment temperature of 540℃, and the PtSnNa/Al₂O₃ catalyst exhibited the best performance of propane dehydrogenation and stability.

Key words: propane, hydrogen, hydrothermal, treatment temperature, chlorine elimination, sintering

中图分类号:

O623.254.3

张海娟, 赵悦, 万海, 高杰, 高文艺, 赵珍珍. 氯的脱除对丙烷脱氢PtSnNa/Al₂O₃催化剂结构的影响[J]. 化工进展, 2018, 37(09): 3424-3429.

ZHANG Haijuan, ZHAO Yue, WAN Hai, GAO Jie, GAO Wenyi, ZHAO Zhenzhen. The effect of chlorine elimination on the structure of PtSnNa/Al₂O₃ catalyst for propane dehydrogenation[J]. Chemical Industry and Engineering Progress, 2018, 37(09): 3424-3429.

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氯的脱除对丙烷脱氢PtSnNa/Al₂O₃催化剂结构的影响

The effect of chlorine elimination on the structure of PtSnNa/Al₂O₃ catalyst for propane dehydrogenation

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