化工进展 ›› 2018, Vol. 37 ›› Issue (01): 68-79.DOI: 10.16085/j.issn.1000-6613.2017-0798
孟凡飞, 王海波, 廖昌建
收稿日期:
2017-04-30
修回日期:
2017-05-24
出版日期:
2018-01-05
发布日期:
2018-01-05
通讯作者:
孟凡飞(1985-),男,硕士研究生,工程师。
作者简介:
孟凡飞(1985-),男,硕士研究生,工程师。E-mail:mengfanfei.fshy@sinopec.com。
MENG Fanfei, WANG Haibo, LIAO Changjian
Received:
2017-04-30
Revised:
2017-05-24
Online:
2018-01-05
Published:
2018-01-05
摘要: 沼气是一种重要的可再生能源,对沼气进行充分高值利用对于缓解我国能源需求和环境压力具有重要意义。沼气在高值利用前必须进行脱碳提纯处理,本文介绍了一种可用于沼气提纯的新技术——水合物分离技术。介绍了水合物分离技术的基本理论,调研总结了水合物法提纯沼气和可用于沼气体系(CH4/CO2)的水合物分离技术研究进展,包括相平衡研究、热力学促进剂、动力学促进剂、机械强化、外场强化、添加多孔介质/纳米流体等和采用油/水乳液促进技术,并对各种水合物分离促进技术进行了分析:相平衡研究为水合物法提纯沼气提供了理论基础;合理地选用热力学和动力学促进剂能够有效改善气体水合物相平衡条件,促进水合物生成,增加储气效果和提高分离效率;机械强化及外场作用通过强化水合反应过程的传质传热效果促进水合物生成;添加多孔介质和纳米流体等能够增大气液接触面积,对水合过程发挥促进作用;采用油/水乳液不但能够强化气液接触,而且微乳状态下的水合物具有很好的流动性,具有良好工业应用前景。最后对水合物法提纯沼气技术进行了展望,水合物提纯沼气研究虽处在起步阶段,但随着研究的不断深入,该技术凭借操作条件温和,对原料气要求低,并且具有操作简单灵活、安全性高、环保无污染等优点,必将在我国沼气产业发展过程中发挥作用。
中图分类号:
孟凡飞, 王海波, 廖昌建. 水合物法提纯沼气技术研究进展[J]. 化工进展, 2018, 37(01): 68-79.
MENG Fanfei, WANG Haibo, LIAO Changjian. Research progress of hydrate separation technology for biogas purification[J]. Chemical Industry and Engineering Progress, 2018, 37(01): 68-79.
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