Au/CeO2基材料在挥发性有机物催化燃烧反应中的研究进展

doi:10.16085/j.issn.1000-6613.2017-0536

摘要/Abstract

摘要： 挥发性有机物（VOCs）来源广泛、种类繁多，是大气污染的重要组成部分，因其高毒性和高危害性，严重威胁人类健康。催化燃烧是目前众多VOCs消除技术中最有效的手段之一。因纳米金颗粒的高催化活性和二氧化铈独特的低温氧化还原性能，目前围绕Au/CeO₂基材料在催化燃烧VOCs方面的应用日渐成为热点课题。本文着重从CeO₂结构调控、载体掺杂及Au修饰改性3方面归纳梳理了目前Au/CeO₂基材料治理不同种类VOCs时所采用的策略及其表现出来的特性，总结了影响材料性能的各种因素。针对纳米金的结构特点，指出Au/CeO₂基材料应用于VOCs催化燃烧的研究难点，并对未来的研究发展趋势进行了展望，为进一步提高Au/CeO₂基材料的催化性能，拓宽其应用范围，开发高效稳定、廉价实用的催化剂提供参考。

关键词: 催化燃烧, 有机化合物, 金催化, 催化剂载体, 纳米材料

Abstract: Volatile organic compounds(VOCs)are a large group of pollutants emitted from a great variety of sources. They are regarded as major contributors to air pollution and serious threats to human health due to their hazardous and toxic nature. Among numerous VOCs removal methods, catalytic combustion is considered as one of the most efficient methods. Presently, the catalytic combustion of VOCs over Au/CeO₂-based materials becomes a hot topic owing to the excellent catalytic performance of nano-Au and the unique low-temperature redox property of CeO₂. Therefore,a series of Au/CeO₂-based materials for the removal of different kinds of VOCs are summarized in this review. The application strategies and properties of these catalysts are outlined mainly from three aspects:structure modification of CeO₂,carrier doping and Au decoration. Furthermore, different factors that affect the catalytic performance are discussed. Finally, the challenges and outlooks of catalytic combustion of VOCs over Au/CeO₂-based materials are featured based on the structural properties of nano-Au. This brief summary provides reference for improving the properties of Au/CeO₂-based catalysts, broadening their application scopes,and developing highly efficient and stable catalysts.

Key words: catalytic combustion, organic compounds, gold catalysis, catalyst support, nanomaterials

中图分类号:

张晓岚, 袁静, 蔡婷, 叶俊辉, 何丹农. Au/CeO₂基材料在挥发性有机物催化燃烧反应中的研究进展[J]. 化工进展, 2017, 36(12): 4453-4461.

ZHANG Xiaolan, YUAN Jing, CAI Ting, YE Junhui, HE Dannong. Research progress of Au/CeO₂-based materials for catalytic combustion of VOCs[J]. Chemical Industry and Engineering Progress, 2017, 36(12): 4453-4461.

参考文献

[1] KAMAL M S,RAZZAK S A,HOSSAIN M M. Catalytic oxidation of volatile organic compounds(VOCs)-a review[J]. Atmospheric Environment,2016,140:117-134.
[2] 汪涵,郭桂悦,周玉莹,等. 挥发性有机废气治理技术的现状与进展[J]. 化工进展,2009,28(10):1833-1841. WANG H,GUO G Y,ZHOU Y Y,et al. Status and progress of treating volatile organic compounds[J]. Chemical Industry and Engineering Progress,2009,28(10):1833-1841.
[3] 阚家伟,李兵,李林,等. 含氯挥发性有机化合物催化燃烧催化剂的研究进展[J]. 化工进展,2016,35(2):499-505. KAN J W,LI B,LI L,et al. Advances in catalysts for catalytic combustion of chlorinated volatile organic compounds[J]. Chemical Industry and Engineering Progress,2016,35(2):499-505.
[4] HARUTA M,KOBAYASHI T,SANO H,et al. Novel gold catalysts for the oxidation of carbon monoxide at a temperature far below 0.DEG.C.[J]. Chemistry Letters,1987,16(2):405-408.
[5] 李金金,胡江林,李光兴. 金催化在化工过程中的研究与应用进展[J]. 化工进展,2011,30(12):2575-2585. LI J J,HU J L,LI G X. Progress in research and application of gold catalysis in chemical industry[J]. Chemical Industry and Engineering Progress,2011,30(12):2575-2585.
[6] 李永强,朱华星. 铈基氧化物用于VOCs催化燃烧的研究进展[J]. 重庆工商大学学报(自然科学版),2016,33(2):101-105. LI Y Q,ZHU H X. Research progress in ceria based oxides for catalytic combustion of volatile organic compounds[J]. Journal of Chongqing Technology and Business University (Natural Science Edition),2016,33(2):101-105.
[7] DELANNOY L,FAJERWERG K,LAKSHMANAN P,et al. Supported gold catalysts for the decomposition of VOC:total oxidation of propene in low concentration as model reaction[J]. Applied Catalysis B:Environmental,2010,94(1):117-124.
[8] SCIRE S,LIOTTA L F. Supported gold catalysts for the total oxidation of volatile organic compounds[J]. Applied Catalysis B:Environmental,2012,125:222-246.
[9] TOMATIS M,XU H H,HE J,et al. Recent development of catalysts for removal of volatile organic compounds in flue gas by combustion:a review[J]. Journal of Chemistry,2016. DOI:10.1155/2016/832/4826.
[10] LI J,LIU H,DENG Y,et al. Emerging nanostructured materials for the catalytic removal of volatile organic compounds[J]. Nanotechnology Reviews,2016,5(1):147-181.
[11] LI H Y,WANG H F,GUO Y L,et al. Exchange between sub-surface and surface oxygen vacancies on CeO₂(111):a new surface diffusion mechanism[J]. Chemical Communications,2011,47(21):6105-6107.
[12] NEDYALKOVA R,ILIEVA L,BERNARD M C,et al. Gold supported catalysts on titania and ceria,promoted by vanadia or molybdena for complete benzene oxidation[J]. Materials Chemistry & Physics,2009,116(1):214-218.
[13] ZHANG J,JIN Y,LI C,et al. Creation of three-dimensionally ordered macroporous Au/CeO₂ catalysts with controlled pore sizes and their enhanced catalytic performance for formaldehyde oxidation[J]. Applied Catalysis B:Environmental,2009,91(1):11-20.
[14] OUSMANE M,LIOTTA L F,CARLO G D,et al. Supported Au catalysts for low-temperature abatement of propene and toluene,as model VOCs:support effect[J]. Applied Catalysis B:Environmental,2011,101(3/4):629-637.
[15] YING F,WANG S,AU C T,et al. Highly active and stable mesoporous Au/CeO₂ catalysts prepared from MCM-48 hard-template[J]. Microporous & Mesoporous Materials,2011,142(1):308-315.
[16] LI H F,ZHANG N,CHEN P,et al. High surface area Au/CeO₂,catalysts for low temperature formaldehyde oxidation[J]. Applied Catalysis B:Environmental,2011,110(22):279-285.
[17] LIU B,LI C,ZHANG Y,et al. Investigation of catalytic mechanism of formaldehyde oxidation over three-dimensionally ordered macroporous Au/CeO₂,catalyst[J]. Applied Catalysis B:Environmental,2012,111/112(2):467/475.
[18] LIU B,LIU Y,LI C,et al. Three-dimensionally ordered macroporous Au/CeO₂-Co₃O₄,catalysts with nanoporous walls for enhanced catalytic oxidation of formaldehyde[J]. Applied Catalysis B:Environmental,2012,127:47-58.
[19] ILIEVA L,PETROVA P,TABAKOVA T,et al. Relationship between structural properties and activity in complete benzene oxidation over Au/CeO₂-CoO_x,catalysts[J]. Catalysis Today,2012,187(1):30-38.
[20] TABAKOVA T,DIMITROV D,MANZOLI M,et al. Impact of metal doping on the activity of Au/CeO₂,catalysts for catalytic abatement of VOCs and CO in waste gases[J]. Catalysis Communications,2013,35(17):51-58.
[21] CHEN B B,SHI C,CROCKER M,et al. Catalytic removal of formaldehyde at room temperature over supported gold catalysts[J]. Applied Catalysis B:Environmental,2013,132/133(1):245-255.
[22] ABOUKAIS A,AOUAD S,EL-AYADI H,et al. Catalytic oxidation of propylene,toluene,carbon monoxide,and carbon black over Au/CeO₂ solids:comparing the impregnation and the deposition-precipitation methods[J]. The Scientific World Journal,2013,313:824979.
[23] TAN W,GUO G,DENG J,et al. Au/Ce_0.6Zr_0.3Y_0.1O₂ nanorods:highly active catalysts for the oxidation of carbon monoxide and toluene[J]. Industrial & Engineering Chemistry Research,2014,53(48):18452-18461.
[24] XU Q,LEI W,LI X,et al. Efficient removal of formaldehyde by nanosized gold on well-defined CeO₂ nanorods at room temperature[J]. Environmental Science & Technology,2014,48(16):9702-9708.
[25] JIANG X,HUA J,DENG H,et al. Influence of pre-added NaOH on the microstructure of Au-CeO₂ catalyst and its activity for benzene oxidation[J]. Journal of Molecular Catalysis A:Chemical,2014,383/384(3):188-193.
[26] BARAKAT T,IDAKIEV V,COUSIN R,et al. Total oxidation of toluene over noble metal based Ce,Fe and Ni doped titanium oxides[J]. Applied Catalysis B:Environmental,2014,146:138-146.
[27] YANG H,DENG J,LIU Y,et al. Preparation and catalytic performance of Ag,Au,Pd or Pt nanoparticles supported on 3DOM CeO₂-Al₂O₃,for toluene oxidation[J]. Journal of Molecular Catalysis A:Chemical,2016,414:9-18.
[28] ALMUKHLIFI H A,BURNS R C. The complete oxidation of isobutane over CeO₂and Au/CeO₂,and the composite catalysts MO_x/CeO₂ and Au/M_x/CeO₂ (Mⁿ⁺=Mn,Fe,Co and Ni):the effects of gold nanoparticles obtained from n-hexanethiolate-stabilized gold nanoparticles[J]. Journal of Molecular Catalysis A:Chemical,2016,415:131-143.
[29] KAMINSKI P,ZIOLEK M. Mobility of gold,copper and cerium species in Au,Cu/Ce,Zr-oxides and its impact on total oxidation of methanol[J]. Applied Catalysis B:Environmental,2016,187:328-341.
[30] ILIEVA L,PETROVA P,LIOTTA L F,et al. Gold catalysts on Y-doped ceria supports for complete benzene oxidation[J]. Catalysts,2016,6(7):99.
[31] 于旭霞,冯俊小. 催化燃烧治理氯苯类挥发性有机化合物的最新进展[J]. 化工进展,2016,35(5):1514-1518. YU X X,FENG J X. Recent process in the removal of chlorobenzenes volatile organic compounds by catalytic combustion[J]. Chemical Industry and Engineering Progress,2016,35(5):1514-1518.
[32] BONELLI R,ALBONETTI S,MORANDI V,et al. Design of nano-sized FeO_x and Au/FeO_x catalysts supported on CeO₂ for total oxidation of VOC[J]. Applied Catalysis A:General,2011,395(1):10-18.
[33] 夏寒梅,陈立芳,方云进. 高分散金纳米催化剂的研究进展[J]. 化工进展,2010,29(12):2274-2282. XIAO H M,CHEN L F,FANG Y J. Progress in highly dispersed gold nanocatalysts[J]. Chemical Industry and Engineering Progress,2010,29(12):2274-2282.
[34] LAKSHMANAN P,KIM D H,PARK E D. Effect of gold particle size on steam reforming of methanol over Au/CeO₂-ZrO₂catalysts[J]. Journal of Nanoscience and Nanotechnology,2016,16(5):4386-4392.
[35] QIAO B,LIU J,WANG Y G,et al. Highly efficient catalysis of preferential oxidation of CO in H₂-rich stream by gold single-atom catalysts[J]. ACS Catalysis,2015,5(11):6249-6254.
[36] LEE D S,CHEN Y W. The mutual promotional effect of Au-Pd/CeO₂ bimetallic catalysts on destruction of toluene[J]. Journal of the Taiwan Institute of Chemical Engineers,2013,44(1):40-44.
[37] FIORENZA R,CRISAFULLI C,CONDORELLI G G,et al. Au-Ag/CeO₂,and Au-Cu/CeO₂,catalysts for volatile organic compounds oxidation and CO preferential oxidation[J]. Catalysis Letters,2015,145(9):1-12.
[38] ALI A M,DAOUS M A,PETROV L A. Role of Mn in supported Au-Mn/TOS catalysts[J]. Bulgarian Chemical Communications,2015,47:25-33.
[39] TABAKOVA T,ILIEVA L,PETROVA P,et al. Complete benzene oxidation over mono and bimetallic Au-Pd catalysts supported on Fe-modified ceria[J]. Chemical Engineering Journal,2015,260:133-141.
[40] PETROVA P,MILANOVA M,TABAKOVA T,et al. Nanosized gold catalysts on cobalt-modified ceria supports for complete benzene oxidation:effect of support preparation and pretreatment conditions[J]. Journal of Chemical Technology & Metallurgy,2016,51(5):500-507.
[41] 谭伟. Au/Ce_0.6Zr_0.3Y_0.1O₂和Au-Pd/Ce_0.6Zr_0.3Y_0.1O₂催化剂可控制备及其对CO和甲苯氧化的催化性能研究[D]. 北京:北京工业大学,2015. TAN W. Controlled preparation and catalytic performance of Au/Ce_0.6Zr_0.3Y_0.1O₂and Au-Pd/Ce_0.6Zr_0.3Y_0.1O₂ for the oxidation of carbon monoxide and toluene[D]. Beijing:Beijing University of Technology,2015.
[42] SOLSONA B,GARCIA T,MURILLO R,et al. Ceria and gold/ceria catalysts for the abatement of polycyclic aromatic hydrocarbons:an in situ DRIFTS study[J]. Topics in Catalysis,2009,52(5):492-500.
[43] LAMALLEM M,COUSIN R,THOMAS R,et al. Investigation of the effect of support thermal treatment on gold-based catalysts' activity towards propene total oxidation[J]. Comptes Rendus Chimie,2009,12(6):772-778.
[44] PESSTRYAKOV A N,LUNIN V V,BOGDANCHIKOVA N,et al. Active states of gold in small and big metal particles in CO and methanol selective oxidation[J]. Fuel,2013,110(4):48-53.
[45] DELANNOY L,FAJERWERG K. Supported gold catalysts for the decomposition of VOC:total oxidation of propene in low concentration as model reaction[J]. Applied Catalysis B:Environmental,2010,94(1):117-124.
[46] HERNANDEZ W Y,ROMERO-SARRIA F,CENTENO M A,et al. In situcharacterization of the dynamic gold-support interaction over ceria modified Eu³⁺. influence of the oxygen vacancies on the CO oxidation reaction[J]. The Journal of Physical Chemistry C,2010,114(24):10857-10865.
[47] QIAO B,WANG A,YANG X,et al. Single-atom catalysis of CO oxidation using Pt₁/FeO_x[J]. Nature Chemistry,2011,3(8):634-641.
[48] YANG T,FUKUDA R,HOSOKAWA S,et al. A theoretical investigation on CO oxidation by single-atom catalysts M₁/γ-Al₂O₃ (M=Pd,Fe,Co,and Ni)[J]. ChemCatChem,2017,9(7):1222-1229.
[49] TANG H,LIU F,WEI J,et al. Ultrastable hydroxyapatite/titanium-dioxide-supported gold nanocatalyst with strong metal-support interaction for carbon monoxide oxidation[J]. Angewandte Chemie International Edition,2016,55(36):10606-10611.
[50] ZHAN W,HE Q,LIU X,et al. A sacrificial coating strategy toward enhancement of metal-support interaction for ultrastable Au nanocatalysts[J]. Journal of the American Chemical Society,2016,138(49):16130-16139.

Au/CeO₂基材料在挥发性有机物催化燃烧反应中的研究进展

Research progress of Au/CeO₂-based materials for catalytic combustion of VOCs

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张婷婷, 左旭乾, 田玲娣, 王世猛. 化工园区挥发性有机物排放清单及因子库构建方法[J]. 化工进展, 2023, 42(S1): 549-557.
[2]	王鹏, 史会兵, 赵德明, 冯保林, 陈倩, 杨妲. 过渡金属催化氯代物的羰基化反应研究进展[J]. 化工进展, 2023, 42(9): 4649-4666.
[3]	葛亚粉, 孙宇, 肖鹏, 刘琦, 刘波, 孙成蓥, 巩雁军. 分子筛去除VOCs的研究进展[J]. 化工进展, 2023, 42(9): 4716-4730.
[4]	杨莹, 侯豪杰, 黄瑞, 崔煜, 王兵, 刘健, 鲍卫仁, 常丽萍, 王建成, 韩丽娜. 利用煤焦油中酚类物质Stöber法制备碳纳米球用于CO₂吸附[J]. 化工进展, 2023, 42(9): 5011-5018.
[5]	尹新宇, 皮丕辉, 文秀芳, 钱宇. 特殊浸润性材料在防治油气管道中水合物成核与聚集的应用[J]. 化工进展, 2023, 42(8): 4076-4092.
[6]	吴亚, 赵丹, 方荣苗, 李婧瑶, 常娜娜, 杜春保, 王文珍, 史俊. 用于复杂原油乳液的高效破乳剂开发及应用研究进展[J]. 化工进展, 2023, 42(8): 4398-4413.
[7]	徐沛瑶, 陈标奇, KANKALA Ranjith Kumar, 王士斌, 陈爱政. 纳米材料用于铁死亡联合治疗的研究进展[J]. 化工进展, 2023, 42(7): 3684-3694.
[8]	于志庆, 黄文斌, 王晓晗, 邓开鑫, 魏强, 周亚松, 姜鹏. B掺杂Al₂O₃@C负载CoMo型加氢脱硫催化剂性能[J]. 化工进展, 2023, 42(7): 3550-3560.
[9]	龚鹏程, 严群, 陈锦富, 温俊宇, 苏晓洁. 铁酸钴复合碳纳米管活化过硫酸盐降解铬黑T的性能及机理[J]. 化工进展, 2023, 42(7): 3572-3581.
[10]	许春树, 姚庆达, 梁永贤, 周华龙. 氧化石墨烯/碳纳米管对几种典型高分子材料的性能影响[J]. 化工进展, 2023, 42(6): 3012-3028.
[11]	张巍, 秦川, 谢康, 周运河, 董梦瑶, 李婕, 汤云灏, 马英, 宋健. H₂-SCR改性铂系催化剂低温脱硝的应用及性能强化挑战[J]. 化工进展, 2023, 42(6): 2954-2962.
[12]	张晨宇, 王宁, 徐洪涛, 罗祝清. 纳米颗粒强化传热的多级潜热储热器性能评价[J]. 化工进展, 2023, 42(5): 2332-2342.
[13]	王科菊, 赵成, 胡晓玫, 云军阁, 魏凝涵, 姜雪迎, 邹昀, 陈志航. 金属氧化物低温催化氧化VOCs的研究进展[J]. 化工进展, 2023, 42(5): 2402-2412.
[14]	马源, 肖晴月, 岳君容, 崔彦斌, 刘姣, 许光文. CeO₂-Al₂O₃复合载体负载Ni基催化剂催化CO _x 共甲烷化性能[J]. 化工进展, 2023, 42(5): 2421-2428.
[15]	陈少华, 王义华, 胡强飞, 胡坤, 陈立爱, 李洁. 电化学修饰电极在检测Cr(Ⅵ)中的研究进展[J]. 化工进展, 2023, 42(5): 2429-2438.