异丁烷/丁烯烷基化固体酸催化剂的再生方法研究进展

doi:10.16085/j.issn.1000-6613.2015.09.014

化工进展 ›› 2015, Vol. 34 ›› Issue (09): 3296-3302.DOI: 10.16085/j.issn.1000-6613.2015.09.014

异丁烷/丁烯烷基化固体酸催化剂的再生方法研究进展

彭凯, 张成喜, 李永祥

中国石化石油化工科学研究院石油化工催化材料与反应工程国家重点实验室, 北京 100083

收稿日期:2014-12-01 修回日期:2015-04-02 出版日期:2015-09-05 发布日期:2015-09-05
通讯作者: 李永祥,教授级高级工程师,从事固体酸烷基化和己内酰胺绿色技术研究。E-mail:liyx.ripp@sinopec.com
作者简介:彭凯(1988-),男,硕士研究生,研究方向为固体酸烷基化。E-mail:pengkaisky@sina.com
基金资助:
中国石油化工股份有限公司项目(114026、114039)。

Advances in regeneration methods of solid acid catalyst for isobutane/butene alkylation

PENG Kai, ZHANG Chengxi, LI Yongxiang

State Key Laboratory of Catalytic Material and Reaction Engineering, Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China

Received:2014-12-01 Revised:2015-04-02 Online:2015-09-05 Published:2015-09-05

摘要/Abstract

摘要： 阐述了固体酸烷基化催化剂在异丁烷/丁烯烷基化中的再生方法研究进展,包括金属临氢再生、氧化煅烧再生、超临界流体再生、洗涤再生,同时对固体酸烷基化催化剂的失活原因和失活形式进行了分析评述。这些方法在一定条件下可以实现催化剂不同程度的再生,但由于操作以及成本等原因都停留在实验室阶段,本文综合比较了各种再生方法的再生工艺过程以及再生效果,分析各种再生方法的优劣。固体酸烷基化催化剂失活较快是阻碍异丁烷/丁烯固体酸烷基化工艺工业化的关键因素,研究探索操作简单、成本低、有效的固体酸烷基化催化剂再生方法仍将是今后该领域的研究热点。

关键词: 固体酸, 催化剂, 异丁烷, 丁烯, 烷基化, 失活, 再生

Abstract: Regeneration methods of solid acid catalyst for isobutane/butene alkylation were reviewed,including hydrogenative regeneration,classical oxidative treatment,supercritical fluid regeneration,and solvent extraction regeneration,the cause and type of deactivation about solid acid catalyst were also analyzed and reviewed. All these methods can be employed to recover the activity of solid acid catalysts in some degree,but they are all in lab research stage due to their complicate operation and high cost. This paper will compare the process and performance of these regeneration methods,analyze their advantage and shortcoming. Quick deactivation of catalyst is the key reason to hinder the industrialization of solid acid catalyst technology for isobutane/butene alkylation. Researching and finding regeneration methods,which are efficient and easily operated with low cost,will still be research focus in this field in future.

Key words: solid acid, catalyst, isobutane, butene, alkylation, deactivation, regeneration

中图分类号:

TE02

彭凯, 张成喜, 李永祥. 异丁烷/丁烯烷基化固体酸催化剂的再生方法研究进展[J]. 化工进展, 2015, 34(09): 3296-3302.

PENG Kai, ZHANG Chengxi, LI Yongxiang. Advances in regeneration methods of solid acid catalyst for isobutane/butene alkylation[J]. Chemical Industry and Engineering Progree, 2015, 34(09): 3296-3302.

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异丁烷/丁烯烷基化固体酸催化剂的再生方法研究进展

Advances in regeneration methods of solid acid catalyst for isobutane/butene alkylation

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