基于太阳能蓄热过程的甲烷二氧化碳重整研究进展

doi:10.16085/j.issn.1000-6613.2016.06.012

摘要/Abstract

摘要： 热化学储能技术因为其储能密度高、热损小、能长距离运输等优点而成为保证太阳能长久稳定供应的关键技术。本文对基于甲烷二氧化碳重整反应的太阳能热化学储热系统研究现状进行了回顾,重点讨论了甲烷重整催化剂、重整反应器以及储能系统整体的传热特性等3个方向的研究进展。指出新型高效催化剂以及反应器开发和性能测试是目前该领域的主要研究方向。发现辐射热损失、非均匀温度分布特性、辐射热流的时变波动特性,以及由此造成的能量与化学反应的不匹配限制了热化学系统能量储存效率的进一步提高,并提出催化剂的催化特性与物性/结构参数依变关系,反应器辐射吸收特性、传热传质特性和反应特性之间的相互作用机制,以及系统时变动态特性与反应物流/辐射能流的匹配关系是建立甲烷重整热化学储能系统优化设计理论亟待解决的关键问题。

关键词: 太阳能, 热化学储能, 甲烷重整反应, 催化剂, 反应器, 传热特性

Abstract: School of Chemical Engineering and Technology,Xi'an Jiaotong University,Xi'an 710049,Shaanxi,China)Abstract:Thermochemical energy storage is the key technique to guarantee long term and steady supply of solar energy due to its advantages of high energy density,low heat loss as well as transportability over long distance. In this work,the development of CO₂ reforming of methane that has been applied in the solar thermochemical energy storage system was summarized. Particular emphasis was put on the studies of methane reforming catalyst,methane reforming reactor,and thermal analysis of thermochemical energy storage system. New high-efficiency catalysts and reforming reactors were the main interests of the current researches. Radiation heat loss,non-uniform temperature distribution,time-varying radiation heat flux,as well as the mismatching between energy and chemical reaction restricted the improvement of thermochemical energy storage efficiency. In order to further improve the performance of thermochemical energy storage system and establish its optimization design theory,some key questions were proposed to be answered,including the relationship between the catalytic performance and properties/structure parameters of the catalyst,the interaction mechanism of thermal radiation absorption,heat/mass transfer and thermochemical reaction characteristics of the chemical reactor,as well as the time-varying dynamic features and matching relationship with radiation heat flux of the thermochemical system.

Key words: solar energy, thermochemical energy storage, reforming of methane, catalyst, reforming reactor, heat transfer characteristics

中图分类号:

TK519

谢涛, 杨伯伦. 基于太阳能蓄热过程的甲烷二氧化碳重整研究进展[J]. 化工进展, 2016, 35(06): 1723-1732.

XIE Tao, YANG Bolun. Advances of CO₂ reforming of methane based on the solar energy storage[J]. Chemical Industry and Engineering Progree, 2016, 35(06): 1723-1732.

参考文献

[1] KENISARIN M,MAHKAMOV K. Solar energy storage using phase change materials[J]. Renewable & Sustainable Energy Reviews,2007,11(9):1913-1965.
[2] ZALBA B,MARIN J M,CABEZA L F,et al. Review on thermal energy storage with phase change:materials,heat transfer analysis and applications[J]. Applied Thermal Engineering,2003,23 (3):251-283.
[3] 杜娟. 甲烷重整热化学储能过程催化反应及传输特性[D]. 广州:华南理工大学,2013.
[4] 吴娟,龙新峰. 太阳能热化学储能研究进展[J]. 化工进展,2014,33(12):3238-3245.
[5] SHEU E J,MOKHEIMER E M,GHONIEM A F. A review of solar methane reforming systems[J]. International Journal of Hydrogen Energy,2015,40(38):12929-12955.
[6] DAHL J K,WEIMER A W,LEWANDOWSKI A,et al. Dry reforming of methane using a solar-thermal aerosol flow reactor[J]. Industrial & Engineering Chemistry Research,2004,43(18): 5489-5495.
[7] KLEIN H H,KARNI J,RUBIN R. Dry methane reforming without a metal catalyst in a directly irradiated solar particle reactor[J]. Journal of Solar Energy Engineering,2009,131(2):021001.
[8] PAKHARE D,SPIVEY J. A review of dry (CO₂) reforming of methane over noble metal catalysts[J]. Chemical Society Reviews,2014,43(22):7813-7837.
[9] FISCHER F,TROPSCH H. Conversion of methane into hydrogen and carbon monoxide[J]. Brennst-Chem,1928,3(9):39–46.
[10] ASHCROFT A,CHEETHAM A,GREEN M. Partial oxidation of methane to synthesis gas using carbon dioxide[J]. Nature,1991,352 (6332):225-226.
[11] SOLYMOSI F,KUTSAN G,ERDOHELYI A. Catalytic reaction of CH₄ with CO₂ over alumina-supported Pt metals[J]. Catalysis Letters,1991,11(2):149-156.
[12] WANG S,LU G Q,MILLAR G J. Carbon dioxide reforming of methane to produce synthesis gas over metal-supported catalysts:state of the art[J]. Energy & Fuels,1996,10(4):896-904.
[13] BRADFORD M C J,VANNICE M A. Catalytic reforming of methane with carbon dioxide over nickel catalysts I. Catalyst characterization and activity[J]. Applied Catalysis A:General,1996,142(1):73-96.
[14] KODAMA T,KIYAMA A,SHIMIZU K I. Catalytically activated metal foam absorber for light-to-chemical energy conversion via solar reforming of methane[J]. Energy & Fuels,2003,17(1):13-17.
[15] KODAMA T,KIYAMA A,MORIYAMA T,et al. Solar methane reforming using a new type of catalytically-activated metallic foam absorber[J]. Journal of Solar Energy Engineering,2004,126(2):808-811.
[16] GOKON N,OSAWA Y,NAKAZAWA D,et al. Kinetics of CO₂ reforming of methane by catalytically activated metallic foam absorber for solar receiver-reactors[J]. International Journal of Hydrogen Energy,2009,34(4):1787-1800.
[17] 桑丽霞,孙彪,李艳霞,等. 太阳能甲烷重整反应中的催化活性吸收体[J]. 化学进展,2011,23(11):2233-2239.
[18] 桑丽霞,王国瑞,孙彪,等. 太阳能甲烷重整中催化活性吸收体的表面特性[J]. 分子催化,2013,27(3):287-294.
[19] SANG L X,SUN B,TAN H Y,et al. Catalytic reforming of methane with CO₂ over metal foam based monolithic catalysts[J]. International Journal of Hydrogen Energy,2012,37(17):13037-13043.
[20] EBMANN C,MAIER L,LI A,et al. Natural gas steam reforming over rhodium/alumina catalysts:experimental and numerical study of the carbon deposition from ethylene and carbon monoxide[J]. Industrial & Engineering Chemistry Research,2014,53(31): 12270-12278.
[21] KODAMA T,KOYANAGI T,SHIMIZU T,et al. CO₂ reforming of methane in a molten carbonate salt bath for use in solar thermochemical processes[J]. Energy & Fuels,2001,15(1):60-65.
[22] GOKON N,OKU Y,KANEKO H,et al. Methane reforming with CO₂ in molten salt using FeO catalyst[J]. Solar Energy,2002,72 (3):243-250.
[23] BUCK R,MUIR J F,HOGAN R E. Carbon dioxide reforming of methane in a solar volumetric receiver/reactor:the CAESAR project[J]. Solar Energy Materials,1991,24(1):449-463.
[24] SKOCYPEC R D,HOGAN R E,MUIR J F. Solar reforming of methane in a direct absorption catalytic reactor on a parabolic dish:Ⅱmodeling and analysis[J]. Solar Energy,1994,52(6):479-490.
[25] WORNER A,TAMME R. CO₂ reforming of methane in a solar driven volumetric receiver–reactor[J]. Catalysis Today,1998,46(2): 165-174.
[26] BERMAN A,KARN R K,EPSTEIN M. A new catalyst system for high-temperature solar reforming of methane[J]. Energy & Fuels,2006,20(2):455-462.
[27] BERMAN A,KARN R K,EPSTEIN M. Steam reforming of methane on a Ru/Al₂O₃ catalyst promoted with Mn oxides for solar hydrogen production[J]. Green Chemistry,2007,9(6):626-631.
[28] RUBIN R,KARNI J. Carbon dioxide reforming of methane in directly irradiated solar reactor with porcupine absorber[J]. Journal of Solar Energy Engineering,2011,133(3):021008.
[29] 穆金霞,殷学锋. 微通道反应器在合成反应中的应用[J]. 化学进展,2008,20(1):60-75.
[30] YAO X,ZHANG Y,Du L,et al. Review of the applications of microreactors[J]. Renewable and Sustainable Energy Reviews,2015,47:519-539.
[31] DROST K,EILERS B,PETERSON D,et al. Detailed numerical modeling of a microchannel reactor for methane-steam reforming[C]// Proceedings of the ASME/JSME 2011 8th Thermal Engineering Joint Conference,Honolulu,Hawaii,March 13–17,2011. American Society of Mechanical Engineers,2011.
[32] DROST K,EILERS B,APTE S,et al. Design of a microchannel based solar receiver/reactor for methane-steam reforming[J]. International Journal of Micro-Nano Scale Transport,2012,3(1/2):53-68.
[33] GU X,TAYLOR R A,LI Q,et al. Thermal analysis of a micro solar thermal collector designed for methanol reforming[J]. Solar Energy,2015,113:189-198.
[34] CHEIN R Y,CHEN Y C,CHUNG J. Thermal resistance effect on methanol-steam reforming performance in micro-scale reformers[J]. International Journal of Hydrogen Energy,2012,37(1):250-262.
[35] CHEIN R Y,CHEN L C,CHEN Y C,et al. Heat transfer effects on the methanol-steam reforming with partially filled catalyst layers[J]. International Journal of Hydrogen Energy,2009,34(13):5398-5408.
[36] SUH J S,LEE M T,GREIF R,et al. Transport phenomena in a steam-methanol reforming microreactor with internal heating[J]. International Journal of Hydrogen Energy,2009,34(1):314-322.
[37] MEI D,QIAN M,LIU B,et al. A micro-reactor with micro-pin-fin arrays for hydrogen production via methanol steam reforming[J]. Journal of Power Sources,2012,205:367-376.
[38] MEI D,LIANG L,QIAN M,et al. A performance study of methanol steam reforming in an A-type microchannel reactor[J]. International Journal of Hydrogen Energy,2014,39(31):17690-17701.
[39] ZHOU W,TANG Y,WANG Q,et al. Optimization of catalyst loading for porous copper fiber sintered felts used in methanol steam reforming microreactors[J]. Chemical Engineering & Technology,2013,36(2):307-314.
[40] MOLLER S,KAUCIC D,SATTLER C. Hydrogen production by solar reforming of natural gas:a comparison study of two possible process configurations[J]. Journal of Solar Energy Engineering,2005,128(1):16-23.
[41] AGRAFIOTIS C,VON STORCH H,ROEB M,et al. Solar thermal reforming of methane feedstocks for hydrogen and syngas production:a review[J]. Renewable and Sustainable Energy Reviews,2014,29:656-682.
[42] DE FALCO M,PIEMONTE V. Solar enriched methane production by steam reforming process:reactor design[J]. International Journal of Hydrogen Energy,2011,36(13):7759-7762.
[43] ROLDAN M,SMIRNOVA O,FEND T,et al. Thermal analysis and design of a volumetric solar absorber depending on the porosity[J]. Renewable Energy,2014,62:116-128.
[44] WANG F,TAN J,MA L,et al. Effects of key factors on solar aided methane steam reforming in porous medium thermochemical reactor[J]. Energy Conversion and Management,2015,103:419-430.
[45] ZHENG R,DIVER R,CALDWELL D,et al. Integrated solar thermochemical reaction system for steam methane reforming[J]. Energy Procedia,2015,69:1192-1200.
[46] LU J,CHEN Y,DING J,et al. High temperature energy storage performances of methane reforming with carbon dioxide in a tubular packed reactor[J]. Applied Energy,2015,162:1473-1482.
[47] JIN H G,SUI J,HONG H,et al. Prototype of middle-temperature solar receiver/reactor with parabolic trough concentrator[J]. Journal of Solar Energy Engineering,2007,129(4):378-381.
[48] LIU Q,JIN H,HONG H,et al. Performance analysis of a mid‐and low‐temperature solar receiver/reactor for hydrogen production with methanol steam reforming[J]. International Journal of Energy Research,2011,35(1):52-60.
[49] HONG H,LIU Q,JIN H. Solar hydrogen production integrating low-grade solar thermal energy and methanol steam reforming[J]. Journal of Energy Resources Technology,2009,131 (1):012601.
[50] PETRASCH J,STEINFELD A. Dynamics of a solar thermochemical reactor for steam-reforming of methane[J]. Chemical Engineering Science,2007,62(16):4214-4228.