化工进展 ›› 2019, Vol. 38 ›› Issue (04): 1794-1803.DOI: 10.16085/j.issn.1000-6613.2018-1125
收稿日期:
2018-05-30
修回日期:
2018-10-01
出版日期:
2019-04-05
发布日期:
2019-04-05
通讯作者:
方莉
作者简介:
<named-content content-type="corresp-name">冯明</named-content>(1993—),男,硕士研究生,研究方向为煤基固废综合利用。E-mail:<email>863414516@qq.com</email>。|方莉,教授,博士生导师,研究方向为煤基固废综合利用。E-mail:<email>fangli@sxu.edu.cn</email>。
基金资助:
Ming FENG1,2(),Li FANG1,2(),Yanxia GUO2,Fangqin CHENG2
Received:
2018-05-30
Revised:
2018-10-01
Online:
2019-04-05
Published:
2019-04-05
Contact:
Li FANG
摘要:
离子印迹技术与电化学检测相结合制备的离子印迹电化学传感器(ion imprinted electrochemical sensor, IIES)可以有效检测水溶液中的痕量金属离子,因此在重金属和放射性元素的检测及贵金属回收等领域有着广泛的应用前景。基于此,本文以元素周期表中的过渡元素、主族元素、稀土/锕系元素等为IIES的分类标准,介绍了IIES的构建方法及其在不同金属离子检测中应用的最新研究进展,对不同方法构建的IIES的灵敏度、选择性、检测范围和稳定性等进行了评述,指出目前研究中存在制备方法不成熟、体系要求严苛等问题,提出现阶段IIES面临的挑战、可能的解决策略和未来发展趋势,尤其需加强在稀土金属及难印迹金属如锂等元素的IIES构建及应用、功能单体开发、交联剂筛选和制备技术等方面的研究。
中图分类号:
冯明, 方莉, 郭彦霞, 程芳琴. 金属离子印迹电化学传感器研究进展[J]. 化工进展, 2019, 38(04): 1794-1803.
Ming FENG, Li FANG, Yanxia GUO, Fangqin CHENG. A review of metal ion imprinted electrochemical sensors[J]. Chemical Industry and Engineering Progress, 2019, 38(04): 1794-1803.
1 | TSUKAGOSHI K , YU K Y , MAEDA M , et al . Metal ion-selective adsorbent prepared by surface-imprinting polymerization[J]. Bull. Chem. Soc. Jpn., 1993, 66(1): 114-120. |
2 | GARCIA R , PINEL C , MADIC C , et al . Ionic imprinting effect in gadolinium/lanthanum separation[J]. Tetrahedron Lett., 1998, 39(47): 8651-8654. |
3 | 朱彩艳, 马慧敏, 张强, 等 . 离子印迹聚合物功能单体的研究进展[J]. 化工进展, 2014, 33(11): 3013-3020. |
ZHU C Y , MA H M, ZHANG Q , et al . Recent advances in functional monomers in ion-imprinted polymer[J]. Chemical Industry and Engineering Progress, 2014, 33(11): 3013-3020. | |
4 | FASIHI J , ALAHYARI S A , SHAMSIPUR M , et al . Adsorption of uranyl ion onto an anthraquinone based ion-imprinted copolymer[J]. React. Funct. Polym., 2011, 71(8): 803-808. |
5 | FEHMI K , ORHAN G . Development and characterization of ion-imprinted sol-gel derived fluorescent film for selective recognition of mercury(Ⅱ) ion[J]. Sol-Gel. Sci. Technol., 2015, 76(2): 349-357. |
6 | 傅骏青, 王晓艳, 李金花, 等 . 重金属离子印迹技术[J]. 化学进展, 2016, 28(1): 83-90. |
FU J Q , WANG X Y , LI J H , et al . Ion imprinting technology for heavy metal ions[J]. Prog. Chem., 2016, 28(1): 83-90. | |
7 | 牟怀燕, 高云玲, 付坤, 等 . 离子印迹聚合物研究进展[J]. 化工进展, 2011, 30(11): 2467-2480. |
MU H Y , GAO Y L , FU K , et al . Progress in template-ion imprinted polymer[J]. Chemical Industry and Engineering Progress, 2011, 30(11): 2467-2480. | |
8 | BAI H , WANG S , LIU P , et al . An electrochemical sensor based on in situ polymerized ion-imprinted membranes at a graphene modified electrode for palladium determination[J]. J. Electroanal. Chem., 2016, 771(15): 29-36. |
9 | GUO X . Surface plasmon resonance based biosensor technique: a review[J]. J. Biophotonics., 2012, 5(7): 483-501. |
10 | GUNEY S , GUNEY O . A novel electrochemical sensor for selective determination of uranyl ion based on imprinted polymer sol-gel modified carbon paste electrode[J]. Sensor. Actuat. B: Chem., 2016, 231: 45-53. |
11 | HERNANDEZ-IBANEZ N , GARCIA-CRUZ L , MONTIEL V , et al . Electrochemical lactate biosensor based upon chitosan/carbon nanotubes modified screen-printed graphite electrodes for the determination of lactate in embryonic cell cultures[J]. Biosens. Bioelectron., 2015, 77(15): 1168-1174. |
12 | SEBASTIAN M , MATHEW B . Carbon nanotube based ion imprinted polymer as electrochemical sensor and sorbent for Zn(Ⅱ) ion from paint industry wastewater[J]. Int. J. Polym. Anal. Ch., 2017, 23(1): 18-28. |
13 | BAI H , XIONG C , WANG C , et al . Electrochemical sensor based on Rh(III) ion-imprinted polymer as a new modifying agent for rhodium determination[J]. J. Nanosci. Nanotechno. , 2018, 18(5): 3577-3584. |
14 | GHANEI-MOTLAGHA M , TAHERB M A . An electrochemical sensor based on novel ion imprinted polymeric nanoparticles for selective detection of lead ions[J]. Anal. Bioanal. Chem. Res., 2017, 4(2): 295-306. |
15 | DEHGANREYHAN S , NAJAFI M . Preparation of molecularly imprinted polymers-based electrochemical renewable ceramic electrode as a sensitive uranyl ions sensor[J]. Sensor. Lett., 2018, 16(1): 48-53. |
16 | 王春琼, 白慧萍, 熊彩云, 等 . 基于原位聚合的钯(Ⅱ)印迹传感器制备与应用[J]. 分析试验室, 2016, 35(10): 1125-1130. |
WANG C Q , BAI H P , XIONG C Y , et al . Preparation and application of palladium ion imprinted sensor based on in situ polymerization technique[J]. Chin. J. Anal. Lab. , 2016, 35(10): 1125-1130. | |
17 | BAI H , WANG C , ZHANG K , et al . A novel ion imprinted electrochemical sensor based on in-situ polymerization for detection of platinum[J]. RSC Adv., 2014, 4(103): 49-67. |
18 | FU X C , WU J , NIE L , et al . Electropolymerized surface ion imprinting films on a gold nanoparticles/single-wall carbon nanotube nanohybrids modified glassy carbon electrode for electrochemical detection of trace mercury(Ⅱ) in water[J]. Anal. Chim. Acta., 2012, 720(1): 29-37. |
19 | FU X C , CHEN X , GUO Z , et al . Stripping voltammetric detection of mercury (Ⅱ) based on a surface ion imprinting strategy in electropolymerized microporous poly(2-mercaptobenzothiazole) films modified glassy carbon electrode[J]. Anal. Chim. Acta., 2011, 685(1): 21-28. |
20 | SHAMSIPUR M , HASHEMI B , DEHDASHTIAN S , et al . Silver ion imprinted polymer nanobeads based on a AZA-thioether crown containing a 1,10-phenanthroline subunit for solid phase extraction and for voltammetric and potentiometric silver sensors[J]. Anal. Chim. Acta., 2014, 852(3): 223-235. |
21 | BEHNIA N , ASGARI M , FEIZBAKHSH A . Sub-nanomolar detection of zinc on the ion-imprinted polymer modified glassy carbon electrode[J]. J. Electroanal. Chem. , 2015, 3(1): 271-276. |
22 | 单益江, 武国凡, 卢小泉, 等 . 基于金纳米材料修饰的Cu2+印迹电化学传感器的研制[J]. 化学研究与应用, 2017, 29(6): 786-792. |
SHAN Y J , WU G F , LU X Q , et al . Studies on the copper ion imprinting sensors based on the gold nanomaterials[J]. Chem. Res. Appl., 2017, 29(6): 786-792. | |
23 | LUO X , HUANG W , SHI Q , et al . Electrochemical sensor based on lead ion-imprinted polymer particles for ultra-trace determination of lead ions in different real samples[J]. RSC Adv., 2017, 7(26): 16033-16040. |
24 | ASHKENANI H , TAHER M A . Determination of cadmium(Ⅱ) using carbon paste electrode modified with a Cd-ion imprinted polymer[J]. Microchim. Acta., 2012, 178(1/2): 53-60. |
25 | BOJDI M K , BEHBAHANI M , SAHRAGARD A , et al . A palladium imprinted polymer for highly selective and sensitive electrochemical determination of ultra-trace of palladium ions[J]. Electrochim. Acta., 2014, 149(10): 108-116. |
26 | KALATE BOJDI M , BEHBAHANI M , NAJAFI M , et al . Selective and sensitive determination of uranyl ions in complex matrices by ion imprinted polymers-based electrochemical sensor[J]. Electroanalysis, 2015, 27(10): 2458-2467. |
27 | RAJABI H R , ROUSHANI M , SHAMSIPUR M . Development of a highly selective voltammetric sensor for nanomolar detection of mercury ions using glassy carbon electrode modified with a novel ion imprinted polymeric nanobeads and multi-wall carbon nanotubes[J]. J. Electroanal. Chem. , 2013, 693(6): 16-22. |
28 | ALIZADEH T , HAMIDI N , GANJALI M R , et al . Determination of subnanomolar levels of mercury(Ⅱ) by using a graphite paste electrode modified with MWCNTs and Hg(Ⅱ)-imprinted polymer nanoparticles[J]. Microchim. Acta., 2018, 185(1): 16. |
29 | FU J , CHEN L , LI J , et al . Current status and challenges of ion imprinting[J]. J. Mater. Chem. A. , 2015, 3(26): 13598-13627. |
30 | 国家环境保护局, 国家技术监督局 . 污水综合排放标准: GB 8978—1996[S]. 北京: 中国标准出版社, 1996. |
National Environmental Protection Agency, The State Bureau of Technical Supervision . Integrated wastewater discharge standard: GB 8978—1996[S]. Beijing: Standards Press of China, 1996. | |
31 | WANG F , WEI X , WANG C , et al . Langmuir-blodgett film of p-tert-butylthiacalix[4]arene modified glassy carbon electrode as voltammetric sensor for the determination of Hg(II)[J]. Talanta, 2010, 80(3): 1198-1204. |
32 | CABELLO-CARRAMOLINO G , PETIT-DOMINGUEZ M D . Application of new sol-gel electrochemical sensors to the determination of trace mercury[J]. Anal. Chim. Acta., 2008, 614(1): 103-111. |
33 | UGO P, MORETTO L M , MAZZOCCHIN G A . Voltammetric determination of trace mercury in chloride media at glassy carbon electrodes modified with polycationic ionomers[J]. Anal. Chim. Acta., 1995, 305(1): 74-82. |
34 | AFKHAMI A , MADRAKIAN T , SOLTANI-SHAHRIVAR M , et al . Selective and sensitive electrochemical determination of trace amounts of mercury ion in some real samples using an ion imprinted polymer nano-modifier[J]. J. Electrochem Soc., 2016, 163(3): B68-B75. |
35 | DAVIDSON A . Ion imprinted polymer based potentiometric sensor for the trace determination of cadmium(Ⅱ) ions[J]. Arab. J. Chem., 2017, 10(1): S864-S869. |
36 | DAHAGHIN Z , KILMARTIN P A , MOUSAVI H Z . Determination of cadmium(Ⅱ) using a glassy carbon electrode modified with a Cd-ion imprinted polymer[J]. J. Electroanal Chem., 2018, 810(1): 185-190. |
37 | ALIZADEH T , GANJALI M R , NOUROZI P , et al . A carbon paste electrode impregnated with Cd2+ imprinted polymer as a new and high selective electrochemical sensor for determination of ultra-trace Cd2+ in water samples[J]. J. Electroanal Chem., 2011, 657(1/2): 98-106. |
38 | ABU-DALO M A , SALAM A A , NASSORY N S . Ion imprinted polymer based electrochemical sensor for environmental monitoring of copper(II)[J]. Int. J. Electroanal Sci. , 2015, 10(8): 6780-6793. |
39 | LIANG R , ZHANG R , SONG W , et al . Potentiometric sensor based on an ion-imprinted polymer for determination of copper[J]. Sensor. Lett., 2011, 9(2): 557-562. |
40 | 王晶, 张朝晖, 闫亮, 等 . 基于石墨烯修饰碳电极的铜离子印迹电化学传感器的制备与应用[J]. 化学通报, 2017, 80(4): 367-372. |
WANG J , ZHANG Z H , YAN L , et al . Preparation and application of copper ion imprinted electrochemical sensor based on graphene modified carbon electrode[J]. Chem. Bull., 2017, 80(4): 367-372. | |
41 | 徐丽娟, 李锦书, 卢小泉, 等 . 分子印迹铜离子伏安传感器的研制与应用[J]. 化学研究与应用, 2013, 25(10): 1351-1356. |
XU L J , LI J S , LU X Q , et al . Preparation and application of the copper ion voltametric sensors based on molecularly imprinting technology[J]. Chem. Res. Appl., 2013, 25(10): 1351-1356. | |
42 | ZHIANI R , GHANEI-MOTLAG M , RAZAVIPANAH I . Selective voltammetric sensor for nanomolar detection of silver ions using carbon paste electrode modified with novel nanosized Ag(I)-imprinted polymer[J]. J. Mol. Liq., 2016, 219: 554-560. |
43 | TORKASHVAND M , GHOLIVAND M B , AZIZI R . Synthesis, characterization and application of a novel ion-imprinted polymer based voltammetric sensor for selective extraction and trace determination of cobalt(II) ions[J]. Sensor. Actuat. B: Chem., 2017, 243: 283-291. |
44 | BEHNIA N , ASGARI M , FEIZBAKHSH A . Sub-nanomolar detection of zinc on the ion-imprinted polymer modified glassy carbon electrode[J]. J. Environ. Chem. Eng. ., 2015, 3(1): 271-276. |
45 | ROUSHANI M , SAEDI Z , HAMDI F , et al . Preparation an electrochemical sensor for detection of manganese(Ⅱ) ions using glassy carbon electrode modified with multi walled carbon nanotube-chitosan-ionic liquid nanocomposite decorated with ion imprinted polymer[J]. J. Electroanal. Chem. , 2017, 804(1): 1-6. |
46 | WU S , DAI X , CHENG T , et al . Highly sensitive and selective ion-imprinted polymers based on one-step electrodeposition of chitosan-graphene nanocomposites for the determination of Cr(Ⅵ)[J]. Carbohyd. Polym., 2018, 195(1): 199-206. |
47 | ALIZADEH T , AMJADI S . Preparation of nano-sized Pb2+ imprinted polymer and its application as the chemical interface of an electrochemical sensor for toxic lead determination in different real samples[J]. J. Hazard. Mater. , 2011, 190(1/3): 451-459. |
48 | HU S , XIONG X , HUANG S , et al . Preparation of Pb(II) ion imprinted polymer and its application as the interface of an electrochemical sensor for trace lead determination[J]. Anal. Sci. Int. J. Jpn. Soc. Anal. Chem., 2016, 32(9): 975-980. |
49 | BOJDI M K , MASHHADIZADEH M H , BEHBAHANI M , et al . Synthesis, characterization and application of novel lead imprinted polymer nanoparticles as a high selective electrochemical sensor for ultra-trace determination of lead ions in complex matrixes[J]. Electrochim. Acta., 2014, 136(8): 59-65. |
50 | FAYAZI M , GHANEI-MOTLAGH M , TAHER M A , et al . Synthesis and application of a novel nanostructured ion-imprinted polymer for the preconcentration and determination of thallium(I) ions in water samples[J]. J. Hazard. Mater., 2016, 309(15): 27-36. |
51 | CHANG K L , LIAO W T , YU C L , et al . Effects of gallium on immune stimulation and apoptosis induction in human peripheral blood mononuclear cells[J]. Toxicol. Appl. Pharmacol., 2003, 193(2): 209-217. |
52 | ALIZADEH T , HAMIDI N , GANJALI M R , et al . Development of a highly selective and sensitive electrochemical sensor for Bi3+ determination based on nano-structured bismuth-imprinted polymer modified carbon/carbon nanotube paste electrode[J]. Sensor. Actuat. B-Chem., 2017, 245: 605-614. |
53 | MOJTABA N M , MOHAMMAD T , HAMID F . Synthesis and application of nano-sized ionic imprinted polymer for the selective voltammetric determination of thallium[J]. Talanta, 2015, 144(1): 204-209. |
54 | HU Y , ZHANG Z , ZHANG H , et al . Electrochemical sensor for sensitive determination of Ga(Ⅲ) ion based on β-cyclodextrin incorporated multi-walled carbon nanotubes and imprinted sol-gel composite film[J]. Chin. J. Chem. , 2012, 30(2): 377-385. |
55 | ALIZADEH T , SHAMKHALI A N , HANIFEHPOUR Y , et al . A Ca2+ selective membrane electrode based on calcium-imprinted polymeric nanoparticles[J]. New J. Chem., 2016, 40(10): 8479-8487. |
56 | 顾保江, 龙志奇, 黄小卫, 等 . 我国稀土化合物产业现状和展望[J]. 稀有金属, 2003, 27(3): 391-394. |
GU B J , LONG Z Q , HUANG X W , et al . Present status and prospect of RE compound industry in China[J]. Rare Metals, 2003, 27(3): 391-394. | |
57 | PRASAD B B , JAUHARI D . Double-ion imprinted polymer@magnetic nanoparticles modified screen printed carbon electrode for simultaneous analysis of cerium and gadolinium ions[J]. Anal. Chim. Acta., 2015, 875(22): 83-91. |
58 | TAN L V , LE N T N . Spectrophotometric determination of cerium using azocalixarene derivative in geological samples[J]. Int. J. Chem. Eng. Appl. , 2011, 2(6): 381-384. |
59 | CHEN J , BAI H , LI Z , et al . Stripping voltammetric determination of cerium in food using an electropolymerized poly-catechol and ion-imprinted membrane modified electrode[J]. J. Electroanal Chem., 2017, 808(1): 41-49. |
60 | ABU-DALO M A , AL-RAWASHDEH N A F , AL-MHEIDAT I R , et al . Preparation and evaluation of new uranyl imprinted polymer electrode sensor for uranyl ion based on uranyl-carboxybezotriazole complex in PVC matrix membrane[J]. Sensor Actuat. B-Chem., 2016, 227: 336-345. |
[1] | 张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286. |
[2] | 胡喜, 王明珊, 李恩智, 黄思鸣, 陈俊臣, 郭秉淑, 于博, 马志远, 李星. 二硫化钨复合材料制备与储钠性能研究进展[J]. 化工进展, 2023, 42(S1): 344-355. |
[3] | 张杰, 白忠波, 冯宝鑫, 彭肖林, 任伟伟, 张菁丽, 刘二勇. PEG及其复合添加剂对电解铜箔后处理的影响[J]. 化工进展, 2023, 42(S1): 374-381. |
[4] | 许春树, 姚庆达, 梁永贤, 周华龙. 共价有机框架材料功能化策略及其对Hg(Ⅱ)和Cr(Ⅵ)的吸附性能研究进展[J]. 化工进展, 2023, 42(S1): 461-478. |
[5] | 王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497. |
[6] | 李化全, 王明华, 邱贵宝. 硫酸酸解钙钛矿相精矿的行为[J]. 化工进展, 2023, 42(S1): 536-541. |
[7] | 邓丽萍, 时好雨, 刘霄龙, 陈瑶姬, 严晶颖. 非贵金属改性钒钛基催化剂NH3-SCR脱硝协同控制VOCs[J]. 化工进展, 2023, 42(S1): 542-548. |
[8] | 王晋刚, 张剑波, 唐雪娇, 刘金鹏, 鞠美庭. 机动车尾气脱硝催化剂Cu-SSZ-13的改性研究进展[J]. 化工进展, 2023, 42(9): 4636-4648. |
[9] | 林晓鹏, 肖友华, 管奕琛, 鲁晓东, 宗文杰, 傅深渊. 离子聚合物-金属复合材料(IPMC)柔性电极的研究进展[J]. 化工进展, 2023, 42(9): 4770-4782. |
[10] | 雷伟, 姜维佳, 王玉高, 和明豪, 申峻. N、S共掺杂煤基碳量子点的电化学氧化法制备及用于Fe3+检测[J]. 化工进展, 2023, 42(9): 4799-4807. |
[11] | 朱传强, 茹晋波, 孙亭亭, 谢兴旺, 李长明, 高士秋. 固体高分子脱硝剂选择性非催化还原NO x 特性[J]. 化工进展, 2023, 42(9): 4939-4946. |
[12] | 李伯耿, 罗英武, 刘平伟. 聚合物产品工程研究内容与方法的思考[J]. 化工进展, 2023, 42(8): 3905-3909. |
[13] | 毛善俊, 王哲, 王勇. 基团辨识加氢:从概念到应用[J]. 化工进展, 2023, 42(8): 3917-3922. |
[14] | 王报英, 王皝莹, 闫军营, 汪耀明, 徐铜文. 聚合物包覆膜在金属分离回收中的研究进展[J]. 化工进展, 2023, 42(8): 3990-4004. |
[15] | 向阳, 黄寻, 魏子栋. 电催化有机合成反应的活性和选择性调控研究进展[J]. 化工进展, 2023, 42(8): 4005-4014. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 版权所有 © 《化工进展》编辑部 地址:北京市东城区青年湖南街13号 邮编:100011 电子信箱:hgjz@cip.com.cn 本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn |