化工进展 ›› 2024, Vol. 43 ›› Issue (7): 3955-3963.DOI: 10.16085/j.issn.1000-6613.2023-0924
• 材料科学与技术 • 上一篇
收稿日期:
2023-06-05
修回日期:
2023-07-30
出版日期:
2024-07-10
发布日期:
2024-08-14
通讯作者:
徐阳
作者简介:
周锐(1999—),男,硕士研究生,研究方向为功能纺织材料、防护纺织品。E-mail:6213011113@stu.jiangnan.edu.cn。
基金资助:
ZHOU Rui(), YU Kejing, XU Yang()
Received:
2023-06-05
Revised:
2023-07-30
Online:
2024-07-10
Published:
2024-08-14
Contact:
XU Yang
摘要:
为提高碳纤维(CF)的屏蔽性能和实现宽频化应用,本文通过化学镀方法分别在CF表面沉积Ni、FeNi金属层,制备了碳纤维杂化材料(CF@Ni、CF@FeNi)。其次以水性聚氨酯(WPU)为基体,依次以CF、CF@Ni和CF@FeNi为填料,制备了轻质、柔性的复合材料。同时测试了复合材料在30~3000MHz的电磁屏蔽性能和10~100kHz的磁屏蔽性能。结果表明,成功地在碳纤维表面镀覆了一层致密、均匀的金属层,其中CF@FeNi的饱和磁化强度(Ms)、剩余磁化强度(Br)和矫顽力(Hc)分别达到了10.02emu/g、0.76emu/g和26.06Oe。金属镀层改善了碳纤维的电磁屏蔽性能,并有效提高了其在低频段的磁屏蔽性能。当添加量为9%时,WPU@CF@FeNi在30~3000MHz与10~100kHz的屏蔽效能峰值分别达到26.9dB和18.0dB。
中图分类号:
周锐, 俞科静, 徐阳. 化学镀铁镍碳纤维制备及其电磁屏蔽性能[J]. 化工进展, 2024, 43(7): 3955-3963.
ZHOU Rui, YU Kejing, XU Yang. Preparation and electromagnetic interference shielding properties of electroless iron-nickel plated carbon fiber[J]. Chemical Industry and Engineering Progress, 2024, 43(7): 3955-3963.
镀液成分 | 浓度/g·L-1 | 镀液成分 | 浓度/g·L-1 | |
---|---|---|---|---|
次亚磷酸钠 | 40 | 硫酸铵 | 49 | |
硫酸镍 | 30 | 15 | 酒石酸钾钠 | 60 |
硫酸亚铁铵 | 0 | 15 | 碳纤维 | 1 |
表1 化学镀液成分及浓度
镀液成分 | 浓度/g·L-1 | 镀液成分 | 浓度/g·L-1 | |
---|---|---|---|---|
次亚磷酸钠 | 40 | 硫酸铵 | 49 | |
硫酸镍 | 30 | 15 | 酒石酸钾钠 | 60 |
硫酸亚铁铵 | 0 | 15 | 碳纤维 | 1 |
元素 | 质量分数/% | 原子分数/% |
---|---|---|
C | 16.0 | 42.8 |
O | 3.3 | 6.7 |
P | 12.7 | 13.2 |
Ni | 68.0 | 37.3 |
表2 CF@Ni的元素百分含量
元素 | 质量分数/% | 原子分数/% |
---|---|---|
C | 16.0 | 42.8 |
O | 3.3 | 6.7 |
P | 12.7 | 13.2 |
Ni | 68.0 | 37.3 |
元素 | 质量分数/% | 原子分数/% |
---|---|---|
C | 14.8 | 37.8 |
O | 8.5 | 16.3 |
P | 12.6 | 12.4 |
Fe | 6.3 | 3.4 |
Ni | 57.8 | 30.1 |
表3 CF@FeNi元素百分含量
元素 | 质量分数/% | 原子分数/% |
---|---|---|
C | 14.8 | 37.8 |
O | 8.5 | 16.3 |
P | 12.6 | 12.4 |
Fe | 6.3 | 3.4 |
Ni | 57.8 | 30.1 |
样品 | 饱和磁化强度 Ms/emu·g-1 | 剩余磁化强度Br /emu·g-1 | 矫顽力 Hc/Oe |
---|---|---|---|
CF@Ni | 8.40 | 0.56 | 60.22 |
CF@FeNi | 10.02 | 0.76 | 26.06 |
表4 CF@Ni、CF@FeNi的磁性能参数
样品 | 饱和磁化强度 Ms/emu·g-1 | 剩余磁化强度Br /emu·g-1 | 矫顽力 Hc/Oe |
---|---|---|---|
CF@Ni | 8.40 | 0.56 | 60.22 |
CF@FeNi | 10.02 | 0.76 | 26.06 |
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