光子晶体结构色纺织材料的制备及应用研究进展

doi:10.16085/j.issn.1000-6613.2021-1959

摘要/Abstract

摘要：

为解决当前纺织印染行业大量使用高污染、高能耗且易褪色的传统化学染料和颜料的问题，针对结构生色材料所具有的不含着色剂、颜色鲜艳、不易褪色等特点，本文综述了近年来光子晶体结构色纺织材料的制备及应用研究进展。介绍了光子晶体结构及其结构生色机理，阐述了结构色纺织材料常用的制备方法，着重归纳了光子晶体结构色在纤维、纱线、织物及颜料等方面的应用，并分析了其在应用过程中存在的问题。分析表明，光子晶体结构色纺织材料已经可以达到大面积快速制备，且在织物上构筑结构色较为方便且研究较多，在纱线上构筑结构色的研究较少，在纤维上构筑结构色容易赋予其功能性且相关研究逐渐增多。最后总结了光子晶体结构色应用于纺织领域所存在的问题，并对该研究方向进行了展望。

关键词: 光子晶体, 结构色, 纺织材料, 纤维, 纱线, 织物, 颜料

Abstract:

In order to solve the problem that traditional chemical dyes and pigments with high pollution, high energy consumption and easy fading are widely used in textile printing and dyeing industry, the research progress in preparation and application of textile materials with photonic crystal structural colors in recent years was reviewed according to the characteristics of structural colors materials such as colorant free, bright color and not easy to fade. This paper introduced the structure of photonic crystal and its color generating mechanism, expounded the common preparation methods of textile materials with structural color, summarized the application of photonic crystal structural color in fiber, yarn, fabric and pigment, and analyzed the problems existing in the application process. The analysis showed that photonic crystal structural colors textile materials can achieve rapid preparation with large area. Constructing structural colors on fabrics was more convenient with more researches, while there were fewer studies on constructing structural colors on yarns. Constructing structural colors on fibers was easy to give them functionality and related research was gradually increasing. Finally, the problems in the application of photonic crystal structural colors to the textile field were summarized and the research direction was prospected.

Key words: photonic crystal, structural colors, textile material, fiber, yarn, fabric, pigment

中图分类号:

O734

陈欢欢, 高伟洪, 陈凯凯, 张之悦, 赵小燕. 光子晶体结构色纺织材料的制备及应用研究进展[J]. 化工进展, 2022, 41(8): 4327-4340.

CHEN Huanhuan, GAO Weihong, CHEN Kaikai, ZHANG Zhiyue, ZHAO Xiaoyan. Research progress on the fabrication and application of textile materials with photonic crystal structural colors[J]. Chemical Industry and Engineering Progress, 2022, 41(8): 4327-4340.

图/表 15

参考文献 77

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制备方法	优点	缺点
垂直沉积法^{［31，34］}	织物结构色均匀、饱和度高、可实现双面着色，制备工艺简单可控	垂直方向上厚度易不均匀，对胶体颗粒的尺寸、基材、温湿度等外部条件要求较高
重力沉降法^［35-37］	制备工艺简单、对设备要求低	效率低，无法大面积着色，对胶体颗粒尺寸要求严格
电泳沉积法^［30］	周期短、晶体结构可控、操作简便，可用于模拟传统的纤维染色工艺	对设备的要求较高且基材必须导电
喷墨打印法^{［11，40-42］}	不受基布组织结构的影响，可以大规模制备结构色图案	图案边缘会出现“咖啡环”效应，图案的颜色不均匀、容易出现裂纹
胶体静电纺丝法^［44-45］	便捷、精准，可制备颜色均匀的光子晶体结构色膜	工艺参数复杂，且无法大规模制备
静电自组装法^［46-47］	可在分子水平控制多功能性光子晶体膜层的厚度，应用范围广，高效，可控性强	实验条件十分苛刻
磁控溅射法^{［33，48］}	操作方便、环境友好、对织物的适应性强，适合大规模生产	在空间受限精密设备中制备，无法连续化制备，不能大规模生产
丝网印刷法^［50-51］	易于操作、快速制备较厚的涂层、大面积制备结构色图案	无显著缺点
剪切诱导自组装法^［52］	易于操作、大面积制备结构色纺织品	无显著缺点

制备方法	优点	缺点
垂直沉积法^{［31，34］}	织物结构色均匀、饱和度高、可实现双面着色，制备工艺简单可控	垂直方向上厚度易不均匀，对胶体颗粒的尺寸、基材、温湿度等外部条件要求较高
重力沉降法^［35-37］	制备工艺简单、对设备要求低	效率低，无法大面积着色，对胶体颗粒尺寸要求严格
电泳沉积法^［30］	周期短、晶体结构可控、操作简便，可用于模拟传统的纤维染色工艺	对设备的要求较高且基材必须导电
喷墨打印法^{［11，40-42］}	不受基布组织结构的影响，可以大规模制备结构色图案	图案边缘会出现“咖啡环”效应，图案的颜色不均匀、容易出现裂纹
胶体静电纺丝法^［44-45］	便捷、精准，可制备颜色均匀的光子晶体结构色膜	工艺参数复杂，且无法大规模制备
静电自组装法^［46-47］	可在分子水平控制多功能性光子晶体膜层的厚度，应用范围广，高效，可控性强	实验条件十分苛刻
磁控溅射法^{［33，48］}	操作方便、环境友好、对织物的适应性强，适合大规模生产	在空间受限精密设备中制备，无法连续化制备，不能大规模生产
丝网印刷法^［50-51］	易于操作、快速制备较厚的涂层、大面积制备结构色图案	无显著缺点
剪切诱导自组装法^［52］	易于操作、大面积制备结构色纺织品	无显著缺点

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