锡酸锌纳米材料的制备方法及应用研究进展

doi:10.16085/j.issn.1000-6613.2021-1595

摘要/Abstract

摘要：

锡酸锌由于具有较高的电子迁移率、稳定性、高电导率，优异的吸附性能、光学性能和阻燃抑烟性能等特性，近年来逐渐受到科研人员的关注。本文介绍了锡酸锌纳米颗粒的制备方法（水热法、化学沉淀法、固相化学合成法、微波合成法、溶胶-凝胶法、模板法等）、形貌结构（颗粒状、立方体、球形、八面体、纳米棒、片状、纳米花状等）、粒径及其在不同领域（锂电负极材料、气敏材料、电触头材料、DSSC阳极、光催化、阻燃等）的应用研究进展，分析了利用不同锡化合物原料、不同方法制备锡酸锌纳米颗粒的原理、制备条件和产品特性，指出了每种制备方法的优缺点及每种制备方法中不同结构的形成机理，以及不同结构是如何对Zn₂SnO₄相关性能产生影响的。文章指出如何高效可控制备特定形貌和晶粒尺寸的锡酸锌是锡酸锌纳米材料未来的发展方向。

关键词: 锡酸锌, 纳米材料, 制备方法, 应用, 形貌结构

Abstract:

Zinc stannate has gradually attracted the attention of scientific researchers in recent years due to its high electron mobility, stability, high electrical conductivity, excellent adsorption properties, optical properties, and flame and smoke suppression properties. This paper presentes the research progress on the preparation methods of zinc stannate nanoparticles (hydrothermal, chemical precipitation, solid-phase chemical synthesis, microwave synthesis, sol-gel method, template method, etc.), morphology and structure (granular, cubic, spherical, octahedral, nano-rod, flake, nano-flower, etc.), particle sizes and their applications in different fields (lithium battery anode materials, gas-sensitive materials, electrical contact materials, DSSC anodes, photocatalysis, flame retardant, etc.). The principles, preparation conditions and product properties of Zn₂SnO₄ nanoparticles using different tin compounds and different methods are analyzed, and the advantages and disadvantages of each preparation method and the formation mechanism of different structures in each preparation method are pointed out, as well as how the different structures affected the relevant properties of Zn₂SnO₄. The article indicates that how efficient and controllable preparation of zinc stannate with specific morphology and grain size is a future direction for zinc stannate nanomaterials.

Key words: zinc stannate, nanomaterial, preparation method, application, topography

中图分类号:

TQ115

马殿普, 李俊, 覃德清, 袁英杰, 潘飞, 符泽卫. 锡酸锌纳米材料的制备方法及应用研究进展[J]. 化工进展, 2022, 41(6): 3113-3126.

MA Dianpu, LI Jun, QIN Deqing, YUAN Yingjie, PAN Fei, FU Zewei. Research progress on the preparation method and application of zinc stannate nanomaterials[J]. Chemical Industry and Engineering Progress, 2022, 41(6): 3113-3126.

图/表 18

图1 水热法制备的正八面体Zn2SnO4的扫描电镜（SEM）图

图2 NaOH添加量与Zn2SnO4结构关系的SEM图

图3 水热法制备的 Zn2SnO4空心球的透射电镜（TEM）图

图4 沉淀法制备的Zn2SnO4空心球的SEM图

图5 固相法制备的立方体形Zn2SnO4粉体的TEM图

图6 微波法合成的纳米棒状Zn2SnO4的SEM图

图7 采用微波法，在不同锌/锡比下合成的Zn2SnO4的形貌及X射线衍射（XRD）图

图8 高温燃烧合成-喷射法制备的Zn2SnO4微纳米颗粒

图9 碳热还原热蒸发法制备的秧苗状Zn2SnO4纳米线

图10 Zn2SnO4/C电接触材料Li存储容量和循环寿命

表1 Zn2SnO4对不同气体的气敏性能

形貌	气体	工作温度/℃	气体浓度/10^-6	灵敏度	响应恢复时间/s	检测限/10^-6	文献
空心八面体	H₂S	260	50	46.0	—	1	［38］
纳米立方体	正丁胺	350	400	102.2	—	30	［39］
纳米薄膜	NO₂	200	200	2.66	25/326（200×10^-6）	50	［40］
纳米花状	LPG	室温	5000	2.5	180/240（5000×10^-6）	—	［41］
齿状纳米线	乙醇	—	200	27	7/8	1	［42］
纳米粒子	乙醇	180	100	46.5	—	5	［43］
纳米球	乙醇	180	50	23.4	—	5	［44］
八面体	TEA	200	100	37	2/17（100×10^-6）	5	［45］
空心立方体	丙酮	260	200	141.7	—	10	［46］
空心球	丙酮	200	200	153	7/9（200×10^-6）	20	［47］

图11 Zn2SnO4空心八面体结构传感器对不同种类气体的灵敏度选择性图及对不同浓度H2S的响应图

图12 Zn2SnO4立方体与不规则结构传感器对不同气体的灵敏度图

表2 不同增强相制得的Ag基电接触材料性能对比

材料

电阻率

/μΩ·cm^-1

硬度HV

/MPa

理论密度

/g·cm^-3

相对密度

Ag/SnO₂

Ag/Zn₂SnO₄

图13 Zn2SnO4表面处理工艺及反应机理

图14 CNTs增强Zn2SnO4光催化活性机理

图15 Zn2SnO4-C3N4降解RhB和PNP的机理图

表3 Zn2SnO4对软质 PVC阻燃消烟性能的影响

阻燃剂添加量 /份	极限氧指数 /%	烟密度等级 /%	最大烟密度等级 /%	残炭率 /%
0	28.7	90.5	100.0	20.8
5	33.1	88.3	95.7	23.4
10	34.9	85.8	93.7	26.7
15	36.0	86.2	93.2	29.7
20	36.4	86.4	94.5	29.4

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