沥青基钠离子电池负极材料研究进展

doi:10.16085/j.issn.1000-6613.2025-0469

摘要/Abstract

摘要：

钠离子电池（sodium-ion battery，SIB）因钠资源丰富、成本低廉，在大规模储能领域展现出广阔应用前景，但其负极材料性能制约了整体发展。沥青作为碳基负极前体，具有原料成本低、碳收率高、结构可调等优势，成为当前研究热点。本文系统综述了沥青基SIB负极材料的优化策略与前沿进展，重点分析了沥青分子改性、孔隙结构设计、杂原子掺杂及电极-电解液界面调控等关键技术。研究表明，通过分子交联-闭孔构筑-界面工程的跨尺度协同，可同步提升可逆容量和首次库仑效率。然而，当前研究仍面临沥青组分波动性大、传统改性工艺污染严重、闭孔储钠机制存在争议以及全电池匹配性缺失等挑战。未来研究需要聚焦绿色制备工艺开发，探索沥青分子精准调控新方法，结合机器学习构建“结构-性能”预测模型，并深化多尺度界面调控机制研究。同时，急需推动沥青基SIB负极的规模化制备与全电池集成验证，解决电极压实密度、电解液浸润性等工程化问题，为实现高性能、低成本SIB储能系统提供关键技术支撑。

关键词: 沥青, 钠离子电池, 负极, 碳材料, 改性

Abstract:

Sodium-ion battery (SIB) hold great promise for large-scale energy storage applications, primarily attributed to the abundant availability of sodium resources and their relatively low cost. Nevertheless, the performance of anode materials in SIB has emerged as a significant bottleneck, impeding their widespread development. Pitch, as a carbon-based precursor for anode materials, offers several notable advantages, including low raw material costs, high carbon yields and the ability to tailor its structure. These characteristics have propelled pitch to the forefront of current research endeavors. This review comprehensively examined the optimization strategies and recent advancements in pitch-based SIB anode materials. Particular emphasis was placed on key techniques such as the modification of pitch molecules, the design of pore structures, the incorporation of heteroatoms and the regulation of the electrode-electrolyte interface. Findings suggested that through the coordinated efforts of molecular crosslinking, closed-pore formation and interface engineering across multiple scales, it was possible to simultaneously enhance the reversible capacity and initial coulombic efficiency of SIB. However, the current research landscape was not without its challenges. These included the significant variability in pitch composition, the high environmental impact of traditional modification processes, ongoing debates regarding the sodium storage mechanism within closed pores and the lack of compatibility in full-cell configurations. Looking ahead, future research should prioritize the development of environmentally friendly preparation methods, the exploration of novel approaches for precisely controlling pitch molecules, the establishment of "structure-performance" predictive models through machine learning and the in-depth investigation of multi-scale interface regulation mechanisms. Simultaneously, there was an urgent need to facilitate the large-scale production of pitch-based SIB anodes and validate their integration in full-cell systems. Addressing engineering challenges such as electrode compaction density and electrolyte wettability would be crucial in providing the necessary technical underpinnings for the realization of high-performance and cost-effective SIB energy storage systems.

Key words: pitch, sodium-ion battery, anode, carbon material, modification

中图分类号:

TQ152

杜亮亮, 邵杰, 汪超, 宋俊达, 程尧, 开元, 胡超. 沥青基钠离子电池负极材料研究进展[J]. 化工进展, 2025, 44(S1): 307-322.

DU Liangliang, SHAO Jie, WANG Chao, SONG Junda, CHENG Yao, KAI Yuan, HU Chao. Research progress on pitch-based anode materials for sodium-ion batteries[J]. Chemical Industry and Engineering Progress, 2025, 44(S1): 307-322.

图/表 8

图1 钠离子电池负极材料的发展概况

图2 沥青基钠离子电池优化方向

图3 沥青结构模型及热解机理示意图

图4 沥青不同组分预氧化的反应途径[30]

图5 氧化改性策略对沥青基碳负极结构和性能的影响

图6 碳正离子引入及卤化策略对沥青基碳负极结构和性能的影响（1Å=0.1nm）

图7 孔结构优化和表面包覆提升沥青基碳负极的储钠性能

图8 界面调控与优化提升沥青基碳负极的储钠性能

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