“木质素优先”还原催化分馏工艺与模拟研究进展

doi:10.16085/j.issn.1000-6613.2024-1855

化工进展 ›› 2025, Vol. 44 ›› Issue (5): 2683-2693.DOI: 10.16085/j.issn.1000-6613.2024-1855

• 可再生能源利用 • 上一篇

“木质素优先”还原催化分馏工艺与模拟研究进展

艾佳臻¹(), 张振磊¹(), 詹国雄², 马龙巍¹, 史国靖¹, 尹海川¹, 张香平¹^,²()

^1.中国石油大学(北京)，重质油全国重点实验室，北京 102249
^2.中国科学院过程工程研究所，离子液体清洁过程北京市重点实验室，北京 100190

收稿日期:2024-11-12 修回日期:2025-04-02 出版日期:2025-05-25 发布日期:2025-05-20
通讯作者: 张振磊,张香平
作者简介:艾佳臻（1994—），女，博士研究生，研究方向为绿色系统集成。E-mail：2023310255@student.cup.edu.cn。
基金资助:
国家自然科学基金(22408397);中央高校基本科研业务费专项资金(2462024BJRC001)

Advances in "lignin-first" reductive catalytic fractionation process and simulation

AI Jiazhen¹(), ZHANG Zhenlei¹(), ZHAN Guoxiong², MA Longwei¹, SHI Guojing¹, YIN Haichuan¹, ZHANG Xiangping¹^,²()

^1.State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249, China
^2.Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2024-11-12 Revised:2025-04-02 Online:2025-05-25 Published:2025-05-20
Contact: ZHANG Zhenlei, ZHANG Xiangping

摘要/Abstract

摘要：

“木质素优先”策略通过优先提取木质素并将其原位转化为高附加值化学品，为生物精炼技术的发展开辟了新路径。本文聚焦还原催化分馏（RCF）工艺的研究进展与工业化挑战，重点分析了原料结构、催化体系及溶剂特性对木质素解聚效率与产物选择性的影响规律。结合过程模拟、技术经济分析（TEA）与生命周期评估（LCA），量化揭示了溶剂循环优化、多因素协同调控等策略对工艺经济性与环境效益的影响。未来研究需突破下游转化模拟研究不足、评价体系单一等局限，开发多原料适配的智能工艺模型，构建机器学习与多目标优化工具；深化不同“木质素优先”工艺的系统对比与协同设计；推动木质素油向航空燃料、生物质基材料等高附加值产品转化，助力生物质资源的高值化利用。

关键词: 还原催化分馏, 过程系统, 模拟, 木质素优先, 生物精炼, 生物质

Abstract:

The "lignin-first" strategy, which prioritizes the extraction of lignin and its in-situ conversion into high-value-added chemicals, paves a new pathway for the advancement of biorefinery technologies. This paper focuses on the research progress and industrialization challenges of the reductive catalytic fractionation (RCF) process, with a key analysis of the influence mechanisms of feedstock structure, catalytic systems, and solvent properties on lignin depolymerization efficiency and product selectivity. Combining process simulation, techno-economic analysis (TEA), and life cycle assessment (LCA), this study quantifies the impacts of solvent recycling optimization and multi-factor synergetic regulation strategies on process economics and environmental benefits. Future research needs to overcome limitations such as insufficient downstream conversion simulation and single-dimensional evaluation systems. It should develop intelligent process models adaptable to multiple feedstocks, construct machine learning and multi-objective optimization tools, deepen systematic comparisons and collaborative designs among different "lignin-first" processes, and promote the conversion of lignin oil into high-value products such as sustainable aviation fuels and bio-based materials to achieve the valorization of biomass.

Key words: reductive catalytic fractionation, process systems, simulation, lignin-first, biorefining, biomass

中图分类号:

艾佳臻, 张振磊, 詹国雄, 马龙巍, 史国靖, 尹海川, 张香平. “木质素优先”还原催化分馏工艺与模拟研究进展[J]. 化工进展, 2025, 44(5): 2683-2693.

AI Jiazhen, ZHANG Zhenlei, ZHAN Guoxiong, MA Longwei, SHI Guojing, YIN Haichuan, ZHANG Xiangping. Advances in "lignin-first" reductive catalytic fractionation process and simulation[J]. Chemical Industry and Engineering Progress, 2025, 44(5): 2683-2693.

图/表 6

参考文献 70

1	ZHOU Min, Meiqi LYU, CAI Sulin, et al. Effects of enzymatic hydrolysis and physicochemical properties of lignocellulose waste through different choline based deep eutectic solvents (DESs) pretreatment[J]. Industrial Crops and Products, 2023, 195: 116435.
2	ZHOU Min, TIAN Xingjun. Development of different pretreatments and related technologies for efficient biomass conversion of lignocellulose[J]. International Journal of Biological Macromolecules, 2022, 202: 256-268.
3	TUCK Christopher O, Eduardo PÉREZ, HORVÁTH István T, et al. Valorization of biomass: Deriving more value from waste[J]. Science, 2012, 337(6095): 695-699.
4	SOMERVILLE Chris, YOUNGS Heather, TAYLOR Caroline, et al. Feedstocks for lignocellulosic biofuels[J]. Science, 2010, 329(5993): 790-792.
5	SCHUTYSER W, RENDERS T, VAN DEN BOSCH S, et al. Chemicals from lignin: An interplay of lignocellulose fractionation, depolymerisation, and upgrading[J]. Chemical Society Reviews, 2018, 47(3): 852-908.
6	GALKIN Maxim V, SAMEC Joseph S M. Lignin valorization through catalytic lignocellulose fractionation: A fundamental platform for the puture biorefinery[J]. ChemSusChem, 2016, 9(13): 1544-1558.
7	ABU-OMAR Mahdi M, BARTA Katalin, BECKHAM Gregg T, et al. Guidelines for performing lignin-first biorefining[J]. Energy & Environmental Science, 2021, 14(1): 262-292.
8	VAN DEN BOSCH S, SCHUTYSER W, VANHOLME R, et al. Reductive lignocellulose fractionation into soluble lignin-derived phenolic monomers and dimers and processable carbohydrate pulps[J]. Energy & Environmental Science, 2015, 8(6): 1748-1763.
9	DU Xu, TRICKER Andrew W, YANG Weisheng, et al. Oxidative catalytic fractionation and depolymerization of lignin in a one-pot single-catalyst system[J]. ACS Sustainable Chemistry & Engineering, 2021, 9(23): 7719-7727.
10	BERTELLA Stefania, LUTERBACHER Jeremy S. Simultaneous extraction and controlled chemical functionalization of hardwood lignin for improved phenolation[J]. Green Chemistry, 2021, 23(9): 3459-3467.
11	DE SANTI Alessandra, GALKIN Maxim V, LAHIVE Ciaran W, et al. Lignin-first fractionation of softwood lignocellulose using a mild dimethyl carbonate and ethylene glycol organosolv process[J]. ChemSusChem, 2020, 13(17): 4468-4477.
12	LI Xi, XU Ying, ALORKU Kingdom, et al. A review of lignin-first reductive catalytic fractionation of lignocellulose[J]. Molecular Catalysis, 2023, 550: 113551.
13	SAGUES William J, BAO Hanxi, NEMENYI John L, et al. Lignin-first approach to biorefining: Utilizing fenton’s reagent and supercritical ethanol for the production of phenolics and sugars[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(4): 4958-4965.
14	RINALDI Roberto, WOODWARD Robert T, FERRINI Paola, et al. Lignin-first biorefining of lignocellulose: The impact of process severity on the uniformity of lignin oil composition[J]. Journal of the Brazilian Chemical Society, 2019, 30(3): 479-491.
15	SAINI Rahul, OSORIO-GONZALEZ Carlos Saul, HEGDE Krishnamoorthy, et al. Lignocellulosic biomass-based biorefinery: An insight into commercialization and economic standout[J]. Current Sustainable/Renewable Energy Reports, 2020, 7(4): 122-136.
16	宋国勇. “木质素优先”策略下林木生物质组分催化分离与转化研究进展[J]. 林业工程学报, 2019, 4(5): 1-10.
	SONG Guoyong. The development of catalytic fractionation and conversion of lignocellulosic biomass under lignin-first strategy[J]. Journal of Forestry Engineering, 2019, 4(5): 1-10.
17	KORÁNYI Tamás I, Bálint FRIDRICH, PINEDA Antonio, et al. Development of ‘lignin-first’ approaches for the valorization of lignocellulosic biomass[J]. Molecules, 2020, 25(12): 2815.
18	薛泓坤, 胡晓虹, 张琦, 等. 不同组分优先策略下的生物质三大素分离研究进展[J]. 林产化学与工业, 2024, 44(4): 149-162.
	XUE Hongkun, HU Xiaohong, ZHANG Qi, et al. Advances in separation of cellulose, hemicellulose and lignin from biomass under different component prioritization strategies[J]. Chemistry and Industry of Forest Products, 2024, 44(4): 149-162.
19	杨旭, 骆治成, 肖睿, 等. “木质素优先”策略下生物质还原催化分离技术研究进展[J]. 能源环境保护, 2023, 37(3): 64-74.
	YANG Xu, LUO Zhicheng, XIAO Rui, et al. Progress of reductive catalytic fractionation of lignocellulosic biomass based on the lignin-first strategy[J]. Energy Environmental Protection, 2023, 37(3): 64-74.
20	李治宇, 逯炀炀, 王文文, 等. “木质素优先解聚”策略下生物质定向解聚研究进展[J]. 农业工程学报, 2024, 40(1): 129-141.
	LI Zhiyu, LU Yangyang, WANG Wenwen, et al. Progress in directed biomass depolymerisation under the “lignin-first depolymerisation” strategy[J]. Transactions of the Chinese Society of Agricultural Engineering, 2024, 40(1): 129-141.
21	RINALDI Roberto, JASTRZEBSKI Robin, CLOUGH Matthew T, et al. Paving the way for lignin valorisation: Recent advances in bioengineering, biorefining and catalysis[J]. Angewandte Chemie International Edition, 2016, 55(29): 8164-8215.
22	GALKIN Maxim V, SMIT Arjan T, SUBBOTINA Elena, et al. Hydrogen-free catalytic fractionation of woody biomass[J]. ChemSusChem, 2016, 9(23): 3280-3287.
23	DEL RÍO José C, RENCORET Jorge, MARQUES Gisela, et al. Structural characterization of the lignin from jute (Corchorus capsularis) fibers[J]. Journal of Agricultural and Food Chemistry, 2009, 57(21): 10271-10281.
24	DEL RÍO José C, RENCORET Jorge, PRINSEN Pepijin, et al. structural characterization of wheat straw lignin as revealed by analytical pyrolysis, 2D-NMR, and reductive cleavage methods[J]. Journal of Agricultural and Food Chemistry, 2012, 60(23): 5922-5935.
25	DEL RÍO José C, LINO Alessandro G, COLODETTE Jorge L, et al. Differences in the chemical structure of the lignins from sugarcane bagasse and straw[J]. Biomass and Bioenergy, 2015, 81: 322-338.
26	PARSELL Trenton, YOHE Sara, DEGENSTEIN John, et al. A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass[J]. Green Chemistry, 2015, 17(3): 1492-1499.
27	EBIKADE Elvis Osamudiamhen, SAMULEWICZ Nicholas, XUAN Shuangqing, et al. Reductive catalytic fractionation of agricultural residue and energy crop lignin and application of lignin oil in antimicrobials[J]. Green Chemistry, 2020, 22(21): 7435-7447.
28	HUANG Xiaoming, MORALES GONZALEZ Olivia M, ZHU Jiadong, et al. Reductive fractionation of woody biomass into lignin monomers and cellulose by tandem metal triflate and Pd/C catalysis[J]. Green Chemistry, 2017, 19(1): 175-187.
29	SU Shihao, XIAO Lingping, CHEN Xue, et al. Lignin-first depolymerization of lignocellulose into monophenols over carbon nanotube-supported ruthenium: Impact of lignin sources[J]. ChemSusChem, 2022, 15(12): e202200365.
30	VAN DEN BOSCH S, SCHUTYSER W, KOELEWIJN S F, et al. Tuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood[J]. Chemical Communications, 2015, 51(67): 13158-13161.
31	CHEN Jiazhi, LU Fang, SI Xiaoqin, et al. High yield production of natural phenolic alcohols from woody biomass using a nickel-based catalyst[J]. ChemSusChem, 2016, 9(23): 3353-3360.
32	LIU Xue, LI Helong, XIAO Lingping, et al. Chemodivergent hydrogenolysis of eucalyptus lignin with Ni@ZIF-8 catalyst[J]. Green Chemistry, 2019, 21(6): 1498-1504.
33	RENDERS Tom, SCHUTYSER Wouter, VAN DEN BOSCH S, et al. Influence of acidic (H₃PO₄) and alkaline (NaOH) additives on the catalytic reductive fractionation of lignocellulose[J]. ACS Catalysis, 2016, 6(3): 2055-2066.
34	YE Ke, LIU Ying, WU Shubin, et al. A review for lignin valorization: Challenges and perspectives in catalytic hydrogenolysis[J]. Industrial Crops and Products, 2021, 172: 114008.
35	SHUAI Li, LUTERBACHER Jeremy. Organic solvent effects in biomass conversion reactions[J]. ChemSusChem, 2016, 9(2): 133-155.
36	PATEROMICHELAKIS Antreas, PSYCHA Melina, PYRGAKIS Konstantinos, et al. The use of GVL for holistic valorization of biomass[J]. Computers & Chemical Engineering, 2022, 164: 107849.
37	FERRINI Paola, RINALDI Roberto. Catalytic biorefining of plant biomass to non-pyrolytic lignin bio-oil and carbohydrates through hydrogen transfer reactions[J]. Angewandte Chemie International Edition, 2014, 53(33): 8634-8639.
38	ZHAI Qiaolong, LI Jie, MIAO Kangze, et al. Atmospheric one-pot fractionation and catalytic conversion of lignocellulose in multifunctional deep eutectic solvent system[J]. International Journal of Biological Macromolecules, 2025, 290: 138736.
39	REN Tianyu, YOU Shengping, ZHANG Zhaofeng, et al. Highly selective reductive catalytic fractionation at atmospheric pressure without hydrogen[J]. Green Chemistry, 2021, 23(4): 1648-1657.
40	RAUTIAINEN Sari, FRANCESCO Davide Di, KATEA Sarmad Naim, et al. Lignin valorization by cobalt-catalyzed fractionation of lignocellulose to yield monophenolic compounds[J]. ChemSusChem, 2019, 12(2): 404-408.
41	EKEOMA Bernard C, BARA Jason E, SHEEHAN James D. Glycerol-derived ethers enable hydrogen-free reductive catalytic fractionation of softwood lignin into functionalized aromatic monomers[J]. RSC Sustainability, 2024, 2(10): 2851-2870.
42	QIU Shukun, LIU Xudong, WU Yiying, et al. Catalytic depolymerization of camellia oleifera shell lignin to phenolic monomers: Insights into the effects of solvent, catalyst and atmosphere[J]. Bioresource Technology, 2024, 412: 131365.
43	SUN Jiankui, LI Helong, XIAO Lingping, et al. Fragmentation of woody lignocellulose into primary monolignols and their derivatives[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(5): 4666-4674.
44	SONG Qi, WANG Feng, CAI Jiaying, et al. Lignin depolymerization (LDP) in alcohol over nickel-based catalysts via a fragmentation-hydrogenolysis process[J]. Energy & Environmental Science, 2013, 6(3): 994.
45	于丁一, 李圆圆, 王晨钰, 等. pH 响应性木质素水凝胶的制备及药物控释[J]. 化工进展, 2023, 42(6): 3138-3146.
	YU Dingyi, LI Yuanyuan, WANG Chenyu, et al. Preparation of lignin-based pH responsive hydrogel and its application in controlled drug release[J]. Chemical Industry and Engineering Progress, 2023, 42(6): 3138-3146.
46	娄瑞, 牛涛嫄, 曹启航, 等. δ-MnO₂原位负载纳米木质素基分级多孔炭的制备及其电化学性能[J]. 化工进展, 2024, 43(2): 1013-1021.
	LOU Rui, NIU Taoyuan, CAO Qihang, et al. Preparation and electrochemical performances of in-situ growth of δ-MnO₂ on hierarchical porous carbon derived from LNP[J]. Chemical Industry and Engineering Progress, 2024, 43(2): 1013-1021.
47	关红玲, 杨辉, 井红权, 等. 木质素基控释材料及其在药物输送和肥料控释中的应用[J]. 化工进展, 2023, 42(7): 3695-3707.
	GUAN Hongling, YANG Hui, JING Hongquan, et al. Lignin-based controlled release materials and application in drug delivery and fertilizer controlled-release[J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3695-3707.
48	白毓黎, 白富栋, 张雷, 等. 木质素基酚醛树脂的制备和过程优化[J]. 化工进展, 2024, 43(2): 1033-1038.
	BAI Yuli, BAI Fudong, ZHANG Lei, et al. Preparation and process optimization of lignin-based phenolic resin[J]. Chemical Industry and Engineering Progress, 2024, 43(2): 1033-1038.
49	DAELEMANS Brent, JUSNER Paul, SRIDHARAN Balaji, et al. Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines[J]. Chem, 2025: 102525.
50	BARTLING Andrew W, STONE Michael L, HANES Rebecca J, et al. Techno-economic analysis and life cycle assessment of a biorefinery utilizing reductive catalytic fractionation[J]. Energy & Environmental Science, 2021, 14(8): 4147-4168.
51	ARTS W, STONE VAN AELST K, COOREMAN E, et al. Stepping away from purified solvents in reductive catalytic fractionation: A step forward towards a disruptive wood biorefinery process[J]. Energy & Environmental Science, 2023, 16(6): 2518-2539.
52	Laura KÖNIG-MATTERN, SANCHEZ MEDINA Edgar I, KOMAROVA Anastasia, et al. Machine learning-supported solvent design for lignin-first biorefineries and lignin upgrading[J]. Chemical Engineering Journal, 2024, 495: 153524.
53	WEN Huaqiang, Shihao NAN, WU Di, et al. A systematic review on intensifications of artificial intelligence assisted green solvent development[J]. Industrial and Engineering Chemistry Research, 2023, 62(48): 20473-20491.
54	ZHANG Jun, WANG Qin, EDEN Mario, et al. A deep learning-based framework towards inverse green solvent design for extractive distillation with multi-index constraints[J]. Computers and Chemical Engineering, 2023, 177: 108335.
55	WU Di, ZHU Zutao, ZHANG Jun, et al. An interpretable solute-solvent interactive attention module intensified graph-learning architecture toward enhancing the prediction accuracy of an infinite dilution activity coefficient[J]. Industrial and Engineering Chemistry Research, 2024, 63(19): 8741-8750.
56	YANG Lu, LIU Shuoshi, CHANG Chenglin, et al. An efficient and invertible machine learning-driven multi-objective optimization architecture for light olefins separation system[J]. Chemical Engineering Science, 2024, 285: 119553.
57	RENDERS T, VAN DEN BOSCH S, KOELEWIJN S F, et al. Lignin-first biomass fractionation: the advent of active stabilisation strategies[J]. Energy & Environmental Science, 2017, 10(7): 1551-1557.
58	CHAN Min Kang, YE Qun, Zhuang Mao PNG, et al. Valorization of lignin: Effective conversion of depolymerized lignin to oil by simple chemical modifications[J]. Waste and Biomass Valorization, 2017, 8: 2029-2036.
59	YU Shitong, XU Pan, LUO Zhicheng. Catalytic depolymerization and hydrodeoxygenation of lignin to high-density fuel precursors using Ni/Nb₂O₅ catalyst[J]. Industrial Crops and Products, 2024, 222: 119632.
60	HUANG Yong, DUAN Yijing, QIU Shi, et al. Lignin-first biorefinery: A reusable catalyst for lignin depolymerization and application of lignin oil to jet fuel aromatics and polyurethane feedstock[J]. Sustainable Energy & Fuels, 2018, 2(3): 637-647.
61	KOURIS Panos D, BRINI Alberto, SCHEPERS Eline, et al. Optimizing catalytic depolymerization of lignin in ethanol with a day-clustered box-behnken design[J]. Industrial & Engineering Chemistry Research, 2023, 62(18): 6874-6885.
62	DONG Lin, XIN Yu, LIU Xiaohui, et al. Selective hydrodeoxygenation of lignin oil to valuable phenolics over Au/Nb₂O₅ in water[J]. Green Chemistry, 2019, 21(11): 3081-3090.
63	QUINSAAT Jose Enrico Q, FALIREAS Panagiotis G, FEGHALI Elias, et al. Depolymerised lignin oil: A promising building block towards thermoplasticity in polyurethanes[J]. Industrial Crops and Products, 2023, 194: 116305.
64	PANDALONE Bruno, RAIKWAR Deepak, Thuan A VO, et al. Optimum lignin oil — Finding the most suitable feedstock to replace cycloalkanes in sustainable aviation fuel (SAF)[J]. ChemSusChem, 2025: e202402531.
65	LIAO Yuhe, KOELEWIJN Steven-Friso, VAN DEN BOSSCHE Gil, et al. A sustainable wood biorefinery for low-carbon footprint chemicals production[J]. Science, 2020, 367(6484): 1385-1390.
66	董琳, 陈祖鹏. 木质素源多巴胺的合成新工艺[J]. 科学通报, 2023, 68(31): 4079-4081.
	DONG Lin, CHEN Zupeng. An innovative strategy for production of dopamine from lignin[J]. Chinese Science Bulletin, 2023, 68(31): 4079-4081.
67	DONG Lin, WANG Yanqin, DONG Yuguo, et al. Sustainable production of dopamine hydrochloride from softwood lignin[J]. Nature Communications, 2023, 14(1): 4996.
68	SHI Tao, ZHOU Jianzhao, REN Jingzheng, et al. Co-valorisation of sewage sludge and poultry litter waste for hydrogen production: Gasification process design, sustainability-oriented optimization, and systematic assessment[J]. Energy, 2023, 272: 127131.
69	SHI Tao, ABDUL MOKTADIR Md, REN Jingzheng, et al. Comparative economic, environmental and exergy analysis of power generation technologies from the waste sludge treatment[J]. Energy Conversion and Management, 2023, 286: 117074.
70	TSCHULKOW Maxim, PIZZOL Massimo, COMPERNOLLE Tine, et al. The environmental impacts of the lignin-first biorefineries: A consequential life cycle assessment approach[J]. Resources, Conservation and Recycling, 2024, 204: 107466.

原料	溶剂	催化剂	反应条件	单体产率/%	参考文献
桦木	甲醇	Ru/C	250℃，30bar H₂，3h	52.0	[8]
白桦树	γ-戊内酯/水/甲醛	Pd/Ru	120℃，2bar H₂，2h	50.0	[36]
杨木	异丙醇/水	Raney Ni	220℃，无氢气，3h	26.0	[37]
杨木	草酸/乙二醇/氯化胆碱	Ru/C	180℃，无氢气，3h	13.8	[38]
杨木	乙二醇	Ru/C	230℃，30bar H₂，3h	11.8	[39]
桦木	乙醇/水/甲酸/甲酸钠	Co-phen/C	200℃，无氢气，4h	34.0	[40]
松树	1,3-二甲氧基丙-2-醇/乙酸/水	Pt/C	200℃，无氢气，4h	24.9	[41]
油茶花壳	乙醇/水	Pd/C	260℃，20bar H₂，3h	17.0	[42]
桉木	水	MoO _x /SBA-15	260℃，30bar H₂，4h	2.4	[43]

原料	溶剂	催化剂	反应条件	单体产率/%	参考文献
桦木	甲醇	Ru/C	250℃，30bar H₂，3h	52.0	[8]
白桦树	γ-戊内酯/水/甲醛	Pd/Ru	120℃，2bar H₂，2h	50.0	[36]
杨木	异丙醇/水	Raney Ni	220℃，无氢气，3h	26.0	[37]
杨木	草酸/乙二醇/氯化胆碱	Ru/C	180℃，无氢气，3h	13.8	[38]
杨木	乙二醇	Ru/C	230℃，30bar H₂，3h	11.8	[39]
桦木	乙醇/水/甲酸/甲酸钠	Co-phen/C	200℃，无氢气，4h	34.0	[40]
松树	1,3-二甲氧基丙-2-醇/乙酸/水	Pt/C	200℃，无氢气，4h	24.9	[41]
油茶花壳	乙醇/水	Pd/C	260℃，20bar H₂，3h	17.0	[42]
桉木	水	MoO _x /SBA-15	260℃，30bar H₂，4h	2.4	[43]

项目	甲醇	乙醇	无氢	乙二醇
粗RCF油最低销售价格/USD	1.12	1.18	0.76	0.98
木质素部分最低销售价格/USD	1.74	1.88	1.34	1.51
单体部分最低销售价格/USD	3.63	3.76	7.58	3.07
木质素部分全球变暖潜能值 /kg CO₂·kg^-1	0.079	-0.175	-0.018	0.392
木质素部分累积能源需求/MJ	74.03	77.47	75.36	77.93

项目	甲醇	乙醇	无氢	乙二醇
粗RCF油最低销售价格/USD	1.12	1.18	0.76	0.98
木质素部分最低销售价格/USD	1.74	1.88	1.34	1.51
单体部分最低销售价格/USD	3.63	3.76	7.58	3.07
木质素部分全球变暖潜能值 /kg CO₂·kg^-1	0.079	-0.175	-0.018	0.392
木质素部分累积能源需求/MJ	74.03	77.47	75.36	77.93

[1]	曹湘洪, 周峰, 姜睿, 刘诗哲, 方向晨, 亢万忠, 乔金樑, 聂红. 加快我国生物基材料产业发展的对策[J]. 化工进展, 2025, 44(5): 2385-2393.
[2]	钟家伟, 谭涛, 谢君, 陈勇. 生物质高值能源转换技术[J]. 化工进展, 2025, 44(5): 2524-2528.
[3]	聂红, 习远兵, 葛泮珠, 丁石, 张登前. 可持续航空燃料生产路线与展望——以中石化石科院为例[J]. 化工进展, 2025, 44(5): 2529-2534.
[4]	王水众, 宋国勇. 木质素选择性氢解制备高功能化单酚及其高值利用[J]. 化工进展, 2025, 44(5): 2535-2540.
[5]	陈彦君, 戴杰, 单军强, 张思欣, 计磊, 朱晨杰, 应汉杰. 我国纤维素乙醇的研究进展和发展趋势[J]. 化工进展, 2025, 44(5): 2541-2562.
[6]	乔凯, 张震宇, 马会霞, 傅杰, 周峰. 生物基呋喃二甲酸关键技术路线和产业发展现状[J]. 化工进展, 2025, 44(5): 2577-2586.
[7]	许镇浩, 易子骁, 曾晨, 王宇辰, 严凯. 生物质基平台分子转化升级的研究进展[J]. 化工进展, 2025, 44(5): 2642-2654.
[8]	冯娇, 刘明明, 刘耀, 王昕, 陈可泉. 利用可再生原料生物合成脂肪族短链二元胺与醇的研究进展[J]. 化工进展, 2025, 44(5): 2655-2666.
[9]	孙仲顺, 刘根, 程春昱, 李美昕, 杨宪坛, 吴志强, 杨伯伦. 生物质热化学转化制备绿氢研究进展[J]. 化工进展, 2025, 44(5): 2667-2682.
[10]	戴月明, 周梅芳, 沈建华, 姜海波, 李春忠. TiO₂纳米颗粒烧结机制分子动力学模拟[J]. 化工进展, 2025, 44(4): 2202-2214.
[11]	周郭宁, 朱昊辰, 贺文智, 李光明. 水热技术用于农业废弃物处理的研究进展Ⅰ：生物原油制备[J]. 化工进展, 2025, 44(4): 2297-2312.
[12]	周郭宁, 朱昊辰, 贺文智, 李光明. 水热技术用于农业废弃物处理的研究进展Ⅱ：水热炭化[J]. 化工进展, 2025, 44(4): 2313-2327.
[13]	陶金泉, 贾亦静, 白天瑜, 姚荣鹏, 黄文斌, 崔岩, 周亚松, 魏强. Silicalite-1分子筛的低成本合成及其MTP催化性能[J]. 化工进展, 2025, 44(3): 1550-1558.
[14]	冯鹏, 徐东海, 何冰, 刘欢腾, 杨立杰, 王攀, 刘青山. 亚/超临界水中典型硫酸盐Na₂SO₄和K₂SO₄的溶解特性及机理[J]. 化工进展, 2025, 44(3): 1706-1715.
[15]	邱泽刚, 石亚斐, 李志勤. 生物质衍生芳香族含氧化合物中C—O键断裂研究进展[J]. 化工进展, 2025, 44(3): 1183-1193.

“木质素优先”还原催化分馏工艺与模拟研究进展

Advances in "lignin-first" reductive catalytic fractionation process and simulation

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 70

相关文章 15

编辑推荐

Metrics

本文评价