超疏水-高疏油SiC膜的制备及性能

doi:10.16085/j.issn.1000-6613.2023-1195

化工进展 ›› 2024, Vol. 43 ›› Issue (8): 4516-4522.DOI: 10.16085/j.issn.1000-6613.2023-1195

• 材料科学与技术 • 上一篇

超疏水-高疏油SiC膜的制备及性能

李莉¹(), 蔡鑫宇¹, 陈寅杰¹, 张文启¹, 李光辉², 饶品华¹()

^1.上海工程技术大学化学化工学院，上海 201620
^2.上海工程技术大学环境与资源创新中心，上海 201620

收稿日期:2023-07-13 修回日期:2023-09-06 出版日期:2024-08-15 发布日期:2024-09-02
通讯作者: 饶品华
作者简介:李莉（1999—），女，硕士研究生，研究方向为碳化硅膜的表面功能化。E-mail：a625101098@163.com。
基金资助:
上海市地方院校能力建设项目(21010501400);上海市浦江人才计划(20PJ1404600)

Preparation and properties of superhydrophobic-highly oleophobic SiC membrane

LI li¹(), CAI Xinyu¹, CHEN Yinjie¹, ZHANG Wenqi¹, LI Guanghui², RAO Pinhua¹()

^1.School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620，China
^2.Innovation Center for Environment and Resources, Shanghai University of Engineering Science, Shanghai 201620, China

Received:2023-07-13 Revised:2023-09-06 Online:2024-08-15 Published:2024-09-02
Contact: RAO Pinhua

摘要/Abstract

摘要：

基于SiO₂粒子共混喷涂与浸渍方法，研发了一种在SiC膜上制备超疏水-高疏油表面的工艺。通过喷涂不同粒径的SiO₂颗粒，在SiC膜表面构造具有双疏性能的微纳双重粗糙结构，然后通过浸渍将十七氟癸基三甲氧基硅烷接枝至SiC膜表面，成功制备了具有超疏水-高疏油特性和优异自清洁性能的SiC膜。通过改变含氟量、粗糙度，分析了各参数对表面润湿性的影响。经改性后所得超疏水-高疏油SiC膜表面上水和正十六烷的静态接触角分别为152.6°和146.3°，滚动角分别为5.2°和10.2°，这归因于SiC膜表面的微纳结构和低表面能物质降低了其与其他物质的黏附力。在强酸和强碱溶液中，超疏水-高疏油SiC膜表现出稳定的双疏性。本研究为在无机膜上构建具有优异耐酸碱性的超疏水-高疏油表面提供了一种简便的工艺。

关键词: SiC膜, 喷涂, 超疏水-高疏油, 表面修饰, 自清洁

Abstract:

A process was developed to prepare a superhydrophobic-highly oleophobic surface on SiC membrane based on SiO₂ particle blending spraying and immersion method. By spraying SiO₂ particles of different sizes, a micro-nano dual rough structure with amphiphobic capability was created on the surface of the SiC membrane. Then, perfluorodecyltrimethoxysilane was grafted onto the SiC membrane surface through immersion, successfully achieving a SiC membrane with superhydrophobic-highly oleophobic characteristics and excellent self-cleaning performance. The effects of different parameters, such as fluorine content and surface roughness, on surface wettability were analyzed. The modified superhydrophobic-highly oleophobic SiC membrane exhibited the static water contact angle of 152.6°and the static contact angle of n-hexadecane of 146.3°. The sliding angles were measured to be 5.2°and 10.2°, respectively. These properties could be attributed to the micro-nano structure on the SiC membrane surface and the low surface energy material, which reduced the adhesion between the surface and other substances. The superhydrophobic-highly oleophobic SiC membrane also exhibited stable amphiphobicity in strong acid and alkali solutions. This research provided a simple process for constructing superhydrophobic-highly oleophobic surfaces with excellent acid-base resistance on inorganic membranes.

Key words: SiC membrane, spraying, superhydrophobic-highly oleophobic, surface modification, self-cleaning

中图分类号:

李莉, 蔡鑫宇, 陈寅杰, 张文启, 李光辉, 饶品华. 超疏水-高疏油SiC膜的制备及性能[J]. 化工进展, 2024, 43(8): 4516-4522.

LI li, CAI Xinyu, CHEN Yinjie, ZHANG Wenqi, LI Guanghui, RAO Pinhua. Preparation and properties of superhydrophobic-highly oleophobic SiC membrane[J]. Chemical Industry and Engineering Progress, 2024, 43(8): 4516-4522.

图/表 7

图1 超疏水-高疏油SiC膜表面EDS分析

图2 超疏水-高疏油SiC膜表面FTIR分析

图3 原SiC膜和超疏水-高疏油SiC膜表面形貌

图4 喷涂层数、SiO2粒径配比对膜表面粗糙度的影响

图5 超疏水-高疏油SiC膜表面接触角分析（质量比为70nmSiO2∶1μmSiO2∶2μmSiO2=2∶1∶1）

图6 超疏水-高疏油SiC膜化学稳定性测试（氟质量分数为1%，质量比70nmSiO2∶1μmSiO2∶2μmSiO2=2∶1∶1）

图7 原膜和超疏水-高疏油SiC膜的抗润湿性能和自清洁性能（氟质量分数为1%，质量比70nmSiO2∶1μmSiO2∶2μmSiO2=2∶1∶1）

参考文献 22

1	WU Ting, XU Wenhua, GUO Kang, et al. Efficient fabrication of lightweight polyethylene foam with robust and durable superhydrophobicity for self-cleaning and anti-icing applications[J]. Chemical Engineering Journal, 2021, 407: 127100.
2	JIANG Rujian, HAO Lingwan, SONG Lingjie, et al. Lotus-leaf-inspired hierarchical structured surface with non-fouling and mechanical bactericidal performances[J]. Chemical Engineering Journal, 2020, 398: 125609.
3	KREDER Michael J, ALVARENGA Jack, KIM Philseok, et al. Design of anti-icing surfaces: Smooth, textured or slippery?[J]. Nature Reviews Materials, 2016, 1(1): 15003.
4	DENG R, HU Y M, WANG L, et al. An easy and environmentally-friendly approach to superamphiphobicity of aluminum surfaces[J]. Applied Surface Science, 2017, 402: 301-307.
5	ZHAO Xiaoxiao, PARK Daniel S, CHOI Junseo, et al. Flexible-templated imprinting for fluorine-free, omniphobic plastics with reentrant structures[J]. Journal of Colloid and Interface Science, 2021, 585: 668-675.
6	KIM Aeree, LEE Chan, KIM Joonwon. Durable, scalable, and tunable omniphobicity on stainless steel mesh for separation of low surface tension liquid mixtures[J]. Surface and Coatings Technology, 2018, 344: 394-401.
7	TOGASAWA Ryo, OHNUKI Fumiya, SHIRATORI Seimei. A biocompatible slippery surface based on a boehmite nanostructure with omniphobicity for hot liquids and boiling stability[J]. ACS Applied Nano Materials, 2018, 1(4): 1758-1765.
8	ZHANG Junping, YU Bo, WEI Qingyun, et al. Highly transparent superamphiphobic surfaces by elaborate microstructure regulation[J]. Journal of Colloid and Interface Science, 2019, 554: 250-259.
9	PAKDEL Amir, ZHI Chunyi, BANDO Yoshio, et al. Boron nitride nanosheet coatings with controllable water repellency[J]. ACS Nano, 2011, 5(8): 6507-6515.
10	WANG Peizhuang, ZHANG Li, HU Zhiqing, et al. Transparent and anti-fingerprint coating prepared with chitin nanofibers and surface modification via vapor deposition[J]. Progress in Organic Coatings, 2022, 172: 107126.
11	XU Guorong, AN Xiaochan, Rasel DAS, et al. Application of electrospun nanofibrous amphiphobic membrane using low-cost poly (ethylene terephthalate) for robust membrane distillation[J]. Journal of Water Process Engineering, 2020, 36: 101351.
12	HUANG Yuxi, WANG Zhangxin, HOU Deyin, et al. Coaxially electrospun super-amphiphobic silica-based membrane for anti-surfactant-wetting membrane distillation[J]. Journal of Membrane Science, 2017, 531: 122-128.
13	ZHAO Xia, DUAN Yanping. Improve the mechanical durability of superhydrophobic/superamphiphobic coating through multiple cross-linked mesh structure[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 642: 128560.
14	GUO Xudong, GUO Ruibin, FANG Mengqi, et al. A novel composite protective coating with UV and corrosion resistance: Load floating and self-cleaning performance[J]. Ceramics International, 2022, 48(12): 17308-17318.
15	ZHANG Dongjiu, WU Guoqing, LI Hong, et al. Superamphiphobic surfaces with robust self-cleaning, abrasion resistance and anti-corrosion[J]. Chemical Engineering Journal, 2021, 406: 126753.
16	DONG Jie, WANG Qin, ZHANG Yujie, et al. Colorful superamphiphobic coatings with low sliding angles and high durability based on natural nanorods[J]. ACS Applied Materials & Interfaces, 2017, 9(2): 1941-1952.
17	QU Mengnan, LIU Shanshan, HE Jinmei, et al. Bioinspired durable superhydrophobic materials with antiwear property fabricated from quartz sands and organosilane[J]. Journal of Materials Science, 2016, 51(18): 8718-8727.
18	ZHONG Bo, KONG Lingqi, ZHANG Bin, et al. Fabrication of novel hydrophobic SiC/SiO₂ bead-string like core-shell nanochains via a facile catalyst/template-free thermal chemical vapor deposition process[J]. Materials Chemistry and Physics, 2018, 217: 111-116.
19	REZAEI Sasan, MANOUCHERI Iraj, MORADIAN Rostam, et al. One-step chemical vapor deposition and modification of silica nanoparticles at the lowest possible temperature and superhydrophobic surface fabrication[J]. Chemical Engineering Journal, 2014, 252: 11-16.
20	CHEN Liwei, GUO Zhiguang, LIU Weimin. Biomimetic multi-functional superamphiphobic FOTS-TiO₂ particles beyond lotus leaf[J]. ACS Applied Materials & Interfaces, 2016, 8(40): 27188-27198.
21	BIAN Xin, KIM Changho, KARNIADAKIS George Em. 111 Years of Brownian motion[J]. Soft Matter, 2016, 12(30): 6331-6346.
22	CASSIE A B D, BAXTER S. Wettability of porous surfaces[J]. Transactions of the Faraday Society, 1944, 40: 546-551.

[1]	张新宇, 赵祯霞. 金属有机骨架基复合相变储热材料研究进展[J]. 化工进展, 2022, 41(12): 6408-6418.
[2]	王喜倩, 尹国强, 郭清兵, 何明. 多巴胺表面修饰角蛋白/聚乳酸纳米纤维膜的制备及性能[J]. 化工进展, 2022, 41(1): 373-381.
[3]	马冠香, 杨令, 王亭杰. 聚多巴胺修饰纳米SiO₂颗粒[J]. 化工进展, 2021, 40(12): 6729-6737.
[4]	郑细鸣, 范荣玉. 微孔聚丙烯膜表面壳聚糖季铵盐的共价修饰及其抗菌性能[J]. 化工进展, 2021, 40(1): 332-338.
[5]	俞森龙, 胡香凝, 唐飞宇, 祝晨杰, 相恒学, 周家良, 胡泽旭, 冯琦云, 朱美芳. 聚乳酸阻燃改性研究进展[J]. 化工进展, 2020, 39(9): 3421-3432.
[6]	朱恩权, 马玉花, 艾尼娃·木尼热. 红磷光催化材料的研究进展[J]. 化工进展, 2019, 38(s1): 139-143.
[7]	付绒,杨春林,胡燕燕,欧梅桂. 核壳型磁性荧光纳米复合材料的制备及其应用研究进展[J]. 化工进展, 2019, 38(08): 3742-3755.
[8]	陈宝辉, 陆佳政, 马鹏军, 金灵华, 刘刚, 方针. CoFe₂O₄基棕褐色太阳能吸收涂层的制备及性能[J]. 化工进展, 2018, 37(S1): 141-146.
[9]	秦茜, 孙玉绣, 王乃鑫, 谢亚勃, 李建荣. 表面修饰在MOF薄膜制备中的应用[J]. 化工进展, 2017, 36(04): 1306-1315.
[10]	高余良, 朱光明, 马拖拖. Fe₃O₄磁性纳米粒子及其生物医学应用研究进展[J]. 化工进展, 2017, 36(03): 973-980.
[11]	徐冬梅, 刘建, 高军, 刘迪, 刘晓伟. 金纳米棒的合成、光学特性、修饰及其在生物学中的应用[J]. 化工进展, 2016, 35(07): 2121-2129.
[12]	成文凯, 王嘉骏, 顾雪萍, 冯连芳. 聚合物搅拌脱挥设备及其CFD模拟研究进展[J]. 化工进展, 2016, 35(05): 1283-1288.
[13]	马翔宇, 金长春, 董如林. Pt修饰的Pd/石墨烯纳米复合材料的制备及对乙二醇氧化反应的电催化活性[J]. 化工进展, 2015, 34(04): 1019-1022,1073.
[14]	董如林，刘淑赟，陈智栋，金长春，王彩霞. TiO2/SiO2复合薄膜的制备及其自清洁性能[J]. 化工进展, 2013, 32(03): 645-651.
[15]	蔡雷，熊兴泉，唐忠科，徐源鸿. 基于巯基-炔的“点击”化学研究进展 [J]. 化工进展, 2011, 30(9): 1982-.

超疏水-高疏油SiC膜的制备及性能

Preparation and properties of superhydrophobic-highly oleophobic SiC membrane

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 22

相关文章 15

编辑推荐

Metrics

本文评价