木糖生物炼制与高值化应用研究进展

doi:10.16085/j.issn.1000-6613.2023-0947

化工进展 ›› 2024, Vol. 43 ›› Issue (7): 3798-3811.DOI: 10.16085/j.issn.1000-6613.2023-0947

• 能源加工与技术 • 上一篇

木糖生物炼制与高值化应用研究进展

舒岗韦¹(), 林钰程¹, 张为宏², 赵世强¹^,³, 郑晓阳², 常春¹^,⁴()

^1.郑州大学化工学院，河南郑州 450001
^2.焦作市华康糖醇科技有限公司，河南焦作 454150
^3.生物基运输
^1.燃料技术全国重点实验室，河南郑州 450001，郑州大学河南省杰出外籍科学家工作室，河南郑州 450001

收稿日期:2023-06-08 修回日期:2023-08-04 出版日期:2024-07-10 发布日期:2024-08-14
通讯作者: 常春
作者简介:舒岗韦（1997—），男，硕士研究生，研究方向为生物质炼制与高值化。E-mail：shuke9723@163.com。
基金资助:
国家自然科学基金(22178328);河南省重点研发与推广项目（科技攻关）(222102320059);生物质资源加工与高效利用杰出外籍科学家工作室项目(GZS2022007)

Research progress in biorefinery and high value application of xylose

SHU Gangwei¹(), LIN Yucheng¹, ZHANG Weihong², ZHAO Shiqiang¹^,³, ZHENG Xiaoyang², CHANG Chun¹^,⁴()

^1.School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China
^2.Henan Jiaozuo Huakang Sugar Alcohol Technology Co. , Ltd. , Jiaozuo 454150, Henan, China
^3.National Key Laboratory of Biobased Transport Fuel Technology, Zhengzhou 450001, Henan, China
^4.Henan Center for Outstanding Overseas Scientists, Zhengzhou University, Zhengzhou 450001, Henan, China

Received:2023-06-08 Revised:2023-08-04 Online:2024-07-10 Published:2024-08-14
Contact: CHANG Chun

摘要/Abstract

摘要：

木糖作为木质纤维素生物质中半纤维素部分最丰富的戊糖，其衍生物具有巨大的应用市场。在国家“双碳”目标下，绿色高效的木糖炼制工艺不仅符合国家节能减排、绿色循环发展的要求，也能有效降低木糖制备成本并促进木糖的高值化利用。本文对木糖的生物炼制工艺进行了综述，并分析了不同工艺发展现状及存在的问题。同时综述了近年来木糖水解分离技术的进展以及木糖在生物基化学品和生物基材料的高值化应用，最后提出了促进木糖生物炼制发展的建议并对木糖高值化应用进行了展望。

关键词: 生物炼制, 半纤维素, 木糖, 高值化应用

Abstract:

Xylose is the most abundant pentose in hemicellulose of lignocellulosic biomass, and its derivatives have a huge application market. Under the national“carbon peaking and carbon neutrality”strategic goal, the more green and efficient xylose refining process conforms to the national requirements of energy conservation, emission reduction and green cycle development, and can also effectively reduce the cost of xylose preparation and promote the high-value utilization of xylose. In this paper, the biological refining process of xylose is reviewed, and the development status and existing problems of different processes are analyzed. At the same time, the development of xylose hydrolysis and separation technology in recent years and the high-value applications of xylose in bio-based chemicals and bio-based materials are reviewed. Finally, suggestions for promoting the development of xylose biorefinery and prospects for high-value applications of xylose are proposed.

Key words: biorefinery, hemicellulose, xylose, high value application

中图分类号:

TQ353

舒岗韦, 林钰程, 张为宏, 赵世强, 郑晓阳, 常春. 木糖生物炼制与高值化应用研究进展[J]. 化工进展, 2024, 43(7): 3798-3811.

SHU Gangwei, LIN Yucheng, ZHANG Weihong, ZHAO Shiqiang, ZHENG Xiaoyang, CHANG Chun. Research progress in biorefinery and high value application of xylose[J]. Chemical Industry and Engineering Progress, 2024, 43(7): 3798-3811.

图/表 11

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名称	纤维素/%	半纤维素/%	木质素/%	参考文献
水葫芦	18~24	26~48	3~11	[4-5]
小麦秸秆	35~40.37	28~37.32	20~22.31	[17-18]
大麦壳	34.2	35.8	13.6~18.8	[19]
柳枝稷	45	31.4	12	[20]
毛竹	35~40	20~32	20~30	[21]
玉米芯	35.3~45	30.2~37	15.3~20.6	[22-23]
稻壳	27.9~35.4	11.8~29.4	15.3~19.9	[19]
玉米秸秆	30~39	21~26	17~25	[24-25]
杨木	49.8	24.4	23.3	[26]
巨菌草	41.3~43.9	22.9~25.8	17.3~18.6	[3,27]
核桃青皮	33.82	22.42	21.42	[28]

名称	纤维素/%	半纤维素/%	木质素/%	参考文献
水葫芦	18~24	26~48	3~11	[4-5]
小麦秸秆	35~40.37	28~37.32	20~22.31	[17-18]
大麦壳	34.2	35.8	13.6~18.8	[19]
柳枝稷	45	31.4	12	[20]
毛竹	35~40	20~32	20~30	[21]
玉米芯	35.3~45	30.2~37	15.3~20.6	[22-23]
稻壳	27.9~35.4	11.8~29.4	15.3~19.9	[19]
玉米秸秆	30~39	21~26	17~25	[24-25]
杨木	49.8	24.4	23.3	[26]
巨菌草	41.3~43.9	22.9~25.8	17.3~18.6	[3,27]
核桃青皮	33.82	22.42	21.42	[28]

原料	酸	酸浓度/%	温度/℃	物料比/g·mL^-1	时间/min	木糖质量产率/%	参考文献
玉米芯	硫酸	1.2	120	1∶10	90	86.36	[33]
油棕空壳	硫酸	6	120	1∶12.5	15	—	[34]
稻草	硝酸	1	121	1∶10	30	71.32	[35]
高粱秸秆	盐酸	6	122	1∶10	70	—	[36]
玉米秸秆	盐酸	0.7	120	1∶10	40	81.0	[37]
甘蔗渣	草酸	3.6	120	1∶20	10	93.2	[38]
玉米芯	草酸	1.2	130	1∶8	120	96.1	[6]
芒草	甲酸	88	100	1∶10	180	88.58	[39]
玉米芯	乙酸/乙酸钠	0.9	170	1∶10	60	74.8	[40]
杨木	乙酸/乙酸钠	0.9	170	—	60	55.7	[41]
玉米芯	丙酸	5	170	—	50	68.5	[42]

原料	酸	酸浓度/%	温度/℃	物料比/g·mL^-1	时间/min	木糖质量产率/%	参考文献
玉米芯	硫酸	1.2	120	1∶10	90	86.36	[33]
油棕空壳	硫酸	6	120	1∶12.5	15	—	[34]
稻草	硝酸	1	121	1∶10	30	71.32	[35]
高粱秸秆	盐酸	6	122	1∶10	70	—	[36]
玉米秸秆	盐酸	0.7	120	1∶10	40	81.0	[37]
甘蔗渣	草酸	3.6	120	1∶20	10	93.2	[38]
玉米芯	草酸	1.2	130	1∶8	120	96.1	[6]
芒草	甲酸	88	100	1∶10	180	88.58	[39]
玉米芯	乙酸/乙酸钠	0.9	170	1∶10	60	74.8	[40]
杨木	乙酸/乙酸钠	0.9	170	—	60	55.7	[41]
玉米芯	丙酸	5	170	—	50	68.5	[42]

原料	反应体系溶剂	固体酸/碳前体	催化剂负载量/g·g^-1	温度/℃	时间/min	木糖质量产率/%	参考文献
玉米芯	水	碳基固体酸/木质素磺酸钠	—	130	720	84.2	[43]
玉米芯	水	碳基固体酸/稻壳	0.5	160	180	48.65	[44]
玉米芯	水	碳基固体酸/微晶纤维素	0.25	140	360	78.1	[45]
木聚糖	水	碳基固体酸/微晶纤维素、棉纤维纸浆	—	150	240	58.8	[46]
桉木屑	水	碳基固体酸/蔗糖	0.05	200	5	40.7	[47]
玉米芯	水	磁性碳基固体酸/微晶纤维素	0.5	150	120	73.4	[8]
甘蔗渣	水	磁性碳基固体酸/微晶纤维素	1	170	10	91.62	[48]
玉米芯	水	SO₄^2-/TiO₂-ZrO₂/La³⁺	—	180	120	6.8	[49]
油茶果壳	水	碳基固体酸/油茶果壳	0.2	170	20	51.41	[50]
玉米芯	水	碳基固体酸/油茶果壳	0.2	160	20	41.04	[50]
甘蔗渣	水	碳基固体酸/油茶果壳	0.15	160	20	45.03	[50]
玉米秸秆	水	H-USY沸石	—	170	180	40	[51]
竹粉	水-甲苯	菱沸石（CHA）	—	170	120	—	[52]
玉米芯	水	ZrO₂	0.33	153	318	33	[53]
玉米芯	水	阳离子交换树脂（NKC-9）	5	131	42	47.7	[54]
甘蔗渣	水	硝酸浸渍的活性炭	0.03	120	—	50	[55]

木糖生物炼制与高值化应用研究进展

Research progress in biorefinery and high value application of xylose

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原料	优化条件	效果	参考文献
玉米秸秆	0.5% H₂SO₄浸泡24h，121℃下1.21MPa保压30min	叶子和秸秆外壳的糖化率最高达89.27%	[56]
玉米秸秆	2% H₂SO₄浸泡秸秆，200℃下保压10min	半纤维素几乎全部被去除	[57]
玉米秸秆	10%(NH₄)₂CO₃浸泡秸秆，200℃保压10min	还原糖浓度显著高于单独蒸汽爆破	[58]
玉米芯	0.3% H₂SO₄以固液比为3∶1预浸6h后，200℃下蒸煮5min	提高了半纤维素的水解率	[59]
玉米秸秆	玉米秸秆使用氯化胆碱以1∶2.2的比例，1.0MPa、184℃处理15min	得到78.3%的木糖产率，增强了残渣的酶促反应	[60]
大麦秸秆	180℃下蒸汽爆破30min，固体残渣使用糖苷水解酶处理	增强酶促反应，每100g原料得到11.1g低聚木糖	[61]
小麦秸秆	小麦秸秆与蒸馏水1∶1浸润，190℃保压10min后酶处理	木糖的浓度从13.8g/L提升到18.9g/L	[62]
啤酒糟	原料使用5%H₂SO₄室温下浸渍12h后进行蒸汽爆破（170℃，30min）	与没有酸浸相比，得到了最高的木糖（49.8%）和阿拉伯糖（61.5%）质量产率	[63]

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