化工进展 ›› 2023, Vol. 42 ›› Issue (1): 204-214.DOI: 10.16085/j.issn.1000-6613.2022-0501

• 工业催化 • 上一篇    下一篇

草酸二甲酯加氢制乙醇酸甲酯反应网络分析及其多相加氢催化剂研究进展

张大洲(), 卢文新, 商宽祥, 胡媛, 朱凡, 张宗飞   

  1. 中国五环工程有限公司,湖北 武汉 430223
  • 收稿日期:2022-03-28 修回日期:2022-06-01 出版日期:2023-01-25 发布日期:2023-02-20
  • 通讯作者: 张大洲
  • 作者简介:张大洲(1987—),男,博士,高级工程师,研究方向为能源催化及工艺技术开发等。E-mail:zhangdazhou@cwcec.com

Reaction network analysis of dimethyl oxalate hydrogenation to methyl glycolate and recent progress in the heterogeneous catalysts

ZHANG Dazhou(), LU Wenxin, SHANG Kuanxiang, HU Yuan, ZHU Fan, ZHANG Zongfei   

  1. Wuhuan Engineering Co. , Ltd. , Wuhan 430023, Hubei, China
  • Received:2022-03-28 Revised:2022-06-01 Online:2023-01-25 Published:2023-02-20
  • Contact: ZHANG Dazhou

摘要:

乙醇酸甲酯(MG)官能团丰富,是一种重要的精细化工中间体,而且经过缩聚反应可制得新一代可生物降解材料聚乙醇酸。采用合成气经草酸二甲酯(DMO)加氢路线可实现MG的规模化制备,而该技术工业化的关键是高性能加氢催化剂的开发,当前DMO加氢制MG催化剂正处于工业化前期阶段。本文分析了DMO加氢反应网络及各特征反应的热力学特点,重点概述了DMO多相加氢制MG催化剂的研究进展,包括铜基催化剂、银基催化剂、非铜/银基催化剂等,基于网络特点分析了各催化剂的研究重点及存在的难题,并从反应工艺控制、催化剂载体设计、助剂及活性组分选择等角度提出了改善工业化催化剂开发及性能的思路,建议近期将改性复合载体负载的铜基催化剂,或以银、镍等为第二助剂的复合铜基催化剂作为重点攻关方向,远期将新型非贵金属体系作为储备方向,期望能为开发我国自主知识产权的工业化催化剂提供有益参考。

关键词: 合成气, 乙醇酸甲酯, 多相催化剂, 乙二醇, 可降解材料, 加氢

Abstract:

Methyl glycolate(MG) is an important fine chemical intermediate with special functional groups, and a new biodegradable plastic of polyglycolic acid (PAG) can be synthesized by the polycondensation of MG. MG can be produced in large-scale via selective hydrogenation of dimethyl oxalate from syngas and the high-performance catalyst is the key, which however is still in the early stage of industrialization. The reaction network and reaction characteristics are analyzed in the work. Subsequently, the heterogeneous catalysts for the hydrogenation of DMO to MG is overviewed, including Cu-based catalysts, Ag-based catalysts, and other catalyst systems. The focuses and existing problems of current researches are discussed in detail, and some improvements for the MG catalysts are also suggested. This review will be a useful reference for the development of hydrogenation catalyst with independent intellectual property rights.

Key words: syngas, methyl glycolate, heterogeneous catalyst, ethylene glycol, biodegradable plastics, hydrogenation

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