微反应器中费托合成的研究进展

doi:10.16085/j.issn.1000-6613.2021-0512

摘要/Abstract

摘要：

目前费托合成常用的固定床、浆态床和流化床三种反应器存在不同程度的传质和传热问题，同时反应物/产物与催化剂难以分离，而微反应器因其可在接近等温和很小压降条件下进行反应，从而有望改善费托合成的反应性能，提高所用催化剂的活性和选择性。本文首先介绍了微反应器的结构和特性，然后从催化剂种类及其在微反应器中颗粒装填式和器壁涂覆式两种形式简述了微反应器中费托合成的实验研究，并从计算流体力学和动力学研究等方面简述了微反应器中费托合成的模拟计算。

关键词: 微反应器, 费托合成, 催化剂, 计算流体力学, 反应动力学

Abstract:

At present, the three commonly used fixed bed, slurry bed and fluidized bed reactors for Fischer-Tropsch synthesis have different degrees of mass and heat transfer problems. At the same time, the reactants/products and the catalysts are difficult to separate. The reaction is carried out under conditions close to isothermal and very small pressure drop in the microreactor, which is expected to improve the reaction performance of Fischer-Tropsch synthesis and increase the activity and selectivity of the catalyst used. This article first introduces the structure and characteristics of the microreactor, and then briefly describes the experimental research of the Fischer-Tropsch synthesis in the microreactor from the type of catalyst and its particle loading type and wall coating type in the microreactor. The simulation calculation of Fischer-Tropsch synthesis in microreactors is briefly described from computational fluid dynamics and kinetics research.

Key words: microreactor, Fischer-Tropsch synthesis, catalyst, computational fluid dynamics, reaction kinetics

中图分类号:

TQ531.7

王彦谦, 王远洋. 微反应器中费托合成的研究进展[J]. 化工进展, 2021, 40(S2): 185-191.

WANG Yanqian, WANG Yuanyang. Research progress of Fischer-Tropsch synthesis in microreactor[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 185-191.

图/表 11

图1 基于不同微结构的微反应器[4]

图2 Cao等的多微通道反应器[8]

图3 Myrstad的多微通道反应器[9]

图4 3D打印技术构建的不锈钢涂覆式微反应器[10]

图5 Sun等的涂覆式微反应器[12]

图6 Abrokwah的涂覆式微反应器[13]

图7 Zhang等的涂覆式微结构反应器[15]

图8 Ying等的涂覆式微反应器

图9 Arzamendi等的微反应器模型[17]

图10 Shin等的三维微反应器模型[18]

图11 Derevich的微反应器模型[19]

参考文献 24

1	ENRIQUE Iglesia. Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalyst[J]. Applied Catalysis A: General, 1997, 161(1): 59-78.
2	石勇. 费托合成反应器的进展[J]. 化工技术与开发, 2008, 37(5): 31-38.
	SHI Yong. Development of Fischer-Tropsch synthesis reactor[J]. Technology & Development of Chemical Industry, 2008, 37(5): 31-38.
3	申文杰, 周敬来, 张碧江. FT合成反应器概述[J]. 化学工程, 1995, 23(6): 7-12.
	SHEN Wenjie, ZHOU Jinglai, ZHANG Bijiang. Overview of FT synthesis reactor[J]. Chemical Engineering(China), 1995, 23(6): 7-12.
4	EHRFELD W, HESSEL V, LOWE H. 微反应器：现代化学中的新技术[M]. 骆广生,王玉军, 吕阳成, 译. 北京: 化学工业出版社, 2004: 1-4.
	EHRFELD W, HESSEL V, LOWE H. Microreactors—New technology for modern chemistry[M]. LUO Guangsheng, WANG Yujun, LYU Yangcheng, Trans. Beijing: Chemical Industry Press, 2004: 1-4.
5	QU W L, MUDAWAR I. Flow boiling heat transfer in two-phase micro-channel heat sinks—I. experimental investigation and assessment of correlation methods[J]. International Journal of Heat and Mass Transfer, 2003, 46(15): 2755-2771.
6	骆广生, 王凯, 吕阳成, 等. 微反应器研究最新进展[J]. 现代化工, 2009, 29(5): 27-31.
	LUO Guangsheng, WANG Kai, Yangcheng LYU, et al. Advances in research of micro-reactors[J]. Modern Chemical Industry, 2009, 29(5): 27-31.
7	EHRFELD W, HESSEL V, Löwe HOLGER. State of the art of microreaction technology[M]. New Jersey: John Wiley & Sons, Ltd. 2004: 1-9.
8	CAO C S, PALO D R, TONKOVICH A L Y, et al. Catalyst screening and kinetic studies using microchannel reactors[J]. Catalysis Today, 2007, 125: 29-33.
9	MYRSTAD R, ERI S, PFEIFER P, et al. Fischer-Tropsch synthesis in a microstructured reactor[J]. Catalysis Today, 2009, 147 (S1): S301-S304.
10	MOHAMMAD Nafeezuddin, ABROKWAH Richard Y, STEVENS Boyd Robert G, et al. Fischer-Tropsch studies in a 3D-printed stainless steel microchannel microreactor coated with cobalt-based bimetallic-MCM-41 catalysts[J]. Catalysis Today, 2020, 358: 303-315.
11	BEPARI S, STEVENS-BOYD R, MOHAMMAD N, et al. Composite mesoporous SiO₂-Al₂O₃ supported Fe, FeCo and FeRu catalysts for Fischer-Tropsch studies in a 3-D printed stainless-steel microreactor[J]. Materials Today: Proceedings, 2020, 35: 221-228.
12	SUN Y, JIA Z, YANG G, et al. Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: performance evaluation and kinetic modeling[J]. International Journal of Hydrogen Energy, 2017, 42(49): 29222-29235.
13	ABROKWAH R Y, RAHMAN M M, DESHMANE V G, et al. Effect of titania support on Fischer-Tropsch synthesis using cobalt, iron, and ruthenium catalysts in silicon-microchannel microreactor[J]. Molecular Catalysis, 2019, 478: 110566.
14	MEHTA S, DESHMANE V, ZHAO S, et al. Comparative studies of silica-encapsulated iron, cobalt, and ruthenium nanocatalysts for Fischer-Tropsch synthesis in silicon-microchannel microreactors[J]. Industrial & Engineering Chemistry Research, 2014, 53(42): 16245-16253.
15	ZHANG L, CHU H, QU H, et al. An investigation of efficient microstructured reactor with monolith Co/anodic γ-Al₂O₃/Al catalyst in Fischer-Tropsch synthesis[J]. International Journal of Hydrogen Energy, 2018, 43(6): 3077-3086.
16	YING X, ZHANG L, XU H, et al. Efficient Fischer-Tropsch microreactor with innovative aluminizing pretreatment on stainless steel substrate for Co/Al₂O₃ catalyst coating[J]. Fuel Processing Technology, 2016, 143: 51-59.
17	ARZAMENDI G, DIEGUEZ P M, Montes M, et al. Computational fluid dynamics study of heat transfer in a microchannel reactor for low-temperature Fischer-Tropsch synthesis[J]. Chemical Engineering Journal, 2010, 160(3): 915-922.
18	SHIN M S, PARK N, PARK M J, et al. Computational fluid dynamics model of a modular multichannel reactor for Fischer-Tropsch synthesis: maximum utilization of catalytic bed by microchannel heat exchangers[J]. Chemical Engineering Journal, 2013, 234: 23-32.
19	DEREVICH I V, ERMOLAEV V S, MORDKOVICH V Z, et al. Simulation of fluid dynamics in a microchannel Fischer-Tropsch reactor[J]. Theoretical Foundations of Chemical Engineering, 2012, 46(1): 8-19.
20	DEREVICH I V, ERMOLAEV V S, MORDKOVICH V Z, et al. Modeling of hydrodynamics in microchannel reactor for Fischer-Tropsch synthesis[J]. International Journal of Heat and Mass Transfer, 2012, 55: 1695-1708.
21	SUN Y, YANG G, ZHANG L, et al. Fischer-Tropsch synthesis in a microchannel reactor using mesoporous silica supported bimetallic Co-Ni catalyst: process optimization and kinetic modeling[J]. Chemical Engineering & Processing Process Intensification, 2017, 119: 44-61.
22	MOHAMMAD M, BEPARI S, ARAVAMUDHAN S, et al. Kinetics of Fischer-Tropsch synthesis in a 3-D printed stainless steel microreactor using different mesoporous silica supported Co-Ru catalysts[J]. Catalysts, 2019, 9(10): 872.
23	罗青, 张丽, 曹军, 等. 微通道下费托合成催化剂层涂覆厚度的数值研究[J]. 化工进展, 2015, 34(3): 652-658.
	LUO Qing, ZHANG Li, CAO Jun, et al. Numerical study on catalytic Fischer-Tropsch synthesis reaction in micro-channel[J]. Chemical Industry and Engineering Progress, 2015, 34(3): 652-658.
24	GUMUSLU G, AVCI A K. Parametric analysis of Fischer-Tropsch synthesis in a catalytic microchannel reactor[J]. AIChE Journal, 2012, 58(1): 227-235.

[1]	王云飞, 秦蕊, 郑利军, 李焱, 李清平. 旋转填充床CFD模拟研究进展[J]. 化工进展, 2023, 42(S1): 1-9.
[2]	孙继鹏, 韩靖, 唐杨超, 闫汉博, 张杰瑶, 肖苹, 吴峰. 硫黄湿法成型过程数值模拟与操作参数优化[J]. 化工进展, 2023, 42(S1): 189-196.
[3]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[4]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[5]	谢璐垚, 陈崧哲, 王来军, 张平. 用于SO₂去极化电解制氢的铂基催化剂[J]. 化工进展, 2023, 42(S1): 299-309.
[6]	杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318.
[7]	王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497.
[8]	邓丽萍, 时好雨, 刘霄龙, 陈瑶姬, 严晶颖. 非贵金属改性钒钛基催化剂NH₃-SCR脱硝协同控制VOCs[J]. 化工进展, 2023, 42(S1): 542-548.
[9]	罗成, 范晓勇, 朱永红, 田丰, 崔楼伟, 杜崇鹏, 王飞利, 李冬, 郑化安. 中低温煤焦油加氢反应器不同分配器中液体分布的CFD模拟[J]. 化工进展, 2023, 42(9): 4538-4549.
[10]	程涛, 崔瑞利, 宋俊男, 张天琪, 张耘赫, 梁世杰, 朴实. 渣油加氢装置杂质沉积规律与压降升高机理分析[J]. 化工进展, 2023, 42(9): 4616-4627.
[11]	王鹏, 史会兵, 赵德明, 冯保林, 陈倩, 杨妲. 过渡金属催化氯代物的羰基化反应研究进展[J]. 化工进展, 2023, 42(9): 4649-4666.
[12]	张启, 赵红, 荣峻峰. 质子交换膜燃料电池中氧还原反应抗毒性电催化剂研究进展[J]. 化工进展, 2023, 42(9): 4677-4691.
[13]	王伟涛, 鲍婷玉, 姜旭禄, 何珍红, 王宽, 杨阳, 刘昭铁. 醛酮树脂基非金属催化剂催化氧气氧化苯制备苯酚[J]. 化工进展, 2023, 42(9): 4706-4715.
[14]	葛亚粉, 孙宇, 肖鹏, 刘琦, 刘波, 孙成蓥, 巩雁军. 分子筛去除VOCs的研究进展[J]. 化工进展, 2023, 42(9): 4716-4730.
[15]	邓建, 王凯, 骆广生. 面向硝基化学品安全生产的绝热连续微反应技术发展及思考[J]. 化工进展, 2023, 42(8): 3923-3925.