HCN、COS和CS2催化水解及其水解产物协同净化的研究进展

doi:10.16085/j.issn.1000-6613.2017-0835

摘要/Abstract

摘要： 氰化氢（HCN）、羰基硫（COS）、二硫化碳（CS₂）广泛共存于黄磷尾气、焦炉煤气、碳一化工等化工行业废气中，目前大多数研究局限于3种气体的单独脱除，3种气体同时脱除的研究鲜有报道，而3种气体的协同脱除势在必行。催化水解法能够将HCN转化成NH₃，COS和CS₂水解成H₂S。NH₃和H₂S可以分别被催化氧化为N₂及S，S可以回收利用。一步法实现HCN、COS和CS₂的水解及水解产物NH₃和H₂S的催化氧化的催化剂开发是该技术的核心问题，本文针对近几年3种气体水解催化剂的相关研究成果进行了综述，包括负载型催化剂和非负载型催化剂，与此同时，针对水解产物NH₃和H₂S的催化氧化的协同净化技术进行了分析，旨在为后续3种气体同时催化水解及协同净化其水解产物催化剂的开发提供理论指导，为低温环境下协同催化水解HCN、COS和CS₂，并利用原料气中的氧一步法净化水解产物技术的未来发展及应用提供参考。

关键词: 催化, 水解, 催化剂载体, 氰化氢, 羰基硫, 二硫化碳, 水解产物, 协同净化

Abstract: HCN (hydrogen cyanide), COS (carbonyl sulfide)and CS₂ (carbon disulfide) are widely coexisted in the chemical industry tail gas, for example, yellow phosphorus tail gas, coke oven gas and C1 chemical industry. At present, there are many studies on the single removal of the three gases, and the research on the simultaneous removal of the three gases is rarely reported. So simultaneous removing of three gases is necessary. HCN can be converted into NH₃, and COS/CS₂ can be converted into H₂S during the catalysis hydrolysis process. NH₃ and H₂S can be catalytic oxidized to N₂ and S respectively, and S can be recycled. The development of catalysts for the simultaneous catalytic hydrolysis of HCN, COS and CS₂ and oxidation of NH₃ and H₂S in one step is the key problem of this technology. In this paper, the related research achievements of catalysts for hydrolysis of three gas were reviewed both in supported catalyst and unsupported catalyst. Meanwhile, the synergetic purification technology of hydrolysates (NH₃ and H₂S)was analyzed. This paper provides a reference to the development and application of the way that catalytic hydrolysis of HCN/COS/CS₂ and synergistic purification of hydrolyzate in one-step at low temperature.

Key words: catalysis, hydrolysis, catalyst support, hydrogen cyanide, carbonyl sulfide, carbon disulfide, hydrolysis product, synergetic purification

中图分类号:

X511

刘娜, 宁平, 李凯, 梅毅, 王驰, 孙鑫, 汤立红, 宋辛, 唐勰. HCN、COS和CS₂催化水解及其水解产物协同净化的研究进展[J]. 化工进展, 2018, 37(01): 301-310.

LIU Na, NING Ping, LI Kai, MEI Yi, WANG Chi, SUN Xin, TANG Lihong, SONG Xin, TANG Xie. Research progress in catalytic hydrolysis of HCN, COS and CS₂and synergetic purification of hydrolysates[J]. Chemical Industry and Engineering Progress, 2018, 37(01): 301-310.

参考文献

[1] 蒋明,宁平,王重华,等. 含氰化氢废气治理研究进展[J]. 化工进展,2012,31(11):2563-2569. JIANG M,NING P,WANG Z H,et al. Research progress of HCN-containing exhaust gas treatment[J]. Chemical Industry and Engineering Progress,2012,31(11):2563-2569.
[2] WANG Z,JIANG M,NING P,et al. Thermodynamic modeling and gaseous pollution prediction of the Yellow Phosphorus production[J]. Industrial & Engineering Chemistry Research,2011,50(21):12194-12202.
[3] YUAN S,ZHOU Z,LI J,et al. HCN and NH₃ released from biomass and soybean cake under rapid pyrolysis[J]. Energy Fuels,2010,24(11):6166-6171.
[4] YANG Y,SUH S. Environmental impacts of products in China[J]. Environmental Science & Technology,2011,45(9):4102-4109.
[5] JIANG M,WANG Z H,NING P,et al. Dust removal and purification of calcium carbide furnace off-gas[J]. Journal of the Taiwan Institute of Chemical Engineers,2014,45(3):901-907.
[6] 张奉民,李开喜,吕春祥,等. 氰化氢脱除方法[J]. 新型炭材料,2003(2):151-157. ZHANG F M,LI K X,LU C X,et al. Removal methods of hydrogen cyanide[J]. New Carbon Materials,2003(2):151-157.
[7] TAN H,WANG X,WANG C,et al. Characteristics of HCN removal using CaO at high temperatures[J]. Energy & Fuels,2009,23(3):1545-1550.
[8] YEDDOU A R,CHERGUI S,CHERGUI A,et al. Removal of cyanide in aqueous solution by oxidation with hydrogen peroxide in presence of copper-impregnated activated carbon[J]. Minerals Engineering,2011,24:788-793.
[9] GIMÉNEZ-LÓPEZ J,MILLERA A,BILBAO R,et al. HCN oxidation in an O₂/CO₂ atmosphere:an experimental and kinetic modeling study[J]. Combustion and Flame,2010,157:267-276.
[10] ZHAO Q,TIAN S L,YAN L X,et al. Novel HCN sorbents based on layered double hydroxides:Sorption mechanism and performance[J]. Journal of Hazardous Materials,2015,285:250-258.
[11] COLIN-GARCIA M,HEREDIA A,NEGRON-MENDOZA A,et al.Adsorption of HCN onto sodium montmorillonite dependent on the pH as a component to chemical evolution[J]. International Journal of Astrobiology,2014,13(4):310-318.
[12] NING P,QIU J,WANG X Q,et al. Metal loaded zeolite adsorbents for hydrogen cyanide removal[J]. Journal of Environmental Sciences,2013,25(4):808-814.
[13] HOU H W,ZHU Y,TANG G L,et al. Lamellar γ-AlOOH architectures:synthesis and application for the removal of HCN[J]. Materials Characteriaztion,2012,68:33-41.
[14] MARSH J D F,NEWLING W B S,RICH J. The catalytic hydrolysis of hydrogen cyanide to ammonia[J]. Journal of Applied Chemistry,1952,2(12):681-684.
[15] NABBA T,OBUCHI A,AKARATIWA S,et al. Catalytic hydrolysis of HCN over H-ferrierite[J]. Chemistry Letters,2000,29(9):986-987.
[16] KRÖCHER O,ELSENER M. Hydrolysis and oxidation of gaseous HCN over heterogeneous catalysts[J]. Applied Catalysis B:Environmental,2009,92(1/2):75-89.
[17] 雷军,王先厚,张清建,等. 工业废气中氰化氢脱除技术的工业应用研究[J]. 天然气化工(C1化学与化工),2016(3):82-85. LEI J,WANG X,ZHANG Q J,et al. Application research of HCN removal technology in industrial waste gases[J]. Natural Gas Chemical Industry,2016(3):82-85.
[18] WANG Y J,CHEN S Y. CHEN H,et al. Removal of carbonyl sulfide from CO₂ stream using AgNO₃-modified NaZSM-5[J] Energy Chem.,2013,22:902-906.
[19] WANG X Q,MA Y X,NING P,et al. Adsorption of carbonyl sulfide on modified activated carbon under low-oxygen content conditions[J]. Adsorption-Journal of the International Adsorption Society,2014,20:623-630.
[20] QIU J,NING P,WANG X,et al. Removing carbonyl sulfide with metal-modified activated carbon[J]. Frontiers of Environmental Science & Engineering,2014,10(1):1-8.
[21] LI Q,YI H,TANG X,et al. Preparation and characterization of Cu/Ni/Fe hydrotalcite-derived compounds as catalysts for the hydrolysis of carbon disulfide[J]. Chemical Engineering Journal,2016,284:103-111.
[22] LAPERDRIX E,JUSTIN I,COSTENTIN G,et al. Comparative study of CS₂,hydrolysis catalyzed by alumina and titania[J]. Applied Catalysis B:Environmental,1998,17(1/2):167-173.
[23] WANG X,XU W,LIU N,et al. Synthesis of metallic Ni-Co/graphene catalysts with enhanced hydride sulfurization activity via a low-temperature plasma approach[J]. Catalysis Today,2015,256:203-208.
[24] SHEN C,WANG Y J,XU J H,et al. Synthesis of TS-1 on porous glass beads for catalytic oxidative desulfurization[J]. Chemical Engineering Journal,2015,259(10):552-561.
[25] DOU J,ZENG H C. Integrated networks of mesoporous silica nanowires and their bifunctional catalysis-sorption application for oxidative desulfurization[J]. ACS Catalysis,2014,4(4):566-576.
[26] ABOULAYT A,MAUGE F,HOGGAN P E,et al. Combined FTIR,reactivity and quantum chemistry investigation of COS hydrolysis at metal oxide surfaces used to compare hydroxyl group basicity[J]. Catalysis Letters,1996,39(3):213-218.
[27] SAUR O,BENSITEL M,SAAD A B M,et al. The structure and stability of sulfated alumina and titania[J]. Journal of Catalysis,1986,99(1):104-110.
[28] YUE Y,ZHAO X,HUA W,et al. Nanosized titania and zirconia as catalysts for hydrolysis of carbon disulfide[J]. Applied Catalysis B:Environmental,2003,46(3):561-572.
[29] CLARK P D,DOWLING N I,HUANG M. Conversion of CS₂,and COS over alumina and titania under claus process conditions:reaction with H₂O and SO₂[J]. Applied Catalysis B:Environmental,2001,31(2):107-112.
[30] 唐国旗,张春富,孙长山,等. 活性氧化铝载体的研究进展化工进展[J]. 化工进展,2011,30(8):1756-1765. TANG G Q,ZHANG C F,SUN C S,et al. Research progress of γ-alumina support[J]. Chemical Industry and Engineering Progress,2011,30(8):1756-1765.
[31] LAPEEDRIX E,JUSTIN I,COSTENTIN G,et al. Comparative study of CS₂ hydrolysis catalyzed by alumina and titania[J]. Applied Catalysis B:Environmental,1998,17:167-173.
[32] 陈亚宾. NCT-1有机硫水解催化剂的研制[J]. 化学工业与工程技术,1997,18(3):9-11. CHEN Y B. Investigation and preparation of and NCT-11 organic sulfur hydrolyst[J]. Journal of Chemical Industry & Engineering,1997,18(3):9-11.
[33] WANG L,GUO Y,LU G,et al. Effect of activated carbon support on CS₂ removal over coupling catalysts[J]. Journal of Natural Gas Chemistry,2011,20(4):397-402.
[34] YI H H,LU L L,TANG X L,et al. Catalytic hydrolysis of carbonyl sulfide over modified coal-based activated carbons[J]. Journal of Central South University,2010,17:985-990.
[35] 王红妍,易红宏,唐晓龙,等. 改性活性炭催化水解羰基硫[J]. 中南大学学报(自然科学版),2011,42(3):848-852. WANG H Y,YI H H,TANG X L,et al. Catalytic hydrolysis of carbonyl sulfide over modified activated carbon[J]. Journal of Central South University(Science and Technology),2011,42(3):848-852.
[36] 李凯. COS、CS₂水解催化剂的开发及机理研究[D]. 昆明:昆明理工大学,2013. LI K. Research on development of catalyst for simultaneous catalytic hydrolysis of COS and CS₂ and the reaction mechanism[D]. Kunming:Kunming University of Science and Technology,2013.
[37] 宁平,蒋明,王学谦,等. 低浓度氰化氢在浸渍活性炭上的吸附净化研究[J]. 高校化学工程学报,2010(6):1038-1045. NING P,JIANG M,WANG X Q,et al. Adsorption of low-concentration HCN on impregnated activated carbon[J]. Journal of Chemical Engineering of Chinese Universities,2010(6):1038-1045.
[38] 蒋明,宁平,王重华,等. 改性活性炭吸附脱除氰化氢[J]. 中南大学学报(自然科学版),2012(8):3294-3299. JIANG M,NING P,WANG Z H,et al. Adsorption removal of hydrogen cyanide by modified activated carbon[J]. Journal of Central South University (Science and Technology),2012(8):3294-3299.
[39] 王辉,谈世韵,郭汉贤. 羰基硫在TGH催化剂的表面化学研究[J]. 太原工业大学学报,1991,22(3):56-61. WANG H,TAN S Y,GUO H X. A study of adsorption of COS over TGH catalyst[J]. Journal of Taiyuan University of Technology,1991,22(3):56-61.
[40] TAN S,LI C,LIANG S,et al. Compensation effect in catalytic hydrolysis of carbonyl sulfide at lower temperature[J]. Catalysis Letters,1991(8):155-168.
[41] 于丽丽. 活性炭基水解羰基硫催化剂的筛选及动力学研究[D]. 昆明:昆明理工大学:2009. YU L L.Preparation of activated carbon based catalysts and research of kinetics for catalytic hydrolysis carbonyl sulfide[D]. Kunming:Kunming University of Science and Technology,2009.
[42] 袁信,周键,田森林,等. 过渡金属负载γ-Al₂O₃对HCN催化水解性能的影响[J]. 环境科学研究,2014(12):1465-1471. YUAN X,ZHOU J,TIAN S L,et al. Effects oftransition metals grafted γ-Al₂O₃ on catalytic hydrolysis of HCN[J]. Research of Environmental Sciences,2014(12):1465-1471.
[43] WEST J,WILLIAMS B P,YOUNG N,et al. Ni and Zn-promotion of γ-Al₂O₃ for the hydrolysis of COS under mild conditions[J]. Catalyst Commun,2001(2):135-138.
[44] 刘伟,宣中伟,崔作林,等. 氢电弧等离子体法制备纳米钛粒子脱硫性能研究[J]. 分子催化,2004,18(3):224-230. LIU W,XUAN Z W,CUI Z L,et al. The desulphurization of nano-Ti particles prepared by H²⁺ Ar Arc Plasma Method[J]. Journal of Molecular Catalysiss(China),2004,18(3):224-230.
[45] 余春,上官炬,梁丽彤,等. TiO₂和V₂O₅改性Al₂O₃催化剂催化有机硫化物水解的性能[J]. 石油化工,2009,38(4):384-388. YU C,SHANGGUAN J,LIANG L T,et al. Hydrolysis of organic sulfideon aluminum catalysts with TiO₂ and V₂O₅ modification[J]. Petrochemical Technology,2009,38(4):384-388.
[46] 刘强,柯明,于沛,等. 氧化锆负载型活性炭催化水解COS和CS₂[J]. 石油化工,2016,45(5):552-558. LIU Q,KE M,YU P,et al. Research on catalytic hydrolysis of carbonyl sulfide and carbon disulfide over ZrO₂ modified activated carbon[J]. Petrochemical Technology,2016,45(5):552-558.
[47] OZAY O,INGER E,AKTAS N,et al. Hydrogen production from ammonia borane via hydrogel template synthesized Cu,Ni,Co composites[J]. International Journal of Hydrogen Energy,2011,36(14):8209-8216.
[48] 张菊,丁云杰,郑小明,等. 负载型γ-Al₂O₃催化剂对有机硫的水解性能[J]. 现代化工,1994,14(6):21-23. ZHANG J,DING Y J,ZHENG X M,et al. Hydrulysis of organic sulfur on γ-Al₂O₃-supported catalysts[J]. Modern Chemical Industry,1994,14(6):21-23.
[49] SHANGGUAN J. Hydrolysis of carbonylsulfide and carbon disulfide over alumina based catalysts Ⅰ. Study onactivities of COS and CS₂ hydrolysis[J]. Journal of Natural Gas Chemistry,1998,7(1):24-30.
[50] 王冠,孙同华,张宏波,等. 催化水解法低温脱除煤气中羰基硫的研究[J]. 现代化工,2014,34(1):60-63. WANG G,SUN T H,ZHANG H B,et al. Carbonyl sulfide gas removal by catalytic hydrolysis in low temperature[J]. Modern Chemical Industry,2014,34(1):60-63.
[51] 李春虎,郭汉贤,谭世韶.碱改性γ-Al₂O₃催化剂表面碱强度分布与COS水解活性的研究[J]. 分子催化,1994,8(4):305-311. LI C H,GUO H X,TAN S Z. Study on the alkalized γ-Al₂O₃ catalyst for its base strength distribution and catalyst activity[J]. Journal of Molecular Catalysiss(China),1994,8(4):305-311.
[52] 王丽,李福林,吴迪镛,等. 催化水解-氧化耦合一步法脱除二硫化碳的研究[J]. 燃料化学学报,2004,32(4):466-470. WANG L,LI F L,WU D Y,et al. A novel desulfuring agent for CS₂ removal by couple processing[J]. Journal of Fuel Chemistry and Technology,2004,32(4):466-470.
[53] SUN X,NING P,TANG X,et al. Simultaneous catalytic hydrolysis of carbonyl sulfide and carbon disulfide over Al₂O₃-K/CAC catalyst at low temperature[J]. Journal of Energy Chemistry,2014,23(2):221-226.
[54] NING P,LI K,YI H,et al. Simultaneous catalytic hydrolysis of carbonyl sulfide and carbon disulfide over modified microwave coal-based active carbon catalysts at low temperature[J]. Journal of Physical Chemistry C,2012,116(32):17055-17062.
[55] 柯明,许赛威,刘成翠,等. 常温羰基硫水解催化剂的研究进展[J]. 石油与天然气化工,2007,36(4):271-274. KE M,XU S W,LIU C C,et al. The research developmenton COS hydrolysis catalystat ambient temperature[J]. Chemical Engineering of Oil & Gas,2007,36(4):271-274.
[56] 闫林霞,田森林,宁平,等. 复合金属氧化物Cu-Co-Al低温催化水解HCN[J]. 中国环境科学,2015(10):2964-2971. YAN L X,TIAN S L,NING P,et al. Purification of HCN by catalytic hydrolysis over Cu-Co-Al complex metal oxide under lower temperature[J]. China Environmental Science,2015(10):2964-2971.
[57] YEDDOU A R,CHERGUI S,CHERGUI A,et al. Removal of cyanide in aqueous solution by oxidation with hydrogen peroxide in presence of copper-impregnated activated carbon[J]. Minerals Engineering,2011,24:788-793.
[58] 王红妍,易红宏,唐晓龙,等. 类水滑石衍生复合氧化物催化水解羰基硫的研究[J]. 环境工程学报,2012(2):545-549. WANG H Y,YI H H,TANG X L,et al. Study of hydrolysis carbonyl sulfide over mixed oxides from hydrotalcite-like compounds[J]. Chinese Journal of Environmental Engineering,2012(2):545-549.
[59] GUO H,TANG L,LI K,et al. Influence of the preparation conditions of MgAlCe catalysts on the catalytic hydrolysis of carbonyl sulfide at low temperature[J]. RSC Advances,2015,5(26):20530-20537.
[60] 闫林霞. Cu-Al类水滑石衍生氧化物低温催化水解HCN[D]. 昆明:昆明理工大学,2015. Purification of HCN gases by catalytic hydrolysis over Cu-Al mixed oxides derived from hydrotalcite-like compounds under lower temperature[D]. Kunming:Kunming University of Science and Technology,2015.
[61] 杨丽君,张世鸿,王家强,等. Ru/γ-Al₂O₃和Ru/AC催化剂的制备及其对氨氧化反应的催化性能[J]. 化工环保,2009(5):463-466. YANG L J,ZHANG S H,WANG J Q,et al. Preparation of Ru/γ-Al₂O₃ and Ru/AC catalysts and their catalytic capabilities on oxidation of ammonia[J]. Environmental Protection of Chemical Industry,2009(5):463-466.
[62] ZHANG L,ZHANG C,HE H. The role of silver speci,es on Ag/Al₂O₃ catalysts for the selective catalytic oxidation of ammonia to nitrogen[J]. Journal of Catalysis,2009,261(1):101-109.
[63] HU J,TANG X,YI H,et al. Low-temperature selective catalytic oxidation of ammonia over the CuO_x/C-TiO₂ catalyst[J]. Research on Chemical Intermediates,2014,41:1-10.
[64] KUŠAR H M J,ERSSON A G,VOSECKÝ M,et al. Selective catalytic oxidation of NH₃ to N₂ for catalytic combustion of low heating value gas under lean/rich conditions[J]. Applied Catalysis B:Environmental,2005,58:25-32.
[65] SANG M L,HONG S C. Promotional effect of vanadium on the selective catalytic oxidation of NH₃ to N₂ over Ce/V/TiO₂ catalyst[J]. Applied Catalysis B:Environmental,2015,163:3039.
[66] KALINKIN P,KOVALENKO O,LAPINA O,et al. Kinetic peculiarities in the low-temperature oxidation of H₂S over vanadium catalysts[J]. Journal of Molecular Catalysis A:Chemical,2002,178(1/2):173-180.
[67] SHIN M Y,PARK D W,CHUNG J S. Development of vanadium based mixed oxide catalysts for selective oxidation of H₂S to sulfur[J]. Applied Catalysis B:Environmental,2001,30(3/4):409-419.
[68] CHUNG J S,PAIK S C,KIM H S,et al. Removal of H₂S and or SO₂ by catalytic conversion technologies[J]. Catalysis Today,1997,35(1):37-43.
[69] UHM J H,SHIN M Y,JIANG Z D,et al. Selective oxidation of H₂S to elemental sulfur over chromium oxide catalysts[J]. Applied Catalysis B:Environmental,1999,22(4):293-303.
[70] KIM B G,JU W D,KIM I,et al. Performance of vanadium-molybdenum mixed oxide catalysts in selective oxidation of hydrogen sulfide containing excess water and ammonia[J]. Solid State Ionics,2004,172(1):135-138.
[71] ZHANG X,WANG Z,QIAO N,et al. Selective catalytic oxidation of H₂S over well-mixed oxides derived from Mg₂Al_xV_1-x layered double hydroxides[J]. ACS Catalysis,2014,4(5):1500-1510.
[72] LEE E K,JUNG K D,JOO O S,et al. Support effects in catalytic wet oxidation of H₂S to sulfur on supported iron oxide catalysts[J]. Applied Catalysis A:General,2005,284:1-4.
[73] CARIASO O C,JR WALLKER P L. Oxidation of hydrogen sulfide overmicroporous carbons[J]. Carbon,1975,13(3):233-239.
[74] STEIJNS M,MARS P. Catalytic oxidation of hydrogen sulfideinfluence of pore structure and chemical composition of various porous substances[J]. Industrial and Engineering Chemistry Product Research and Development,1977,16(1):35-41.
[75] KALIVA A N,SMITH J W. Oxidation of low concentrations ofhydrogen sulfide by air on a fixed activated carbon bed[J]. Canadian Journal of Chemical Engineering,1983,61(2):208-212.
[76] BASHOVA S,BAKER F S,WU X X,et al. Activated carbon catalyst for selective oxidation of hydrogen sulphide:on the influence of pore structure,surface characteristics,and catalytically-active nitrogen[J]. Carbon,2007,45(6):1354-1363.

HCN、COS和CS₂催化水解及其水解产物协同净化的研究进展

Research progress in catalytic hydrolysis of HCN, COS and CS₂and synergetic purification of hydrolysates

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[2]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[3]	谢璐垚, 陈崧哲, 王来军, 张平. 用于SO₂去极化电解制氢的铂基催化剂[J]. 化工进展, 2023, 42(S1): 299-309.
[4]	杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318.
[5]	郑谦, 官修帅, 靳山彪, 张长明, 张小超. 铈锆固溶体Ce_0.25Zr_0.75O₂光热协同催化CO₂与甲醇合成DMC[J]. 化工进展, 2023, 42(S1): 319-327.
[6]	王正坤, 黎四芳. 双子表面活性剂癸炔二醇的绿色合成[J]. 化工进展, 2023, 42(S1): 400-410.
[7]	高雨飞, 鲁金凤. 非均相催化臭氧氧化作用机理研究进展[J]. 化工进展, 2023, 42(S1): 430-438.
[8]	王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497.
[9]	邓丽萍, 时好雨, 刘霄龙, 陈瑶姬, 严晶颖. 非贵金属改性钒钛基催化剂NH₃-SCR脱硝协同控制VOCs[J]. 化工进展, 2023, 42(S1): 542-548.
[10]	许友好, 王维, 鲁波娜, 徐惠, 何鸣元. 中国炼油创新技术MIP的开发策略及启示[J]. 化工进展, 2023, 42(9): 4465-4470.
[11]	耿源泽, 周俊虎, 张天佑, 朱晓宇, 杨卫娟. 部分填充床燃烧器中庚烷均相/异相耦合燃烧[J]. 化工进展, 2023, 42(9): 4514-4521.
[12]	程涛, 崔瑞利, 宋俊男, 张天琪, 张耘赫, 梁世杰, 朴实. 渣油加氢装置杂质沉积规律与压降升高机理分析[J]. 化工进展, 2023, 42(9): 4616-4627.
[13]	王晋刚, 张剑波, 唐雪娇, 刘金鹏, 鞠美庭. 机动车尾气脱硝催化剂Cu-SSZ-13的改性研究进展[J]. 化工进展, 2023, 42(9): 4636-4648.
[14]	王鹏, 史会兵, 赵德明, 冯保林, 陈倩, 杨妲. 过渡金属催化氯代物的羰基化反应研究进展[J]. 化工进展, 2023, 42(9): 4649-4666.
[15]	高彦静. 单原子催化技术国际研究态势分析[J]. 化工进展, 2023, 42(9): 4667-4676.